Application of Scanning Electron Microscopy in the observation of dentin-adhesive interface.

The objective of this study was observation of the adhesive interface on original tooth samples, as well as their epoxy replicas, under SEM. A light-cure flowable composite was incrementally placed and light-polymerized in previously prepared cylindrical dentinal cavities on the buccal surfaces of extracted human third molars. After finishing procedures, impressions of the composite/dentin margin were made using polyvinylsiloxane in order to obtain accurate epoxy replicas for SEM analysis. Ultrastructural morphology of the adhesive surface was observed at high magnifications (≥1,000×) on original tooth samples, which were previously prepared to expose the part of the dentin surface, which participates in the formation of adhesive bond. SEM micrographs showed that marginal adaptation was mostly of acceptable quality. In some of the SEM micrographs of original tooth samples, marginal gap formation, and resin tag breakdown were noted, which were ascribed to polymerization shrinkage. Profound understanding of ultrastructural morphology is necessary for achieving more predictable and durable margin between composite restorations and surrounding tooth structures, and SEM analysis can serve that purpose.

Viscoelastic properties of uncured resin composites: Dynamic oscillatory shear test and fractional derivative model.

OBJECTIVE: In this study we analyze viscoelastic properties of three flowable (Wave, Wave MV, Wave HV) and one universal hybrid resin (Ice) composites, prior to setting. We developed a mathematical model containing fractional derivatives in order to describe their properties. METHODS: Isothermal experimental study was conducted on a rheometer with parallel plates. In dynamic oscillatory shear test, storage and loss modulus, as well as the complex viscosity where determined. We assumed four different fractional viscoelastic models, each belonging to one particular class, derivable from distributed-order fractional constitutive equation. The restrictions following from the Second law of thermodynamics are imposed on each model. The optimal parameters corresponding to each model are obtained by minimizing the error function that takes into account storage and loss modulus, thus obtaining the best fit to the experimental data. RESULTS: In the frequency range considered, we obtained that for Wave HV and Wave MV there exist a critical frequency for which loss and storage modulus curves intersect, defining a boundary between two different types of behavior: one in which storage modulus is larger than loss modulus and the other in which the situation is opposite. Loss and storage modulus curves for Ice and Wave do not show this type of behavior, having either elastic, or viscous effects dominating in entire frequency range considered. SIGNIFICANCE: The developed models may be used to predict behavior of four tested composites in different flow conditions (different deformation speed), thus helping to estimate optimal handling characteristics for specific clinical applications.

A model of the viscoelastic behavior of flowable resin composites prior to setting.

OBJECTIVE: The aim of this study is to develop fractional derivative models for the assessment of viscoelastic properties related to handling characteristics of dental resin composites belonging to two classes: flowable (Revolution Formula 2 and Filtek Ultimate) and posterior "bulk-fill" flowable base (Smart Dentin Replace). METHODS: Rheological measurements on all materials tested in this study were performed using dynamic oscillatory rheometer at temperature of 23°C. A parallel plates module with a diameter of 20mm was used to measure the properties of the resin composites tested. We developed two models to describe the obtained data: the generalized Newton model and the generalized Zener model (the so-called three parameter model). Both models contain fractional derivatives of Riemann-Liouville type. By determining the parameters of the model we were able to fit experimental data with high accuracy. RESULTS: Our results show that flowable "bulk-fill" resin-composite material (SDR) has distinct properties as compared to other two flowable resin composite materials (Revolution Formula 2 and Filtek Ultimate). Thus, previously found SDR properties as "bulk-fill" flowable base results in the fact that it is described by generalized Zener model (i.e., it has properties of solid like viscoelastic material). SIGNIFICANCE: Our model may be used to predict behavior of tested composites in different flow conditions. The SDR has initially small almost constant complex viscosity showing that it has good self-leveling property.

A method of improving marginal adaptation by elimination of singular stress point in composite restorations during resin photo-polymerization.

OBJECTIVES: To reduce the effect of stresses due to volumetric shrinkage the authors propose an incremental technique for placing composite restorations. METHODS: The goal of the method is to reduce the volume of the resin that is polymerized and eliminate a stress singular point in the resin that is positioned at the geometric center of the cavity. This is achieved by a two step type incremental technique. In the first step the resin is placed in the cylindrical cavity with a metal pin embedded in the middle of the composite restoration. After polymerization, the metal pin is removed and the cylindrical hole is filled with the second layer of composite. Finally, the second layer in the center of the composite restoration is polymerized. RESULTS: This study confirmed that the proposed incremental type placement technique reduces marginal debonding. SIGNIFICANCE: The main hypothesis is that the elimination of a stress singular point at the center of the restoration results in the reduction of stresses at tooth-composite interface and therefore improve the marginal adaptation (reduces length of the contraction gap at tooth-composite interface).