Strong Intervalley Scattering-Induced Renormalization of Electronic and Thermal Transport Properties and Selection Rule Analysis in 2D Tellurium.

The electron-phonon interaction (EPI) and phonon-phonon interactions are ubiquitous in promising two-dimensional (2D) semiconductors, determining both electronic and thermal transport properties. In this work, based on ab initio calculations, the effects of intervalley scattering on EPI and higher-order four-phonon interactions of α-Te and ß-Te are investigated. Through the proposed selection rules for scattering channels and calculations of full electron-phonon scattering rates, we demonstrate that multiple nearly degenerate local valleys/peaks produce more scattering channels, resulting in stronger intervalley scattering over intravalley scattering. The lattice thermal conductivities of α-Te and ß-Te are decreased by as much as 10.9% and 30.8% by considering EPI under the carrier concentration of 2 × 1013 cm-2 (n-type) at 300 K compared to those limited by three-phonon scattering, respectively. However, when further considering four-phonon scattering, EPI reduces the lattice thermal conductivities by 2.6% and 19.4% for α-Te and ß-Te, respectively. Furthermore, it is revealed that the four-phonon interaction is more dominant in phonon transport for α-Te than that for ß-Te due to the presence of an acoustic-optical phonon gap in α-Te. Finally, we demonstrate strong intervalley scattering induces significant renormalization effects from EPI on all the constituent parameters of thermoelectric performance. Our results show the contributions of intervalley scattering to the electronic properties as well as thermal transport properties in band-convergent thermoelectric materials are essential and highlight the potential of monolayer tellurium as a promising candidate for advanced thermoelectric applications.

Spin-Orbit-Coupling-Induced Topological Transition and Anomalously Strong Intervalley Scattering in Two-Dimensional Bismuth Allotropes with Enhanced Thermoelectric Performances.

The convergence of multivalley bands is originally believed to be beneficial for thermoelectric performance by enhancing the charge conductivity while preserving the Seebeck coefficients, based on the assumption that electron interband or intervalley scattering effects are totally negligible. In this work, we demonstrate that ß-Bi with a buckled honeycomb structure experiences a topological transition from a normal insulator to a Z2 topological insulator induced by spin-orbit coupling, which subsequently increases the band degeneracy and is probably beneficial for enhancement of the thermoelectric power factor for holes. Therefore, strong intervalley scattering can be observed in both band-convergent ß- and aw-Bi monolayers. Compared to ß-Bi, aw-Bi with a puckered black-phosphorus-like structure possesses high carrier mobilities with 318 cm2/(V s) for electrons and 568 cm2/(V s) for holes at room temperature. We also unveil extraordinarily strong fourth phonon-phonon interactions in these bismuth monolayers, significantly reducing their lattice thermal conductivities at room temperature, which is generally anomalous in conventional semiconductors. Finally, a high thermoelectric figure of merit (zT) can be achieved in both bismuth monolayers, especially for aw-Bi with an n-type zT value of 2.2 at room temperature. Our results suggest that strong fourth phonon-phonon interactions are crucial to a high thermoelectric performance in these materials, and two-dimensional bismuth is probably a promising thermoelectric material due to its enhanced band convergence induced by the topological transition.

Laser cooling by over 7†K in Yb-doped ZBLAN fibers with high-power pumping at atmospheric pressure.

Anti-Stokes fluorescence (ASF) cooling has been demonstrated to be a viable method for balancing the waste heat produced in gain materials. In addition, radiation-balanced fiber lasers and amplifiers at atmospheric pressure have recently been developed. Here, we evaluate the cooling characteristics in a long section of a Yb-doped ZBLAN fiber with high pump power. The fiber has a 200-µm-diameter core and is doped with 3 wt. % Yb3+. As indicated by a thermal camera, cooling by over 7 K below ambient temperature was achieved by core pumping at 1030 nm. The temperature drop distribution at multiple measurement points in the fiber was evaluated with a maximum pump power of tens of watts. The results demonstrate the excellent ASF cooling performance of Yb-doped ZBLAN fibers. This study has great significance for the development of high-power radiation-balanced fiber lasers.

Low coherence laser pulse amplification theory for rare earth ions doped glass medium.

