[Raman spectra analysis of Nd : YAG single crystal and its nano-powder].

In the present paper, the authors measured the Raman spectra of YAG/Nd : YAG single crystal, Nd : YAG precursor and the powder sintered at different temperatures. The bands of these Raman spectra were assigned and analyzed. The results show that there is a structure transformation process in the course of sintering Nd : YAG precursor. The powder sintered at 700 degrees C was amorphous and it is of AlO4 tetrahedron structure. With the increase in sintering temperatures, the Raman spectra varied mainly in two respects. One is the decrease in FWHM with the increase in the bands intensity; the other is the bands shift. These should be due to the increase in the order degree of the interface component. Additionally, the difference in the lattice vibration modes between the powders sintered at 800 degrees C and the Nd : YAG single crystal powder was caused by the contribution of the interface component.

[Calculation of spectroscopic parameters of highly doped Er3+ in lithium niobate].

A highly doped Er3+: LiNbO3 (concentration 6 mol%) crystal was grown successfully by Czochralski method. The crystal is higher than that of the lowly doped Er3+ in LiNbO3 crystal, which is helpful to improve absorption coefficient of the grown the pumping efficiency. The absorption spectra at two unpolarized directions (X and Z) and two polarized directions (E parallel Z, E perpendicular Z) were measured. Using the Judd-Ofelt theory, and according to the measured absorption spectra, the intensity parameters omegalambda of Er3+ were fitted. The results of root-mean square (r. m. s) deviation show that the error of polarized fitting is less than that of unpolarized one. Thus fluorescence transition probabilities (Ajj), radioactive lifetime (tau), fluorescence branching ratio (beta), and integrated emission cross section (sigmap) were calculated and accepted according to the polarized results, and were also discussed and compared with the ones reported in the literature.

[Crystal growth and spectral parameter computation of Yb:YAG].

In this article, a good-quality crystal Yb:YAG was grown by pull method, and its absorption spectrum of 200-3000 nm was measured at room temperature. Its absorption of 200-300 nm is from the host YAG, and there exists only the characteristic absorption of Yb3+ in the range of 390-3000 nm. Judd-Ofelt theory computation indicates that the absorption and emission oscillator strengths of electric dipole of (24 at%) Yb:YAG are 3.58 x 10(-6) and 4.77 x 10(-6), respectively, and the absorption and emission transition probabilities are 879 and 1171/s respectively. As for magnetic dipole, the absorption and emission oscillator strengths are 3.32 x 10(-7) and 4.43 x 10(-7) respectively, and the absorption and emission transition probabilities are 82 and 109/s respectively. The lifetime of the energy level2 F(5/2) is 781 micros.