Comparison of leaching behaviour of heavy metals from sediments sampled in sewer systems - environmental and public health aspect.

INTRODUCTION AND OBJECTIVE: The article analyzes the content of heavy metals and standard physical as well as chemical pollution indicators in different types of sediments from stormwater, combined sewer and sanitary sewer systems. MATERIAL AND METHODS: Nickel, lead, chromium, copper, zinc and cadmium, as well as standard physical and chemical pollution indicators, were determined in sewage sediments. Aqueous extracts of sediments samples, taken from storm water sewer inlet sediments traps, storm sewers, sanitary sewers and combined sewers, were prepared in accordance with PN-EN 12457-2:2006. After mineralization, the concentrations of the metals: nickel, lead, chromium, copper, zinc and cadmium in the extracts were determined using the inductively coupled plasma emission spectroscopy technique. RESULTS: The results were analyzed with a non-metric multidimensional scaling algorithm. The heavy metal content was variable depending on the sediments collection site. The heavy metals nickel, lead, chromium, copper, zinc and cadmium were found in the sediments from stormwater inlets, storm sewer and sanitary sewer channels, with variability in the concentration of individual metals. The sediments from the flushing of sanitary sewers and combined sewers did not contain cadmium. CONCLUSIONS: The content of heavy metals in sediments varied depending on the sampling location and type of sewer system, indicating the need for detailed monitoring to identify the sources of emissions. Sediments from stormwater sewers have higher concentrations of heavy metals, with those from sewer inlets showing zinc concentrations exceeding regulatory limits, highlighting the variability and potential environmental impact of different sewer systems.

Macrophyte communities as bioindicator of stormwater pollution in rivers: a quantitative analysis.

Macrophytes are one of the important indicators used in assessing the anthropic impact on aquatic ecosystems. The structure of macrophyte communities of two rivers were compared by species composition, dominant species and projective cover using statistical methods. It is shown that the influence of storm runoff on these rivers is manifested in the form of a change in the dominant species composition. Based on the statistical analysis carried out, it can be argued that, despite the peculiarities of the flora composition of each of the rivers, the influence of storm runoffs largely neutralizes this specificity, determining the situation in local areas immediately below the runoff. In the area of the effluent discharge the dominance of individual species and an increase in the area overgrown with macrophytes was observed. In the area of stormwater discharge on the Psel River, species were usually present: Nuphar lutea, Ceratophyllum demersum, Myriophyllum spicatum and on the Bystrica River-Glyceria maxima, Sagitaria sagittiformis, Stuckenia pectinata and Potamogeton crispus. The use of the NMDS method has been found to provide good insight into the structural rearrangements in macrophyte communities affected by runoff from stormwater systems.

Ratio of abundances of ciliates behavioral groups as an indicator of the treated wastewater impact on rivers.

A method for assessing the degree of impact of wastewater treatment plant discharge on receiving rivers was proposed, based on the structural indicators of the population of ciliated protozoa. It was shown that the ratio of attached, crawling and free-swimming forms in bottom sediments changes under the influence of discharge. In the points subject to organic pollution, the share of attached filter-feeding bacteriovorous ciliates increases in the assemblage of ciliated protozoa. The proposed Attached Form Index (AFI) takes this ratio into account. The use of AFI makes it possible to assess the restructuring of the assemblage of ciliated protozoa under the influence of point sources of pollution, to establish a zone of negative influence of runoff, to assess the degree of restoration of the aquatic ecosystem, as the influence of the pollution source weakened.

Knowledge and Technology Used in Capacitive Deionization of Water.

The demand for water and energy in today's developing world is enormous and has become the key to the progress of societies. Many methods have been developed to desalinate water, but energy and environmental constraints have slowed or stopped the growth of many. Capacitive Deionization (CDI) is a very new method that uses porous carbon electrodes with significant potential for low energy desalination. This process is known as deionization by applying a very low voltage of 1.2 volts and removing charged ions and molecules. Using capacitive principles in this method, the absorption phenomenon is facilitated, which is known as capacitive deionization. In the capacitive deionization method, unlike other methods in which water is separated from salt, in this technology, salt, which is a smaller part of this compound, is separated from water and salt solution, which in turn causes less energy consumption. With the advancement of science and the introduction of new porous materials, the use of this method of deionization has increased greatly. Due to the limitations of other methods of desalination, this method has been very popular among researchers and the water desalination industry and needs more scientific research to become more commercial.

