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1.
Heliyon ; 10(2): e23986, 2024 Jan 30.
Artigo em Inglês | MEDLINE | ID: mdl-38293359

RESUMO

The rising need for energy to actively heat and cool human-made structures is contributing to the growing energy crisis and intensifying global warming. Consequently, there's a pressing need for a sustainable approach to temperature management that minimizes energy consumption and carbon emissions. The substantial temperature differences between the Sun (approximately 5800 K), Earth (around 300 K), and outer space (about 3 K) offer a unique opportunity for passive thermal regulation on a global scale. Recent research indicates the possibility of addressing this issue through various low-carbon, passive technologies such as solar heating and radiative cooling. However, their practical application is often limited to certain seasons and climatic regions due to their static and single-function nature in managing temperature. In this context, we introduce a concept of phase-change metamaterials that provide passive, dynamic, and adjustable radiative thermal control, suitable for widespread engineering applications. Our designed metafilm comprises a Polydimethylsiloxane (PDMS) layer infused with vanadium dioxide (VO2) nanoparticles, backed by a layer of broadband-reflective silver (Ag). This metafilm exhibits a self-adjusting solar absorptance, shifting from 0.96 to 0.25 at a pivotal temperature while maintaining a nearly constant thermal emittance. We can finely tune the metafilm's optical characteristics by altering the VO2 nanoparticle concentration and PDMS layer thickness. To demonstrate its efficacy in solar thermal management and radiative cooling, we simulate its temperature behavior under various weather conditions.

2.
Biotechnol Biofuels Bioprod ; 16(1): 97, 2023 Jun 08.
Artigo em Inglês | MEDLINE | ID: mdl-37291654

RESUMO

BACKGROUND: Lignin played an important role in the establishment of coated fertilizers coating material as a substitute for petrochemical raw materials. However, so far, the lignin-based coated fertilizers was limited in only the poor slow-release performance. To achieve good slow-release performance of lignin-based coated fertilizers, hydrophilic of lignin need to be resolved to establish an green and better controllable lignin-based coated fertilizers. RESULTS: In the study, a novel green double layer coating with lignin-based polyurethane (LPU) as the inner coating and epoxy resin (EP) as the outer coating was effectively constructed for coated urea. Fourier transform infrared spectra confirmed that lignin and polycaprolactone diol successfully reacted with Hexamethylene diisocyanate. The loss weight and water contact angle (WCA, 75.6-63.6°) of the LPUs decreased with the increased lignin content. The average particle hardness of the lignin-based double-layer coated urea (LDCU) first increased from 58.1 N (lignin of 30%) to 67.0 N (lignin of 60%), but then decreased to 62.3 N (lignin of 70%). The release longevity of the coated urea was closely related to the preparation parameters of the coating material. The optimal cumulative nutrient release rate (79.4%) of LDCU was obtained (lignin of 50%, -CNO/-OH molar ratios of 1.15, EP of 35%, and coating ratio of 5%). The aggregates of hydrone on the LDCU caused the dissolution and swelling of nutrients, and then the diffusion of nutrients through the concentration gradient. CONCLUSIONS: A though the nutrient release of the LDCUs was affected by many factors, the successful development of the LDCUs will help improve the rapid development of the coated fertilizer industry.

3.
Tour Manag ; 98: 104759, 2023 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-37035094

RESUMO

The coronavirus disease (COVID-19) pandemic has already caused enormous damage to the global economy and various industries worldwide, especially the tourism industry. In the post-pandemic era, accurate tourism demand recovery forecasting is a vital requirement for a thriving tourism industry. Therefore, this study mainly focuses on forecasting tourist arrivals from mainland China to Hong Kong. A new direction in tourism demand recovery forecasting employs multi-source heterogeneous data comprising economy-related variables, search query data, and online news data to motivate the tourism destination forecasting system. The experimental results confirm that incorporating multi-source heterogeneous data can substantially strengthen the forecasting accuracy. Specifically, mixed data sampling (MIDAS) models with different data frequencies outperformed the benchmark models.

