Biochar-seeded struvite precipitation for simultaneous nutrient recovery and chemical oxygen demand removal in leachate: From laboratory to pilot scale.

Refuse transfer station (RTS) leachate treatment call for efficient methods to increase nutrient recovery (NH4 +-N and PO4 3--P) and chemical oxygen demand (COD) removal. In this study, the effects of various operational factors (seeding dose, pH, initial NH4 +-N concentration, and reaction time) on biochar-seeded struvite precipitation were investigated at laboratory and pilot scales. Mealworm frass biochar (MFB) and corn stover biochar (CSB) were used as seeding materials to compare with traditional seed struvite. The maximum NH4 +-N and PO4 3--P recover efficiency of the MFB-seeded process reached 85.4 and 97.5%, higher than non-seeded (78.5 and 88.0%) and CSB-seeded (80.5 and 92.0%) processes and close to the struvite-seeded (84.5 and 95.1%) process. The MFB-seeded process also exhibited higher COD removal capacity (46.4%) compared to CSB-seeded (35.9%) and struvite-seeded (31.2%) processes and increased the average particle size of the struvite product from 33.7 to 70.2 µm for better sustained release. XRD, FT-IR, and SEM confirmed the orthorhombic crystal structure with organic matter attached to the struvite product. A pilot-scale test was further carried out in a custom-designed stirred tank reactor (20 L). In the pilot-scale test, the MFB-seeded process still spectacularly recovered 77.9% of NH4 +-N and 96.1% of PO4 3--P with 42.1% COD removal, which was slightly lower than the laboratory test due to insufficient and uniform agitation. On the whole, MFB-seeded struvite precipitation is considered to be a promising pretreatment method for rural RTS leachate.

Cobalt doped iron oxychloride as efficient heterogeneous Fenton catalyst for degradation of paracetamol and phenacetin.

Cobalt doped iron oxychloride (Co-FeOCl) was synthesized and employed as catalyst in Fenton degradation of paracetamol (APAP) and phenacetin (PNCT) for the first time. The catalytic performance was evaluated by means of various parameters including catalyst load, hydrogen peroxide (H2O2) dose and pH value. The high removal of APAP (87.5%) and PNCT (76.0%) was obtained under conditions of 0.2 g/L Co-FeOCl and 0.5 mM H2O2 at pH 7.0, with calculated pseudo-first order kinetic constants of 0.031 min-1 for APAP and 0.023 min-1 for PNCT. Particularly, quenching tests and in situ electron spin resonance (ESR) tests were employed for the identification of the reactive oxygen species (ROS) in system. Hydroxyl radical (·OH) and superoxide radical (O2-·) were the primary ROS in Co-FeOCl/H2O2 system. A possible mechanism for H2O2 activation by Co-FeOCl catalyst was proposed as well. Finally, the formation of typical disinfection by-products (DBPs) decreased slightly in Co-FeOCl/H2O2 pre-oxidation. However, stability and reusability of Co-FeOCl were deactivated in the consecutive three cycles.