1.
ACS Omega
; 6(22): 14030-14048, 2021 Jun 08.
Artigo
em Inglês
| MEDLINE
| ID: mdl-34124427
RESUMO
Noncatalyzed, regio- and stereoselective hypochlorite oxidation of 3-aminothieno[2,3-b]pyridine-2-carboxamides is presented. Unexpectedly, the oxidation proceeded by different mechanistic pathways, and different products were formed, depending on the nature of solvents used. A possible mechanism, the structure of products, kinetics and dynamics of intramolecular processes, and biological activity of products are discussed.
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