A new theory for the low coherence laser amplification in rare ions doped glass has been proposed. Based on one-dimensional continuous energy level assumption and independent response assumption, the theory can describe the amplification of low coherence laser pulses with any time scale and any bandwidth. By the new theory, McCumber formula can be obtained, and a complete low coherence optical pulse amplification model in neodymium glass is established. Computation shows that at high fluences, inhomogeneous broadening will severely limit energy extraction of narrowband high coherence laser, therefore the extraction of broadband low coherence laser will exceed that of narrowband high coherence laser. In addition, the portion of long-wave of the output spectrum is slightly larger than that predicted by the homogeneous model. The new theory could be beneficial for the studies of low coherence pulse amplification in rare earth doped medium and other laser mediums.

Fast time-evolving random polarization beam smoothing for laser-driven inertial confinement fusion.

We propose a random polarization smoothing method for low-coherence laser to obtain focal spot with random polarization that evolves rapidly in sub-picosecond timescales. Random polarization smoothing is realized by a half-aperture wave plate with sufficient thickness. The degree of polarization and polarization evolution of the focal spot are studied theoretically. The calculation results show that random polarization smoothing can make the polarization of focal spot evolve rapidly and randomly in time and space. Experimentally, the polarization of the focal spot of low-coherence laser with random polarization smoothing is measured by a single-shot polarimeter. The measurement results show that the degree of polarization of the focal spot is reduced to 0.22 on average, which proves the effectiveness of random polarization smoothing. The random polarization smoothing technique on low-coherence laser is expected to reduce the laser plasmas instability through its multi-dimensional random evolution properties.

Full-aperture random polarization smoothing for a low-coherence laser facility.

Two new random polarization smoothing methods using full-aperture elements are proposed on low-coherence lasers, one using birefringent wedge and one using flat birefringent plate. By designing the crystal axis direction and wedge angle of the birefringent plates, the methods can selectively introduce time delay and spatial displacement, so as to obtain fast random evolution of transient polarization by utilizing low spatiotemporal coherence of the laser focal field. Both methods avoid the near field discontinuity and can be used under high fluence. The method using birefringent wedge can slightly improve focal spot uniformity, and the method using flat birefringent plate can obtain non-polarization with DOP lower than 2%. Theoretical studies show that the resulting focal polarization evolves rapidly on sub-picosecond timescales and rapidly covers the entire Poincaré sphere. The method using birefringent wedge is achieved in experiment. The results show that the degree of polarization of the focal spot is reduced from 1 to 0.27, which proves the effectiveness of the full-aperture random polarization smoothing. The full-aperture random polarization smoothing can generate a focal field very close to unpolarized thermal light, which is expected to suppress the laser plasmas instability.

Electro-optic high-speed optical beam shifting based on a lithium niobate tapered waveguide.

We propose an electro-optic on-chip beam shifting device based on gradient microstructured electrodes and an optical tapered waveguide fabricated using lithium niobate (LN). The distribution of refractive index variations of the optical waveguide can be electro-optically defined and tailored by the designed gradient microstructured electrodes, which directs the beam propagation and shifting. The length of the beam shifting device is 18 mm and the width of the waveguide is gradually increased from 8 µm to 80 µm. The functionality of the beam shifting device is experimentally demonstrated, and it is observed that it has an electro-optic tunability of 0.41 µm/V, and a high-speed response time of 19 ns (λ=1310 nm). This study can provide potential applications in optical switching and modulation, beam scanning and ranging, optical spatial communications, etc.

High-power, low-coherence laser driver facility.

We report the first (to the best of our knowledge) high-power, low-coherence Nd:glass laser delivering kilojoule pulses with a coherent time of 249 fs and a bandwidth of 13 nm, achieving the 63%-efficiency second-harmonic conversion of the large-aperture low-coherence pulse and good beam smoothing effect. It provides a new type of laser driver for laser plasma interaction and high energy density physics research.

Experiment and theory of beam smoothing using induced spatial incoherence with a lens array.

The smoothing effect of induced spatial incoherence combined with a lens array on a large-bandwidth and short-coherence-time laser is reported. A theoretical model based on statistical optics is developed to describe the spatial and temporal characteristics of the focal spot. Theoretical simulation is consistent with the experimental results. A method was proposed to remove or reduce the residual interference fringes of the experimental focal spot, and both the simulation and analysis show that this method does not affect the smoothing speed of the focal spot.

High-efficiency second-harmonic generation of low-temporal-coherent light pulse.

