1.
Chem Commun (Camb)
; 51(15): 3208-10, 2015 Feb 21.
Artigo
em Inglês
| MEDLINE
| ID: mdl-25605668
RESUMO
3/4-Mercaptobenzyl sulfonates were investigated as aryl thiol catalysts for native chemical ligation (NCL). Whilst catalysing NCL processes at a similar rate to 4-mercaptophenyl acetic acid (MPAA), the increased polarity and solubility of 3-mercaptobenzyl sulfonate in particular may favour its selection as NCL catalyst in many instances.