RESUMO
The aim of this investigation was to determine odorous compounds in the air over the landfill sites in France and Poland. Air samples were collected by passive and dynamic methods of preconcentration analytes and analysed by GC-MS and GC-FID. The coupling microTD-microGC-MS was also used for on-site analysis of odorous compounds. The achieved results indicated that the concentrations of odorants in the air varied and strongly depended on the sampling site. The highest concentrations were observed at the points situated near biogas wells and above the fresh waste layer. The concentrations were influenced by landfill activities such as failures of the landfill gas collection system, heavy truck traffic, machinery operations and compacting fresh waste.
Assuntos
Monitoramento Ambiental/métodos , Odorantes/análise , Poluentes Atmosféricos/análise , Cidades , França , Gases/análise , PolôniaRESUMO
The aim of the present investigation was to determine time variation of biogas composition at the gas collection network on the 'Barycz' landfill site in Cracow, Poland, as well as the influence of operational and meteorological conditions on the biogas composition. The study of biogas composition at selected gas wells and gas collectors was conducted using a portable IR landfill gas analyser. The methane concentration in biogas on the part of the landfill site currently in operation varied in the range 59-63% vol. and on the reclaimed part of the landfill, in the range 42-62% vol. It was found that biogas composition is significantly affected by operational conditions and meteorological parameters. For example, methane concentrations were more constant when the pressure in the installation was above the ambient atmosphere than when it was below, where fluctuations of 15% vol. were seen. Low air temperature, high precipitation and high atmospheric pressure, which lower the permeability of the outer layer of the landfill, result in higher quality of the biogas getting to the gas collection system.