4.
Sci Total Environ ; 873: 162334, 2023 May 15.
Artigo em Inglês | MEDLINE | ID: mdl-36813204

RESUMO

Aminated lignin (AL) was prepared and first applied to remediation of cadmium (Cd) pollution in soil. Meanwhile, the nitrogen mineralization characteristics of AL in soil and its effect on soil physicochemical properties were elucidated by soil incubation experiment. The results showed that the Cd availability was dramatically lowered in soil by adding the AL. The DTPA-extractable Cd content of AL treatments was considerably reduced by 40.7-71.4 %. The soil pH (5.77-7.01) and absolute value of zeta potential (30.7-34.7 mV) enhanced simultaneously as the AL additions increased. The content of soil organic matter (SOM) (99.0-264.0 %) and total nitrogen (95.9-301.3 %) were gradually enhanced due to high C (63.31 %) and N (9.69 %) content in AL. Moreover, AL significantly elevated the content of mineral nitrogen (77.2-142.4 %) and available nitrogen (95.5-301.7 %). The first-order kinetic equation of soil nitrogen mineralization revealed that AL greatly enhanced nitrogen mineralization potential (84.7-143.9 %) and reduced environmental pollution by lowering the loss of soil inorganic nitrogen. AL could effectively reduce the availability of Cd through direct (self-adsorption) and indirect effects (improvement of soil pH, SOM and reduction of soil zeta potential), thereby achieving passivation of Cd in soil. In short, this work will develop a novel approach and technical support for soil heavy metal remediation, which is of great significance for improving the sustainable development of agricultural production.

5.
Int J Biol Macromol ; 231: 123334, 2023 Mar 15.
Artigo em Inglês | MEDLINE | ID: mdl-36682667

RESUMO

An advanced hydrophobic lignin-based polyurethane coated urea (HLPCU) was successfully developed by synergy of carbon black (CB) and polysiloxane. In this work, CB and polysiloxane were employed to modify the liquefied lignin-based polyurethane (LLPU) and improve it's the hydrophobicity. The effects of polysiloxane contents and coating rates on the nutrient release of HLPCU were thoroughly investigated. The lignin was degraded into polyol with a low molecular weight. FT-IR, XPS and EDX results confirmed that polysiloxane was grafted to the LLPU. The water contact angle (WCA) of the HLPUs (89.39°-98.68°) gradually increased as the polysiloxane content rose (5 %-15 %). However, when the polysiloxane content further increased to 20 %, the WCA of the HLPUs rapidly declined (90.82°). A proper amount of polysiloxane molecules could increase thermo-physical properties of LLPU. The almost no pores were observed on the section micrograph of the HLPCU obtained by synergy of CB and polysiloxane. Synergy between CB and polysiloxane could significantly improve hydrophobicity and then enhance N release longevity of HLPCU (polysiloxane content of 15 %, coating rates of 7 %) up to 44 days. Compared to traditional urea, HLPCU could improve total N use efficiency the cabbage. The HLPCU and HLPCU85 treatments (15 % weight loss with fertilization) reduced the greenhouse effect of N2O, CO2 and CH4 and finally reduced GWP, especially for HLPCU85 treatment. This work will supply an advanced approach and process technology for progress of HLPCU and sustainable agriculture.


Assuntos
Gases de Efeito Estufa , Gases de Efeito Estufa/análise , Siloxanas , Fuligem , Lignina , Ureia/química , Poliuretanos , Espectroscopia de Infravermelho com Transformada de Fourier , Fertilizantes , Metano , Óxido Nitroso/análise , Agricultura/métodos , Solo , Dióxido de Carbono
6.
Int J Biol Macromol ; 221: 1130-1141, 2022 Nov 30.
Artigo em Inglês | MEDLINE | ID: mdl-36113589

RESUMO

Novel lignin/paraffin/epoxy resin composite coated urea (LPECCU) was successfully prepared. Paraffin and epoxy resin (ER) were used to improve the slow-release properties of the lignin-based polyurethane (LPU) coated urea. The relationships among the N release characteristics, liquid-solid rate, -CNO/-OH molar rate and film formation rate in the coating material of LPECCU were investigated. The results showed that the water contact angle (WCA) of the LPU-paraffin increased with the rate of liquid-solid rate (73.61-88.19°) and -CNO/-OH molar rate (65.17-82.24°) increased. The average particle hardness of LPECCU decreased with the increased of liquid-solid rate (57.10-66.80 N) and the reduced of -CNO/-OH molar rate (48.11-63.00 N). The LPECCU emerged compact micro-structure, low sustained release and high compressive resistance by adding paraffin and ER. The coating material of LPECCU appeared excellent biodegradability in the soil. The optimal N cumulative release rate (72.49 %) of LPECCU was obtained (liquid-solid rate of 1.43, -CNO/-OH molar rate of 2, and the film formation rate of 6.66 %). The lettuce growth study was conducted to further evaluate the pot application of the LPECCU. In comparison to conventional urea, LPECCU could improve the total dry matter accumulation and N use efficiency of the lettuce.


