Captivating nano sensors for mercury detection: a promising approach for monitoring of toxic mercury in environmental samples.

Mercury, a widespread highly toxic environmental pollutant, poses significant risks to both human health and ecosystems. It commonly infiltrates the food chain, particularly through fish, and water resources via multiple pathways, leading to adverse impacts on human health and the environment. To monitor and keep track of mercury ion levels various methods traditionally have been employed. However, conventional detection techniques are often hindered by limitations. In response to challenges, nano-sensors, capitalizing on the distinctive properties of nanomaterials, emerge as a promising solution. This comprehensive review provides insight into the extensive spectrum of nano-sensor development for mercury detection. It encompasses various types of nanomaterials such as silver, gold, silica, magnetic, quantum dot, carbon dot, and electrochemical variants, elucidating their sensing mechanisms and fabrication. The aim of this review is to offer an in-depth exploration to researchers, technologists, and the scientific community, and understanding of the evolving landscape in nano-sensor development for mercury sensing. Ultimately, this review aims to encourage innovation in the pursuit of efficient and reliable solutions for mercury detection, thereby contributing to advancements in environmental protection and public health.

Nanomaterial catalyzed green synthesis of tetrazoles and its derivatives: a review on recent advancements.

Tetrazoles are indispensable nitrogen containing heterocyclic scaffolds that offer a broad spectrum of applications in various domains such as medicinal chemistry, high energy material science, biochemistry, pharmacology etc. Owing to their useful applications, a wide range of catalysts have been explored for green synthesis of tetrazole derivatives. In recent times, nanomaterials have been emerged as extremely efficient catalysts for different organic transformations because of their high surface area-to-volume ratio, easy surface modification, simple fabrications, easy recovery and reusability. In this article, we have presented an overview of utilization of various nano-catalysts, nanocomposites and other solid-supported nanomaterials as an efficient environmental benign catalytic system for green synthesis of tetrazoles and derivatives. This review will provide an exclusive emphasis on boehmite, magnetic, copper, carbon, MCM-41, and composite based nanomaterials that have been developed since the year 2010 for the synthesis of tetrazole derivatives. In addition, we have briefly discussed the fabrication, functionalization and characterization of some novel nanomaterials and their advantages in the synthesis of tetrazole and its derivatives along with the reaction mechanism that involves synthesis of tetrazole derivatives via nanomaterials catalysed reactions.

Recent progress in development of 2,3-diaminomaleonitrile (DAMN) based chemosensors for sensing of ionic and reactive oxygen species.

2,3-Diaminomaleonitrile (DAMN) has proved to be a valuable organic π-conjugated molecule having many applications in the area of chemosensors for sensing of ionic and neutral species because of its ability to act as a building block for well-defined molecular architectures and scaffolds for preorganised arrays of functionality. In this article, we discussed the utilization of 2,3-diaminomaleonitrile (DAMN) for the design and development of chemosensor molecules and their application in the area of metal ion, anion and reactive oxygen species sensing. Along with these, we present different examples of DAMN based chemosensors for multiple ion sensing. We also discuss the ion sensing mechanism and potential uses in other related areas of research.

Indium triflate promoted one-pot multicomponent synthesis of structurally diverse 3-amino-imidazo[1,2-a]pyridines.

An efficient, mild, and expeditious synthetic protocol has been developed for the synthesis of structurally diverse 3-amino-imidazo[1,2-a]pyridines, involving a three-component, one-pot cyclocondensation reaction of 2-aminobenzothiazole/2-aminoazines, ethyl isocyanoacetate/tert-butyl isocyanides, and pyrazole-3(4)-carbaldehyde/substituted aromatic carbonyl compounds in 45 min. using In(OTf)[Formula: see text] as a catalyst in toluene. Mild reaction conditions, high atom economy, operational simplicity, short reaction time, and structural diversity with high product conversion are among the advantages of the present synthetic protocol.