The nonlinear frequency conversion of low-temporal-coherent light holds a variety of applications and has attracted considerable interest. However, its physical mechanism remains relatively unexplored, and the conversion efficiency and bandwidth are extremely insufficient. Here, considering the instantaneous broadband characteristics, we establish a model of second-harmonic generation (SHG) of a low-temporal-coherent pulse and reveal its differences from the coherent conditions. It is found that the second-harmonic spectrum distribution is proportional to the self-convolution of that of a fundamental wave. Because of this, we propose a method for realizing low-temporal-coherent SHG with high efficiency and broad bandwidth, and experimentally demonstrate a conversion efficiency up to 70% with a bandwidth of 3.1 THz (2.9 nm centered at 528 nm). To the best of our knowledge, this is the highest efficiency and broadest bandwidth of low-temporal-coherent SHG to date. Our research opens the door for the study of low-coherent nonlinear optical processes.

50 mm-aperture Nd:LuAG ceramic nanosecond laser amplifier producing 10 J at 10 Hz.

The growth and laser amplifier performance of a large-aperture Nd:LuAG ceramic are reported. Using the vacuum sintering and high-temperature insostatic pressing (HIP) methods, three pieces of a 50 mm-aperture Nd:LuAG ceramic are fabricated and used as the gain medium in a diode-pumped nanosecond distributed active mirror amplifier chain (DAMAC). The energy storage capacity of large-aperture Nd:LuAG is investigated and compared with that of Nd:YAG. Energy amplification up to 10.3 J at 10 Hz is achieved, which, to the best of our knowledge, produces the highest peak power (1 GW) using Nd:LuAG. The excellent energy storage and extraction performance confirm the great potential of Nd:LuAG in high-energy scaling.

Electro-optic deflection in a lithium niobate quasi-single mode waveguide with microstructured electrodes.

We propose an electro-optic mode deflection device based on an annealed proton exchange (APE) waveguide in lithium niobate, associated with isosceles-triangle-shaped array electrodes and a horn-shaped input waveguide. The input waveguide is tapered down to ensure that the output of the device has a good beam quality, i.e., a quasi-single mode in this case. This new device allows beam deflection at a relative low voltage and large deflection angle. At an APE-waveguide width of 80 µm, mode deflections of 0.265 and 0.240 µm/V are obtained for 1064 and 980 nm, respectively. This beam deflection device can be applied in high-speed optical switch, and beam smoothing of a high-power laser, etc.

Ultrafast smoothing scheme for improving illumination uniformities of laser quads.

The beam smoothing technology, smoothing by spectral dispersion, plays an important role in improving the illumination uniformities of the lasers in inertial confinement fusion facilities. However, due to the limitations of the modulation frequency of the electro-optic modulator, the uniformity of the lasers approaches an asymptotic value after tens of picoseconds that are much longer than the response time of laser plasma instabilities. To the best of our knowledge, this is the first time that an ultrafast smoothing approach for improving the uniformity of a laser quad in both radial and azimuthal directions in the picosecond scale was proposed. Among the four individual beams in a quad, two of them were smoothed by independent ultrafast focal zooming, and the rest were transformed into Laguerre-Gaussian (LG) beams that carry same topological charges with opposite signs. The focal spots of these two LG beams were coherent superposed, and their intensity distributions rotated rapidly in a period of several picoseconds. As a result of the focal zooming and rotation, an ultrafast and significant improvement of the uniformity of a laser quad was achieved.

12 J, 10 Hz diode-pumped Nd:YAG distributed active mirror amplifier chain with ASE suppression.

Experimental amplification of 10-ns pulses to an energy of 12.2 J at the repetition rate of 1-10 Hz is reported from a diode-pumped room-temperature distributed active mirror amplifier chain (DAMAC) based on Nd:YAG slabs. Efficient power scaling at the optical-optical efficiency of 20.6% was achieved by suppressing the transverse parasitic oscillation with ASE absorbers. To the best of our knowledge, this is the first demonstration of a diode-pumped Nd:YAG active-mirror laser with nanosecond pulse energy beyond 10 joules. The verified DAMAC concept holds the promise of scaling the energy to a 50 J level and higher by adding 10-12 more pieces of active mirror in the chain.

Optimal coating solution for a compact resonating cavity working at Brewster angle.

