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1.
J Chem Phys ; 158(21)2023 Jun 07.
Artigo em Inglês | MEDLINE | ID: mdl-37272575

RESUMO

Melting of a quantum system of hard spheres has been considered in the case when the effects of Bose and Fermi statistics can be neglected. It has been found that the quantum melting line always differs from the classical line except for T = 0, P = 0, where the both lines cross. It is shown that the classical limit is not reachable at any finite temperature.

2.
J Phys Condens Matter ; 31(13): 135801, 2019 Apr 03.
Artigo em Inglês | MEDLINE | ID: mdl-30669137

RESUMO

We investigate the effect of evolution of energy of longitudinal spin fluctuations on the helimagnetic transition and specific heat in a Heisenberg magnet with the Dzyaloshinskii-Moriya interaction that may arise in a result of applied pressure. Using the classical Monte Carlo calculations for the spin-lattice Hamiltonian accounting for variable spin amplitudes we find that the helical phase transition is pretty robust against the longitudinal spin fluctuations. At the same time the amplitude of the fluctuation hump seen in the specific heat dependence at [Formula: see text] and its position are significantly affected. Depending on the mode of evolution the hump either shifts to lower or higher temperatures increasing its amplitude with the amplitude of the fluctuations.

3.
J Phys Condens Matter ; 26(39): 396001, 2014 Oct 01.
Artigo em Inglês | MEDLINE | ID: mdl-25192039

RESUMO

We measured the Raman spectra of ferromagnetic, nearly half-metallic, CoS2 over a broad temperature range. All five Raman active modes Ag, Eg, Tg(1), Tg(2) and Tg(3) were observed. The magnetic ordering is indicated by a change of the temperature dependences of the frequency and the line width of Ag and Tg(2) modes at the Curie point. The temperature dependence of the frequencies and line widths of the Ag, Eg, Tg(1), Tg(2) modes in the paramagnetic phase can be described in the framework of the Klemens approach. Hardening of the Tg(2), Tg(1) and Ag modes on cooling can be unambiguously seen in the ferromagnetic phase. The line widths of Tg(2) and Ag modes behave in a natural way at low exciting laser powers (they decrease with decreasing temperature) in the ferromagnetic phase. At high exciting laser powers the corresponding line widths increase as temperature decreases below the Curie temperature. Then, as will be shown, the line width of the Ag mode reaches a maximum at about 80 K. Tentative explanations of some of the observed effects are given, taking into account the nearly half-metallic nature of CoS2.

4.
J Phys Condens Matter ; 21(19): 196001, 2009 May 13.
Artigo em Inglês | MEDLINE | ID: mdl-21825499

RESUMO

Measurements of the sound velocities in a single crystal of MnSi were performed in the temperature range 4-150 K. Elastic constants, controlling propagation of longitudinal waves, reveal significant softening at a temperature of about 29.6 K and small discontinuities at ∼28.8 K, which corresponds to the magnetic phase transition in MnSi. In contrast, the shear elastic moduli do not show any softening at all, reacting only to the small volume deformation caused by the magneto-volume effect. The current ultrasonic study exposes an important fact that the magnetic phase transition in MnSi, occurring at 28.8 K, is just a minor feature of the global transformation marked by the rounded maxima or minima of heat capacity, thermal expansion coefficient, sound velocities and absorption, and the temperature derivative of resistivity.

5.
J Chem Phys ; 129(6): 064512, 2008 Aug 14.
Artigo em Inglês | MEDLINE | ID: mdl-18715090

RESUMO

We report a computer-simulation study of the equilibrium phase diagram of a three-dimensional system of particles with a repulsive-step potential. Using free-energy calculations, we have determined the equilibrium phase diagram of this system. At low temperatures, we observe a number of distinct crystal phases. However, under certain conditions the system undergoes a glass transition in a regime where the liquid appears thermodynamically stable. We argue that the appearance of this amorphous low-temperature phase can be understood by viewing this one-component system as a quasibinary mixture.

6.
J Phys Condens Matter ; 20(23): 235222, 2008 Jun 11.
Artigo em Inglês | MEDLINE | ID: mdl-21694313

RESUMO

The heat capacity and thermal expansion of a high quality single crystal of MnSi were measured at ambient pressure at zero and high magnetic fields. The calculated magnetic entropy change in the temperature range 0-30 K is less than 0.1R, a low value that emphasizes the itinerant nature of magnetism in MnSi. A linear temperature term dominates the thermal expansion coefficient in the range 30-150 K, which correlates with an enhancement of the linear electronic term in the heat capacity. A surprising similarity among the variations of the heat capacity, thermal expansion coefficient and temperature derivative of the resistivity is observed through the phase transition in MnSi. Specific forms of the heat capacity, thermal expansion coefficient and temperature derivative of resistivity at the phase transition to a helical magnetic state near 29 K are interpreted as the combination of sharp first-order features and broad peaks or shallow valleys of as yet unknown origin. The appearance of these broad satellites probably hints at a frustrated magnetic state slightly above the transition temperature in MnSi.

7.
Nature ; 428(6982): 542-5, 2004 Apr 01.
Artigo em Inglês | MEDLINE | ID: mdl-15057827

RESUMO

Diamond is an electrical insulator well known for its exceptional hardness. It also conducts heat even more effectively than copper, and can withstand very high electric fields. With these physical properties, diamond is attractive for electronic applications, particularly when charge carriers are introduced (by chemical doping) into the system. Boron has one less electron than carbon and, because of its small atomic radius, boron is relatively easily incorporated into diamond; as boron acts as a charge acceptor, the resulting diamond is effectively hole-doped. Here we report the discovery of superconductivity in boron-doped diamond synthesized at high pressure (nearly 100,000 atmospheres) and temperature (2,500-2,800 K). Electrical resistivity, magnetic susceptibility, specific heat and field-dependent resistance measurements show that boron-doped diamond is a bulk, type-II superconductor below the superconducting transition temperature T(c) approximately 4 K; superconductivity survives in a magnetic field up to Hc2(0) > or = 3.5 T. The discovery of superconductivity in diamond-structured carbon suggests that Si and Ge, which also form in the diamond structure, may similarly exhibit superconductivity under the appropriate conditions.

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