1.
Chem Commun (Camb)
; 57(53): 6542-6545, 2021 Jul 07.
Artigo
em Inglês
| MEDLINE
| ID: mdl-34109342
RESUMO
A novel titanium(iii) phosphite with intriguing polymorphism and solid-state proton-coupled electron transfer (PCET) oxidation is presented. The polymorphs show structure-dependent PCET reactivity, interpretable by proton distribution in channels. Combined with subsequent photoreduction, the redox cycle initiated with TiIII can produce H2 and transform organics.