RESUMO
Developments in interfacial shear rheometers have considerably improved the quality of experimental data. However, data analysis in interfacial shear rheometry is still an active field of research and development due to the intrinsic complexity introduced by the unavoidable contact of the interface with, at least, one supporting bulk subphase. Nonlinear velocity profiles, both at the interface and the bulk phases, pervade the system dynamical behavior in the most usual experimental geometries, particularly in the case of soft interfaces. Such flow configurations demand data analysis schemes based on the explicit calculation of the flow field in both the interface and the bulk phases. Such procedures are progressively becoming popular in this context. In this review, we discuss the most recent advances in interfacial shear rheology data analysis techniques. We extensively review some recently proposed flow field-based data analysis schemes for the three most common interfacial shear rheometer geometries (magnetic needle, double wall-ring, and bicone), showing under what circumstances the calculation of the flow field is mandatory for a proper analysis of the experimental data. All cases are discussed starting at the appropriate hydrodynamical models and using the equation of motion of the probe to set up an iterative procedure to compute the value of the complex Boussinesq number and, from it, the complex interfacial viscosity or, equivalently, the complex interfacial modulus. Moreover, two examples of further extensions of such techniques are proposed, concerning the micro-button interfacial shear rheometer and the potential application of interfacial rheometry instruments, together with adapted flow field-based data analysis techniques, for bulk rheometry, particularly in the case of soft samples.
RESUMO
Thin liquid films are central to everyday life. They are ubiquitous in modern technology (pharmaceuticals, coatings), consumer products (foams, emulsions) and also serve vital biological functions (tear film of the eye, pulmonary surfactants in the lung). A common feature in all these examples is the presence of surface-active molecules at the air-liquid interface. Though they form only molecular-thin layers, these surfactants produce complex surface stresses on the free surface, which have important consequences for the dynamics and stability of the underlying thin liquid film. Here we conduct simple thinning experiments to explore the fundamental mechanisms that allow the surfactant molecules to slow the gravity-driven drainage of the underlying film. We present a simple model that works for both soluble and insoluble surfactant systems in the limit of negligible adsorption-desorption dynamics. We show that surfactants with finite surface rheology influence bulk flow through viscoelastic interfacial stresses, while surfactants with inviscid surfaces achieve stability through opposing surface-tension induced Marangoni flows.
