Advanced Carbon-Nickel Sulfide Hybrid Nanostructures: Extending the Limits of Battery-Type Electrodes for Redox-Based Supercapacitor Applications.

Transition-metal sulfides combined with conductive carbon nanostructures are considered promising electrode materials for redox-based supercapacitors due to their high specific capacity. However, the low rate capability of these electrodes, still considered "battery-type" electrodes, presents an obstacle for general use. In this work, we demonstrate a successful and fast fabrication process of metal sulfide-carbon nanostructures ideal for charge-storage electrodes with ultra-high capacity and outstanding rate capability. The novel hybrid binder-free electrode material consists of a vertically aligned carbon nanotube (VCN), terminated by a nanosized single-crystal metallic Ni grain; Ni is covered by a nickel nitride (Ni3N) interlayer and topped by trinickel disulfide (Ni3S2, heazlewoodite). Thus, the electrode is formed by a Ni3S2/Ni3N/Ni@NVCN architecture with a unique broccoli-like morphology. Electrochemical measurements show that these hybrid binder-free electrodes exhibit one of the best electrochemical performances compared to the other reported Ni3S2-based electrodes, evidencing an ultra-high specific capacity (856.3 C g-1 at 3 A g-1), outstanding rate capability (77.2% retention at 13 A g-1), and excellent cycling stability (83% retention after 4000 cycles at 13 A g-1). The remarkable electrochemical performance of the binder-free Ni3S2/Ni3N/Ni@NVCN electrodes is a significant step forward, improving rate capability and capacity for redox-based supercapacitor applications.

Antimicrobial Efficiency and Surface Interactions of Quaternary Ammonium Compound Absorbed on Dielectric Barrier Discharge (DBD) Plasma Treated Fiber-Based Wiping Materials.

The physicochemical interactions between alkyldimethylbenzylammonium chloride (ADBAC) as disinfectant and three commercial wiping materials made from 100% polyester (PET), 55%cellulose/45%PET (blend), and 100% cellulose were investigated after treatment with dielectric barrier discharge (DBD) plasma at atmospheric pressure. Wipe material type in terms of cellulose content, liquor ratio, and immersion time demonstrated a significant influence on the adsorption of ADBAC. The higher the content of cellulose in the material, the higher is the adsorption of ADBAC active ingredient. The antimicrobial tests confirm that the ADBAC adsorbed on pure cellulosic material is inactivated losing its bactericidal activity, while 100% PET and blend wipes showed good antimicrobial efficacy. XPS analysis demonstrates the strong interactions of ADBAC with the plasma-generated oxygen species in the polyester-containing wipes surface. Unexpectedly, plasma-treated blend wipe displays a reverse antimicrobial effect compared to untreated samples, performing better in Gram-negative bacteria. The best result was obtained in the plasma treated 100% polyester wipe showing an improvement of about 20% in Gram-positive bacteria and an excellent performance in Gram-negative ones. This method allows the unprecedented use of pure polyester as effective wiping material for surface disinfection eliminating the major drawback of pure polyester, its high hydrophobicity.

Chemical, Thermo-Mechanical and Antimicrobial Properties of DBD Plasma Treated Disinfectant-Impregnated Wipes during Storage.

Disinfectant-impregnated wipes are broadly used in hospitals, as an important approach for infection prevention and control. But their ageing performance has rarely been studied. Untreated and Dielectric Barrier Discharge (DBD) plasma pre-treated wiping materials made of nonwoven 100% polyester (W1), nonwoven 55% cellulose/45% polyester (W2) and woven cotton (W3) were impregnated with a quaternary ammonium compound solution (ADBAC) for 30 min, 3, 7, 15, and 30 days of storage time and characterized in term of chemical, thermo-mechanical and antimicrobial efficacy. X-ray photoelectron spectroscopy analysis on the plasma-treated polyester wipes demonstrates the incorporation of reactive oxygen species on the fiber surface. Laser scanning microscopy demonstrates the plasma etching effect in smoothing the surface of the cotton wipe reducing the adsorption of ADBAC. The result showed no significant changes in breaking force and elongation during storage for W1 and W2. However, plasma treatment affects W3 in weft direction reducing the force at break in water and ADBAC treated wipes. Dynamic mechanical analysis results show that ADBAC and plasma treatment have a significant influence in W1 and W3 viscoelastic properties improving the elastic response limiting the polymeric chains mobility and the non-elastic response due to the etching effect, respectively. Overall, the plasma pre-treatment of ADBAC-impregnated wipes is able to enhance the antimicrobial performance and the storage time of polyester-containing wipes.