Scaling Law for the Onset of Solidification at Extreme Undercooling.

Quasi-isentropic compression enables one to study the solidification of metastable liquid states that are inaccessible through other experimental means. The onset of this nonequilibrium solidification is known to depend on the compression rate and material-specific factors, but this complex interdependence has not been well characterized. In this study, we use a combination of experiments, theory, and computational simulations to derive a general scaling law that quantifies this dependence. One of its applications is a novel means to elucidate melt temperatures at high pressures.

Model for the Solid-Liquid Interfacial Free Energy at High Pressures.

The free energy involved in the formation of an interface between two phases (e.g., a solid-liquid interface) is referred to as the interfacial free energy. For the case of solidification, the interfacial free energy dictates the height of the energy barrier required to nucleate stable clusters of the newly forming solid phase and is essential for producing an accurate solidification kinetics model using classical nucleation theory (CNT)-based methods. While various methods have been proposed for modeling the interfacial free energy for solid-liquid interfaces in prior literature, many of these formulations involve making restrictive assumptions or approximations, such as the system being at or near equilibrium (i.e., the system temperature is approximately equal to the melt temperature) or that the system is at pressures close to atmospheric. However, these approximations and assumptions may break down in highly non-equilibrium situations, such as in dynamic-compression experiments where metastable liquids that are undercooled by hundreds of kelvin or overpressurized by several gigapascals or more are formed before eventually solidifying. We derive a solid-liquid interfacial free-energy model for such high-pressure conditions by considering the enthalpies of interactions between pairs of atoms or molecules. We also consider the contribution of interface roughness (disordering) by incorporating a multilayer interface model known as the Temkin n-layer model. Our formulation is applicable to a diverse variety of materials, and we demonstrate it by developing models specifically for two different materials: water and gallium. We apply our interfacial free-energy formulation to CNT-based kinetics simulations of several suites of dynamic-compression experiments that cause liquid water to solidify to the high-pressure solid polymorph ice VII and have found good agreement to the observed kinetics with only minor empirical fitting.