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1.
Inorg Chem ; 54(21): 10250-5, 2015 Nov 02.
Artigo em Inglês | MEDLINE | ID: mdl-26479903

RESUMO

The crystal structure and the Yb valence of the YbFe2Ge2 heavy fermion compound was measured at room temperature and under high pressures using high-pressure powder X-ray diffraction and X-ray absorption spectroscopy via both partial fluorescence yield and resonant inelastic X-ray emission techniques. The measurements are complemented by first-principles density functional theoretical calculations using the self-interaction corrected local spin density approximation investigating in particular the magnetic structure and the Yb valence. While the ThCr2Si2-type tetragonal (I4/mmm) structure is stable up to 53 GPa, the X-ray emission results show an increase of the Yb valence from v = 2.72(2) at ambient pressure to v = 2.93(3) at ∼9 GPa, where at low temperature a pressure-induced quantum critical state was reported.

2.
Nanotechnology ; 22(43): 435401, 2011 Oct 28.
Artigo em Inglês | MEDLINE | ID: mdl-21969305

RESUMO

The decay dynamics of self-assembled germanium islands is studied by time-resolved fluorescence spectroscopy. The scaling behavior of the decay rate with the number of excitons in the islands is shown to agree with expectations for an Auger-recombination-dominated process in the asymptotic limit of high exciton numbers. The multi-excitonic decay time and spectral behavior are compared to theoretical estimates.

3.
Phys Rev E Stat Nonlin Soft Matter Phys ; 70(3 Pt 1): 031105, 2004 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-15524504

RESUMO

We present a dynamical description and analysis of nonequilibrium transitions in the noisy one-dimensional Ginzburg-Landau equation for an extensive system based on a weak noise canonical phase space formulation of the Freidlin-Wentzel or Martin-Siggia-Rose methods. We derive propagating nonlinear domain wall or soliton solutions of the resulting canonical field equations with superimposed diffusive modes. The transition pathways are characterized by the nucleation and subsequent propagation of domain walls. We discuss the general switching scenario in terms of a dilute gas of propagating domain walls and evaluate the Arrhenius factor in terms of the associated action. We find excellent agreement with recent numerical optimization studies.

4.
Phys Rev E Stat Nonlin Soft Matter Phys ; 70(2 Pt 1): 021905, 2004 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-15447513

RESUMO

We investigate by analytical means the stochastic equations of motion of a linear molecular motor model based on the concept of protein friction. Solving the coupled Langevin equations originally proposed by Mogilner et al. [Phys. Lett. A 237, 297 (1998)], and averaging over both the two-step internal conformational fluctuations and the thermal noise, we present explicit, analytical expressions for the average motion and the velocity-force relationship. Our results allow for a direct interpretation of details of this motor model which are not readily accessible from numerical solutions. In particular, we find that the model is able to predict physiologically reasonable values for the load-free motor velocity and the motor mobility.


Assuntos
Biofísica/métodos , Trifosfato de Adenosina/química , Fricção , Hidrólise , Modelos Moleculares , Modelos Estatísticos , Modelos Teóricos , Ligação Proteica , Conformação Proteica , Processos Estocásticos , Estresse Mecânico
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