Assuntos
Nitrogênio , Ureia , Ureia/química , Nitrogênio/química , Lignina/química , Fertilizantes , Resinas Epóxi , Lactuca , Parafina , Resinas Compostas , Poliuretanos/química
7.
Environ Res ; 214(Pt 1): 113826, 2022 11.
Artigo em Inglês | MEDLINE | ID: mdl-35835169

RESUMO

Nitrogen reduction combined with organic fertilizer is of considerable significance for the sustainable development of agriculture. A pot experiment using nitrogen reduction combined with organic fertilizer was conducted to explore the effects of different treatments on matter accumulation, physiological resistance, and fertilizer nitrogen fate in banana seedlings. Compared with conventional fertilization, a 20% reduction of nitrogen did not affect the dry weight, chlorophyll content, physiological resistance, and fertilizer utilization rate of banana seedlings, but significantly reduced the nitrogen leaching loss and increased the nitrogen soil residue. Compared with conventional fertilization, organic nitrogen substituting 20% or 30% of the nitrogen reduced by 20% significantly promoted dry matter accumulation and physiological resistance. Organic nitrogen substituting 30% of the 20% reduction of nitrogen increased the dry matter of the whole plant by 24.94%, the nitrogen uptake in the root by 30.87%, the chlorophyll content by 6.05%, the soluble sugar content by 16.88%, Peroxidase (POD) activity by 26.35%, Catalase (CAT) activity by 27.48%, and Super Oxide Dismutase (SOD) activity by 22.97%. Compared with conventional fertilization, all organic substitution treatments significantly reduced fertilizer nitrogen leaching loss, apparent loss, and increased nitrogen soil residue. Compared with the 20% reduction of nitrogen, organic nitrogen substituting 30% of the 20% reduction of nitrogen significantly increased nitrogen utilization by 16.34% and soil residue rate by 13.26%, and reduced nitrogen leaching loss by 35.46%. The results of the present study revealed that a 20% reduction of nitrogen fertilizer with a 30% organic substitution application promoted matter accumulation, enhanced the physiological resistance of banana seedlings, increased the utilization and residue of nitrogen fertilizer, and reduced nitrogen pollution.


Assuntos
Fertilizantes , Musa , Agricultura , Clorofila , Nitrogênio , Plântula , Solo
8.
Arch Biochem Biophys ; 727: 109323, 2022 09 30.
Artigo em Inglês | MEDLINE | ID: mdl-35714697

RESUMO

The identification of new diagnostic and therapeutic biomarkers might be helpful to understand molecular mechanism of cancer pathogenesis and develop anti-cancer targets. This study reported the alteration of Sodium channel 1 subunit alpha (SCNN1A) expression, its prognostic significance and biological roles in pancreatic cancer. Bioinformatics database was searched to explore the expression of SCNN1A in pancreatic cancer specimens and analysis results were further validated by qRT-PCR and Western blot assay. The correlation between SCNN1A expression and clinicopathological characteristics and its impact on survival outcome of pancreatic cancer patients were investigated using GEPIA database and Kaplan-Meier plotter. Loss- and gain-of-functional experiments in vitro were done to investigate the biological function of SCNN1A in pancreatic cancer. Bioinformatics analysis and validation experiment showed that SCNN1A was frequently overexpressed in pancreatic cancer specimens and cell lines (P < 0.001), and there were significant relevance between high SCNN1A expression and TP53 mutation (P < 0.05) as well as unfavorable prognosis of pancreatic cancer patients (HR for overall survival: 1.9, P = 0.003 and HR for disease-free survival: 1.7, P = 0.014). The silencing of SCNN1A suppressed cell proliferation, migration and invasion and induced cell apoptosis (P < 0.05), while its overexpression promoted aggressive phenotypes of pancreatic cancer cells in vitro (P < 0.05). SCNN1A possessed oncogenic function and its dysregulation could be implicated in the development and metastasis of pancreatic cancer.