Modeling and Optimization of Pollutants Removal during Simultaneous Adsorption onto Activated Carbon with Advanced Oxidation in Aqueous Environment.

The paper presents the results of studies on the modeling and optimization of organic pollutant removal from an aqueous solution in the course of simultaneous adsorption onto activated carbons with varied physical characteristics and oxidation using H2O2. The methodology for determining the models used for predicting the sorption and catalytic parameters in the process was presented. The analysis of the influence of the sorption and catalytic parameters of activated carbons as well as the oxidizer dose on the removal dynamics of organic dyes-phenol red and crystal violet-was carried out based on the designated empirical models. The obtained results confirm the influence of specific surface area (S) of the activated carbon and oxidizer dose on the values of the reaction rate constants related to the removal of pollutants from the solution in a simultaneous process. It was observed that the lower the specific surface area of carbon (S), the greater the influence of the oxidizer on the removal of pollutants from the solution. The proposed model, used for optimization of parameters in a simultaneous process, enables to analyze the effect of selected sorbents as well as the type and dose of the applied oxidizer on the pollutant removal efficiency. The practical application of models will enable to optimize the selection of a sorbent and oxidizer used simultaneously for a given group of pollutants and thus reduce the process costs.

Contribution of prokaryotes and eukaryotes to CO2 emissions in the wastewater treatment process.

Reduction of the greenhouse effect is primarily associated with the reduction of greenhouse gas (GHG) emissions. Carbon dioxide (CO2) is one of the gases that increases the greenhouse effect - it is responsible for about half of the greenhouse effect. Significant sources of CO2 are wastewater treatment plants (WWTPs) and waste management, with about 3% contribution to global emissions. CO2 is produced mainly in the aerobic stage of wastewater purification and is a consequence of activated sludge activity. Although the roles of activated sludge components in the purification process have been studied quite well, their quantitative contribution to CO2 emissions is still unknown. The emission of CO2 caused by prokaryotes and eukaryotes over the course of a year (taking into account subsequent seasons) in model sequencing batch reactors (SBR) is presented in this study. In this work, for the first time, we aimed to quantify this contribution of eukaryotic organisms to total CO2 emissions during the WWTP process. It is of the order of several or more ppm. The contribution of CO2 produced by different components of activated sludge in WWTPs can improve estimation of the emissions of GHGs in this area of human activity.

The Influence of COD Fraction Forms and Molecules Size on Hydrolysis Process Developed by Comparative OUR Studies in Activated Sludge Modelling.

The activated sludge models (ASMs) commonly used by the International Water Association (IWA) task group are based on chemical oxygen demand (COD) fractionations. However, the proper evaluation of COD fractions, which is crucial for modelling and especially oxygen uptake rate (OUR) predictions, is still under debate. The biodegradation of particulate COD is initiated by the hydrolysis process, which is an integral part of an ASM. This concept has remained in use for over 30 years. The aim of this study was to verify an alternative, more complex, modified (Activated Sludge Model No 2d) ASM2d for modelling the OUR variations and novel procedure for the estimation of a particulate COD fraction through the implementation of the GPS-X software (Hydromantis Environmental Software Solutions, Inc., Hamilton, ON, Canada) in advanced computer simulations. In comparison to the original ASM2d, the modified model more accurately predicted the OUR behavior of real settled wastewater (SWW) samples and SWW after coagulation-flocculation (C-F). The mean absolute relative deviations (MARDs) in OUR were 11.3-29.5% and 18.9-45.8% (original ASM2d) vs. 9.7-15.8% and 11.8-30.3% (modified ASM2d) for the SWW and the C-F samples, respectively. Moreover, the impact of the COD fraction forms and molecules size on the hydrolysis process rate was developed by integrated OUR batch tests in activated sludge modelling.