In a compact Nd:Glass resonator, the laser that enters the gain medium at Brewster angle can work either for P-polarization or S-polarization, in which polarization the optical coatings possess higher laser-induced damage threshold (LIDT) was investigated. For the P-polarized configuration, only one high reflection (HR) coating on the rear surface of the Nd:Glass substrate is needed, and the laser-induced damage occurred near the substrate-coating interface at a fluence of 10 ± 2 J/cm2 (1064nm 10ns). Although S-polarized configuration needs two coatings, one HR coating and one anti-reflection (AR) coating on the rear and front surface of the Nd:Glass substrate respectively, its overall LIDT was about 1.8 times higher than that of the P-polarized configuration. The laser-induced damage occurred at the interface between the S-polarized AR coating and the Nd:Glass substrate. The observed interfacial damage behaviors were interpreted using a phenomenological model that took the nano-sized absorbers, electric-field intensity (EFI) distribution and coating thickness into consideration.

Efficient sub-joule energy extraction from a diode-pumped Nd:LuAG amplifier seeded by a Nd:YAG laser.

We report on a joule-level diode-pumped Nd:YAG-Nd:LuAG hybrid active mirror amplifier chain, producing an output energy of 1.52 J at 10 Hz in a 10 ns Q-switched pulse, while a pulse energy of 623 mJ is extracted from the Nd:LuAG stage, corresponding to an optical-to-optical efficiency of 21.7%. To the best of our knowledge, this is the first demonstration of high-energy nanosecond pulse amplification in a Nd:LuAG laser with extracted pulse energies approaching the joule level. The excellent scaling performance confirms Nd:LuAG as a very promising gain medium for high-energy, short-pulse lasers.

[A spectral scanning filtering method for improving the SNR of chirped pulse based on the photorefractive effect].

Based on the principle of spectral scanning filtering method, a new scanning filtering method for improving signal-to-noise ratio (SNR) of the chirped pulse by using the photorefractive effect was proposed and theoretically analyzed. For the scanning filtering implement of Fabry-Perot (F-P) etalon with a built-in photorefractive crystal, the transmittance spectral characteristics of the scanning filter were analyzed quantitatively. Furthermore, the effects of the reflectivity of the parallel-plates of Fabry-Perot etalon, the bandwidth of the transmittance spectral window, the variation of the controlling parameters of the applied field and the variation of the chirped rate to the photorefractive crystal on the SNR improvement and the overall transmittance were discussed in details. The results show that the higher the reflectivity of the F-P parallel-plates is, the transmittance spectral is sharper and the transmittance window is narrower, resulting in the better filtering effect. In order to ensure the efficient SNR improvement, the reflectivity of the F-P parallel-plates should be higher than 0. 99. The control of the applied field exhibits significant impact on the scanning filtering. In practical applications, the applied field and chirped rate should be controlled precisely in order to ensure the synchronous matching between the signal pulse and the filtering function. For the chirped signal pulse with the central wavelength 800 nm, the SNR improvement of about 3 orders of magnitude can be obtained via filtering out the amplified spontaneous emission (ASE) random noise and pre-pulse by the use of the spectral scanning filtering method proposed in this paper.

Design of ultrahigh energy laser amplifier system with high storage energy extraction.

A design concept of realizing high storage energy extraction efficiency is presented for an ultrahigh energy laser system, stressing the advantage of variable-diameter aperture structure for the multistage amplifier system over the constant-aperture design. Based on the established modeling, the conceptual schematic of an amplifier system with optimized high storage energy extraction is developed, which is expected to produce 15 kJ output energy from three stages, with an extremely high storage extraction efficiency of 50.3%.

Optimal design of ultrahigh-energy laser amplifier chain with high storage energy extraction.

This paper presents the concept of constant-fluence amplification. It refers to the fact that laser fluence anywhere in the amplifier gain medium is identical to the design fluence E(design), which represents the maximum allowed fluence in consideration of the laser-induced damage threshold (LIDT). Based on this concept, we explore ideal amplifier model (IAM) and near-ideal amplifier chain (NIAC) and propose an optimal NIAC design method and analytically offer an indicator of the extraction efficiency. Finally, the paper discusses the influences of losses on the NIAC's extraction efficiency.

All-fiber mode-locked nanosecond laser employing intracavity chirped fiber gratings.

We demonstrate that nanosecond pulses are generated directly from an all-fiber mode-locked ytterbium-doped fiber laser. A pair of Chirped Fiber Gratings (CFGs) with different sign of dispersion is employed for intracavity dispersion management. Self-starting stabilized mode-locking operation is achieved by nonlinear polarization evolution (NPE). The 1.27 ns pulses are obtained after one CFG with large positive dispersion. The pulse energy is up to 15 nJ at a repetition rate of 3.48 MHz.