Assuntos
Neoplasias Pancreáticas , Sódio , Carcinogênese/genética , Linhagem Celular Tumoral , Movimento Celular , Proliferação de Células , Canais Epiteliais de Sódio/genética , Canais Epiteliais de Sódio/metabolismo , Regulação Neoplásica da Expressão Gênica , Humanos , Neoplasias Pancreáticas/patologia , Sódio/metabolismo , Canais de Sódio/genética , Neoplasias Pancreáticas
9.
Cancer Sci ; 113(5): 1868-1879, 2022 May.
Artigo em Inglês | MEDLINE | ID: mdl-35271750

RESUMO

Pancreatic adenocarcinoma (PAAD) remains an extremely fatal malignancy with a high mortality rate worldwide. This study focuses on the roles of ubiquitin-specific peptidase 10 (USP10) and cysteine rich angiogenic inducer 61 (Cyr61) in macrophage polarization, immune escape, and metastasis of PAAD. USP10 showed a positive correlation with Yes1 associated transcriptional regulator (YAP1), which, according to the TCGA-PAAD database, is highly expressed in PAAD and indicates poor patient prognosis. USP10 knockdown increased ubiquitination and degradation of YAP1, which further decreased the programmed cell death ligand 1 (PD-L1) and Galectin-9 expression, suppressed immune escape, and reduced the proliferation and metastasis of PAAD cells in vitro and in vivo. Cyr61, a downstream factor of YAP1, was overexpressed in PAAD cells after USP10 silencing for rescue experiments. Overexpression of Cyr61 restored the PD-L1 and Galectin-9 expression in cells and triggered M2 polarization of macrophages, which enhanced the immune escape and maintained the proliferation and metastasis ability of PAAD cells. In conclusion, this work demonstrates that USP10 inhibits YAP1 ubiquitination and degradation to promote Cyr61 expression, which induces immune escape and promotes growth and metastasis of PAAD.


Assuntos
Adenocarcinoma , Neoplasias Pancreáticas , Adenocarcinoma/patologia , Antígeno B7-H1/metabolismo , Cisteína , Enzimas Desubiquitinantes , Galectinas/metabolismo , Regulação Neoplásica da Expressão Gênica , Humanos , Neoplasias Pancreáticas/patologia , Proteínas Proto-Oncogênicas c-yes , Ubiquitina Tiolesterase/metabolismo , Proteases Específicas de Ubiquitina/metabolismo , Neoplasias Pancreáticas
10.
J Fungi (Basel) ; 8(3)2022 Mar 03.
Artigo em Inglês | MEDLINE | ID: mdl-35330263

RESUMO

The purpose of this study was to determine the effect and mechanism of alkaline fertilizer, bio-control fungi, and their synergistic application on control of Fusarium Tr4 incidence. Synchronized use of the alkaline fertilizer and biocontrol fungi eliminates rhizome browning and reduces the incidence rate of banana Fusarium wilt. The incidence of yellow leaves (ratio of yellow leaf to total leaf) and disease index in +Foc Tr4 CF treatment were the same (65%), while incidence of yellow leaves and disease index in +Foc Tr4 AFBCF were 31% and 33%, respectively. Under the stress of Foc Tr4 infection, the synergistic utilization of the alkaline fertilizer and biocontrol fungi would raise the activities of peroxidase, catalase and superoxide dismutase in banana roots. The root activity of banana was also increased. As a result, the banana height and stem diameter increments, shoot and root dry weight, accumulation of N, P and K in banana plants had been increased. The efficacy of the synergistic application of alkaline fertilizer and biocontrol fungi was not only reducing Foc Tr4 pathogen colonization and distribution in banana plants, but also preventing tylosis formation in vascular vessel effectively. Therefore, the normal transport of water and nutrients between underground and aboveground is ensured.

11.
Environ Sci Pollut Res Int ; 29(15): 22742-22755, 2022 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-34796442

RESUMO

With unconventional oil and gas booming in commercial development, its inevitable environmental damage has aroused the public's vigilance. To support the regulation improvement and early-warning system building, it is of great need to learn the regular patterns in recurrent violations both for practitioners and governments. In this respect, we utilized the "Oil and Gas Compliance Report" from the Pennsylvania Department of Environmental Protection from 2000 to 2019, a total of 5737 violation records, to dig out the historical violation patterns. Through LDA (Latent Dirichlet Allocation) analysis combined with the decision tree model, our research attained the following conclusions: first, we find that the LDA themes of violations as "Erosion and sediment" and "Water pollution" are critical factors for "Failed" enforcement results. Therefore, policymakers and practitioners should pay more attention to those two types of accidents. Second, it is noted that counties are also one of the essential features that matter the enforcement results. Third, we need to consider the role of economic punishment dialectically, while it is not a significant feature for successful enforcement results. That is to say, a monetary penalty may not necessarily improve the effectiveness of the company's measurements.


