Estimation of the annual effective dose from exposure to radon in drinking water in Croatia.

Radon is known as the main source of radiation for the general public. Results of extensive measurements of radon in water samples collected from private wells, natural springs and public water supply in Croatia are presented and annual effective doses are estimated. Measurements were performed by two different methods: the emanometry method (by using the AlphaGUARD instrument with additional AquaKIT module) and/or the liquid scintillation method (by using LSC TriCarb 2900). Water samples were collected in public water supplies in urban areas as well as private wells and springs in rural areas. The obtained average radon activity concentration based on the extensive measurement of almost 1000 water samples is 4.1 ± 1.9 Bq/l, with a minimum value of 0.2 and maximum value of 36 Bq/l respectively. The wide range of measured values is a consequence of the source of the water sample (ground/natural water versus treated water) as well as the geological structures around the water source. All estimated ingestion doses due to radon assuming consumption of 2 l of water per day from the observed source were within the interval 6.3-36.8 µSv (with calculated average and standard deviation 19.3 ± 10.3 µSv) for the water consumption from private wells and natural springs and 2.4-40.0 µSv (with calculated average and standard deviation 13.0 ± 10.5 µSv) for the water consumption from the public water supplies.

Simulation and Optimization of FAPbI3 Perovskite Solar Cells with a BaTiO3 Layer for Efficiency Enhancement.

Since the addition of BaTiO3 in perovskite solar cells (PSCs) provides a more energetically favorable transport route for electrons, resulting in more efficient charge separation and electron extraction, in this work we experimentally prepared such a PSC and used a modeling approach to point out which simulation parameters have an influence on PSC characteristics and how they can be improved. We added a layer of BaTiO3 onto the TiO2 electron transport layer and prepared a PSC, which had an FTO/TiO2/BaTiO3/FAPbI3/spiro-OMeTAD/Au architecture with a power conversion efficiency (PCE) of 11%. Further, we used the simulation program SCAPS-1D to investigate and optimize the device parameters (thickness of the BaTiO3 and absorber layers, doping, and defect concentration) resulting in devices with PCEs reaching up to 15%, and even up to 20% if we assume an ideal structure with no interlayer defects. Our experimental findings and simulations in this paper highlight the promising interplay of multilayer TiO2/BaTiO3 ETLs for potential future applications in PSCs.

Simulating the Performance of a Formamidinium Based Mixed Cation Lead Halide Perovskite Solar Cell.

With the aim of decreasing the number of experiments to obtain a perovskite solar cell (PSC) with maximum theoretical efficiency, in this paper, PSC performance was studied using the program solar cell capacitance simulator (SCAPS-1D). The PSC with the architecture ITO/TiO2/perovskite/spiro-MeOTAD/Au was investigated, while the selected perovskite was mixed cation Rb0.05Cs0.1FA0.85PbI3. The analysis was based on an experimentally prepared solar cell with a power conversion efficiency of ~7%. The PSC performance, verified by short-circuit current density (Jsc), open-circuit voltage (Voc), fill factor (FF) and power conversion efficiency (PCE), was studied by optimization of the simulation parameters responsible for improvement of the cell operation. The optimized parameters were absorber layer thickness, doping, defect concentration and the influence of the resistivity (the net effect of ohmic loss, Rs and the leakage current loss represented by the resistivity, Rshunt). The results of SCAPS-1D simulations estimated the theoretical power conversion efficiency of 15% for our material. We have showed that the main contribution to improvement of solar cell efficiency comes with lowering ohmic resistivity of the cell as well as doping and defect concentration, because their concentration is proportional to recombination rate.

Potential benefit of retrospective use of neutron monitors in improving ionising radiation exposure assessment on international flights: issues raised by neutron passive dosimeter measurements and EPCARD simulations during sudden changes in solar activity.

Since air transport became more accessible, more and more people have been exposed to ionising radiation of cosmic origin. Measuring the neutron dose equivalent is a good approximation of total ambient dose equivalent, as neutrons carry about 50 % of the dose at flight altitudes. The aim of our study was to compare our measurements of the neutron component of secondary cosmic radiation dose, taken with passive dosimeters, with the data obtained from a simulation generated by EPCARD software, which is common in assessing flight crew exposure to ionising radiation. We observed deviations (both above and below) from the expected proportion of the neutron component (between 40 and 80 %), which pointed to certain issues with actual passive dosimeter measurement and the EPCARD simulation. The main limitation of the dosimeter are large uncertainties in high energy neutron response, which may result in underestimation of neutron dose equivalent. The main drawback of the software simulation is monthly averaging of solar potential in calculations, which can neglect sporadic high energy events. Since airlines worldwide almost exclusively use software (due to costs and convenience) to estimate the dose received by their crew, it is advisable to retrospectively recalculate the dose taking into account neutron monitor readings when solar activity changes.

Assessing the radiological load on the environment in the middle Danube river basin on the basis of a study of the Kopacki Rit Nature Park, Croatia.

A study of the environmental radioactivity in the Kopacki Rit Nature Park, Croatia, is presented. This wildlife reserve is part of the Middle Danube River Basin, and it is exposed to various pollutants due to a number of human activities in the surroundings, where there is a nuclear power plant and also urban centres and areas of intense agricultural production. Results for the activity concentrations of soil and surface water samples do not indicate any elevated radioactivity level, which is confirmed by on-site measurements of ambient dose rate equivalent. An assessment of the radiological load on the local biota, carried out using the ERICA tool, implies an overall low radiological risk even if conservative values of the risk quotient are used. Therefore, human activities do not have a significant effect on the radiological load on the Kopacki Rit area. A similar conclusion might be made with regard to numerous similar environments in the Middle Danube River Basin.

Identification and mapping of radon-prone areas in Croatia-preliminary results for Lika-Senj and the southern part of Karlovac counties.

Long-term indoor radon measurements performed by LR 115 track etched detectors in Croatian homes during 2003-04 showed that the arithmetic means of radon concentrations in Lika-Senj and the southern part of Karlovac counties were three times higher (198 Bq m(-3)) than in houses at national level (68 Bq m(-3)). Recently, indoor radon measurements in randomly selected houses were investigated. The obtained values in these new measurements have confirmed the values obtained 10 y ago (the average radon value in 225 investigated houses in this area is 223 Bq m(-3)). Radon concentrations in soil gas were measured in September and October 2012 and 2013 with the AlphaGUARD measuring system. Areas with both elevated indoor radon levels and radon in soil gas were identified (some micro locations in Korenica, Licko Lesce, Generalski Stol, Slunj and Ogulin) and visually presented in the form of maps using the inverse distance weighting approach.