Towards a better spatial quantification of nitrogen deposition: A case study for Czech forests.

The quantification of atmospheric deposition flux is essential for assessment of its impact on ecosystems. We present an advanced approach for the estimation of the spatial pattern of atmospheric nitrogen deposition flux over the Czech forests, collating all available measured data and model results. The aim of the presented study is to provide an improved, more complete, more reliable and more realistic estimate of the spatial pattern of nitrogen deposition flux over one country. This has so far usually been based on measurements of ambient NOx concentrations as dry deposition proxy, and [Formula: see text] and [Formula: see text] in precipitation as wet deposition proxy. For estimation of unmeasured species contributing to dry deposition, we used the CAMx Eulerian photochemical dispersion model, coupled with the Aladin regional numeric weather prediction model. The contribution of fog and dissolved organic nitrogen was estimated using a geostatistical data driven model. We prepared individual maps for particular components applying the most relevant approach and then merged all layers to obtain a final map representing the best estimate of nitrogen deposition over the Czech Republic. Final maps accounting for unmeasured species clearly indicate that the approach used so far may result in a substantial underestimation of nitrogen deposition flux. Our results showed that nitrogen deposition over the Czech forested area in 2008 was well above 2 g N m(-2) yr(-1), with almost 70% of forested area receiving 3-4 g N m(-2) yr(-1). NH3 and gaseous HNO3, contributing about 80%, dominated the dry nitrogen deposition. Estimating the unmeasured nitrogen species by modeled values provides realistic approximations of total nitrogen deposition that also result in more realistic spatial patterns that could be used as input for further studies of likely nitrogen impacts on ecosystems.

Spatial and temporal trends of ozone distribution in the Jizerské hory Mountains of the Czech Republic.

We present results of the 5-year monitoring of ambient O3 concentrations in a Central European medium altitude mountain forested area. O3 levels were measured at 11 sites between 714 and 1000 m a.s.l. in 2006-2010 vegetation seasons using Ogawa diffusive samplers. Our results reveal that O3 exposure in the Jizerské hory Mts. was relatively high and comparable with polluted sites in Southern Europe and in higher altitudes. O3 concentrations differed significantly between individual sites and in individual years. O3 concentrations showed clear dependence on altitude at sites with similar aspect. Its gradient for the entire 5-year period under review equaled 3.5 ppb/100 m of altitude, ranging between nearly 5 ppb/100 m of altitude in 2006 and nearly 3 ppb/100 m of altitude in 2010. O3 concentrations at the site with northern aspect were consistently significantly lower than at the site at similar altitude with southern aspect. O3 concentrations measured at the forest edge were consistently lower than those measured at the same site but at the forest clearing. It is evident that the macro-setting of the O3 monitoring site is crucial for obtaining reliable results with high representativeness for the area.