Assuntos
Gás Natural , Poluição da Água , Pennsylvania
12.
Biotechnol Biofuels ; 14(1): 226, 2021 Nov 27.
Artigo em Inglês | MEDLINE | ID: mdl-34838122

RESUMO

Chinese hickory shell, a by-product of the food industry, is still not utilized and urgent to develop sustainable technologies for its valorization. This research focuses on the systematical evaluation of degraded products and xylooligosaccharide production with high yield from the shell via hydrothermal process. The pretreatment was carried out in a bath pressurized reactor at 140-220 °C for 0.5-2 h. The results indicated that the pretreatment condition strongly affected the chemical structures and compositions of the liquid fraction. The maximum yield of XOS (55.3 wt%) with limitation of by-products formation was achieved at 160 °C for 2 h. High temperature (220 °C) and short time (0.5 h) contributed to hydrolysis of xylooligosaccharide with high DP to yield 37.5 wt% xylooligosaccharide with DP from 2 to 6. Xylooligosaccharide obtained mainly consisted of xylan with branches according to the HSQC NMR analysis. Overall, the production of XOS with a high yield from food waste will facilitate the valorization of food waste in the biorefinery industry.

13.
Bioresour Technol ; 342: 125955, 2021 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-34547709

RESUMO

A promising approach for production of value-added xylooligosaccharides (XOS) from poplar was developed by combining hydrothermal pretreatment and endo-xylanase post-hydrolysis. Results showed that the 35.4% XOS (DP 2-6) and 17.6% low DP xylans (DP > 6) were obtained at the identified optimal condition (170 °C, 50 min) for hydrothermal pretreatment. Structural features of low DP xylans generated during the hydrothermal pretreatment were examined, revealing that low DP xylans are mainly comprised of 4-O-methylglucuronic xylan and are involved in lignin carbohydrate complexes. Moreover, higher pretreatment intensity promoted the cleavage of side-chain substituents including arabinose and glucuronic acid groups. The subsequent endo-xylanase hydrolysis of the pretreatment liquor hydrolyzed low DP xylans, contributing to a significant improvement in xylobiose and xylotriose proportions. This combined strategy resulted in a XOS with conversion yield of 44.6% containing 78.7% xylobiose and xylotriose starting from the initial xylan in raw poplar.


Assuntos
Endo-1,4-beta-Xilanases , Glucuronatos , Dissacarídeos , Hidrólise , Oligossacarídeos , Trissacarídeos , Xilanos
14.
Int J Biol Macromol ; 192: 417-425, 2021 Dec 01.
Artigo em Inglês | MEDLINE | ID: mdl-34582914

RESUMO

Deep eutectic solvents (DES) pretreatment is a promising approach to decrease "biomass recalcitrance" and boost the cellulose bioconversion as well as lignin valorization. In this study, a short-time DES pretreatment strategy was performed to enhance the production of high-yield fermentable sugars and tailored lignin nanoparticles (LNPs) from abaca. The glucose yield reached 92.4% under the optimal pretreatment condition (110 °C, 30 min), which was dramatically increased in comparison with that (9.5%) of control abaca. Simultaneously, nuclear magnetic resonance (NMR) and gel permeation chromatography (GPC) techniques indicated that the removed and regenerated DES lignin fractions displayed depolymerized structures and have relatively low molecular weight with relatively homogeneous morphology and narrow size distribution. Transmission electron microscope (TEM) analysis indicated that these lignin fractions are LNPs and the size of the optimal LNPs fraction is ranged from 30 nm to 50 nm. Moreover, all the DES lignin exhibited excellent antioxidant activities as compared to the commercial antioxidant butylated hydroxytoluene (BHT), which can be used as a promising natural antioxidant in industry. In short, this study demonstrated that the short-time DES pretreatment will improve the enzymatic digestibility and facilitate the controllable production and valorization of LNPs from abaca biomass, which will further promote the economic and overall benefits of biorefinery.


Assuntos
Solventes Eutéticos Profundos/química , Lignina/química , Musa/química , Nanopartículas/química , Açúcares/química , Antioxidantes/química , Antioxidantes/farmacologia , Biomassa , Celulose/química , Fermentação , Hidrólise , Estrutura Molecular , Peso Molecular , Análise Espectral
15.
BMC Cancer ; 21(1): 335, 2021 Mar 31.
Artigo em Inglês | MEDLINE | ID: mdl-33789615

RESUMO

BACKGROUND: Gene mutations play critical roles in tumorigenesis and cancer development. Our study aimed to screen survival-related mutations and explore a novel gene signature to predict the overall survival in pancreatic cancer. METHODS: Somatic mutation data from three cohorts were used to identify the common survival-related gene mutation with Kaplan-Meier curves. RNA-sequencing data were used to explore the signature for survival prediction. First, Weighted Gene Co-expression Network Analysis was conducted to identify candidate genes. Then, the ICGC-PACA-CA cohort was applied as the training set and the TCGA-PAAD cohort was used as the external validation set. A TP53-associated signature calculating the risk score of every patient was developed with univariate Cox, least absolute shrinkage and selection operator, and stepwise regression analysis. Kaplan-Meier and receiver operating characteristic curves were plotted to verify the accuracy. The independence of the signature was confirmed by the multivariate Cox regression analysis. Finally, a prognostic nomogram including 359 patients was constructed based on the combined expression data and the risk scores. RESULTS: TP53 mutation was screened to be the robust and survival-related mutation type, and was associated with immune cell infiltration. Two thousand, four hundred fifty-five genes included in the six modules generated in the WGCNA were screened as candidate survival related TP53-associated genes. A seven-gene signature was constructed: Risk score = (0.1254 × ERRFI1) - (0.1365 × IL6R) - (0.4400 × PPP1R10) - (0.3397 × PTOV1-AS2) + (0.1544 × SCEL) - (0.4412 × SSX2IP) - (0.2231 × TXNL4A). Area Under Curves of 1-, 3-, and 5-year ROC curves were 0.731, 0.808, and 0.873 in the training set and 0.703, 0.677, and 0.737 in the validation set. A prognostic nomogram including 359 patients was constructed and well-calibrated, with the Area Under Curves of 1-, 3-, and 5-year ROC curves as 0.713, 0.753, and 0.823. CONCLUSIONS: The TP53-associated signature exhibited good prognostic efficacy in predicting the overall survival of PC patients.


Assuntos
Nomogramas , Neoplasias Pancreáticas/mortalidade , Proteína Supressora de Tumor p53/metabolismo , Idoso , Estudos de Coortes , Feminino , Humanos , Masculino , Mutação , Neoplasias Pancreáticas/genética , Neoplasias Pancreáticas/metabolismo , Prognóstico , Análise de Sequência de RNA , Análise de Sobrevida , Proteína Supressora de Tumor p53/genética
16.
Carbohydr Polym ; 256: 117507, 2021 Mar 15.
Artigo em Inglês | MEDLINE | ID: mdl-33483029

RESUMO

A series of vegetable oil-based waterborne polyurethane composites were prepared through construction of novel semi-interpenetrating polymers network using carboxymethyl chitosan (CA) as the secondary polymer phase. The effects of CA contents on storage stability, and particle size distribution of the composite dispersions and thermal stability, mechanical properties and surface wettability of composite films were investigated and discussed. The results showed that the composite dispersions displayed excellent storage stability and the biomass contents of resulting films were high up to 80 %. A significant increase in crosslinking density and glass transition temperature of the composite films were observed as the CA contents increased, which was attributed to the increasing hard segment of films and strong hydrogen bonding interaction between polyurethanes and CA. This work provided a simple method to tailor the performance of environmentally friendly vegetable oil-based waterborne polyurethane, which could find application in the field of coatings, adhesives, ink and so on.


Assuntos
Óleo de Rícino/química , Quitosana/análogos & derivados , Poliuretanos/química , Água/química , Quitosana/química , Estabilidade de Medicamentos , Humanos , Ligação de Hidrogênio , Teste de Materiais , Tamanho da Partícula , Transição de Fase , Resistência à Tração , Temperatura de Transição , Molhabilidade
17.
Tour Manag Perspect ; 35: 100715, 2020 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-32834957

RESUMO

Utilizing a scientometric review of global trends and structure from 388 bibliographic records over two decades (1999-2018), this study seeks to advance the building of comprehensive knowledge maps that draw upon global travel demand studies. The study, using the techniques of co-citation analysis, collaboration network and emerging trends analysis, identified major disciplines that provide knowledge and theories for tourism demand forecasting, many trending research topics, the most critical countries, institutions, publications, and articles, and the most influential researchers. The increasing interest and output for big data and machine learning techniques in the field were visualized via comprehensive knowledge maps. This research provides meaningful guidance for researchers, operators and decision makers who wish to improve the accuracy of tourism demand forecasting.

18.
Sci Total Environ ; 744: 140935, 2020 Nov 20.
Artigo em Inglês | MEDLINE | ID: mdl-32688005

RESUMO

The novel coronavirus disease 2019 (COVID-19) has spread globally and the meteorological factors vary greatly across the world. Understanding the effect of meteorological factors and control strategies on COVID-19 transmission is critical to contain the epidemic. Using individual-level data in mainland China, Hong Kong, and Singapore, and the number of confirmed cases in other regions, we explore the effect of temperature, relative humidity, and control measures on the spread of COVID-19. We find that high temperature mitigates the transmission of the disease. High relative humidity promotes COVID-19 transmission when temperature is low, but tends to reduce transmission when temperature is high. Implementing classical control measures can dramatically slow the spread of the disease. However, due to the occurrence of pre-symptomatic infections, the effect of the measures to shorten treatment time is markedly reduced and the importance of contact quarantine and social distancing increases.


Assuntos
Infecções por Coronavirus , Coronavirus , Pandemias , Pneumonia Viral , Betacoronavirus , COVID-19 , China , Hong Kong , Humanos , Conceitos Meteorológicos , SARS-CoV-2 , Singapura
19.
ChemSusChem ; 13(17): 4356-4366, 2020 Sep 07.
Artigo em Inglês | MEDLINE | ID: mdl-32291938

RESUMO

As a skeleton component of plants, lignin is an organic macromolecule polymer that can be regenerated and naturally degraded. Annually, plant growth produces about 150 billion tons of lignin. In industrial processes such as paper and biomass-refining industry, large amounts of lignin are formed as by-products. Most of technical lignins are directly combusted to obtain heat, which not only is a waste of organic matter but also leads to environmental pollution and other issues. Interestingly, lignin can be used as slow-release carriers and coating materials for fertilizers due to its excellent slow release properties as well as chelating and other functionalities. Preparation of lignin-based slow/controlled release fertilizers can be achieved by sustainable chemical (ammoxidation, Mannich reaction, and other chemical modifications), coating (without or with chemical modification), and chelation modifications. This Review systematically summarizes the methods, mechanisms, and application of the above methods for preparing lignin-based slow/controlled release fertilizers. Although the evaluation standards and methods of lignin-based slow/controlled release fertilizers are not perfect, it is believed that more and more scholars will pay more attention to them to accelerate the development and application of lignin-based slow/controlled release fertilizers, so as to improve their relevant standards. In short, there is an urgent need to improve the preparation process of lignin-based slow/controlled release fertilizers and application as lignin-based slow/controlled release fertilizers to production practice as soon as possible.

20.
Polymers (Basel) ; 12(3)2020 Mar 03.
Artigo em Inglês | MEDLINE | ID: mdl-32138299

RESUMO

Efficient production of furfural from cornstalk in 2-Methyltetrahydrofuran/aqueous (MTHF/H2O) biphasic system via parameter regulation (e.g., VMTHF/VH2O, temperature, time, and H2SO4 concentration) was proposed. The resulting solid residues achieved from the different MTHF/H2O system conditions for furfural production were also to prepare glucose by adding cellulases to increase the high-value applications of cornstalk. A maximum furfural yield (68.1%) was obtained based on reaction condition (VMTHF:VH2O = 1:1, 170 °C, 60 min, 0.05 M H2SO4). Among these parameters, the concentration of H2SO4 had the most obvious effect on the furfural production. The glucose yields of the residues acquired from different MTHF/H2O processes were enhanced and then a maximum value of 78.9% based on the maximum furfural production conditions was observed. Single factor may not be sufficient to detail the difference in glucose production, and several factors affected the hydrolysis efficiency of the residues. Overall, the MTHF/H2O system effectively converted cornstalk into furfural and glucose via a simple and environment-friendly process, thus was an ideal manner for the food industries.

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