Morphological Fabrication of Rubber Cutaneous Receptors Embedded in a Stretchable Skin-Mimicking Human Tissue by the Utilization of Hybrid Fluid.

Sensors are essential in the haptic technology of soft robotics, which includes the technology of humanoids. Haptic sensors can be simulated by the mimetic organ of perceptual cells in the human body. However, there has been little research on the morphological fabrication of cutaneous receptors embedded in a human skin tissue utilizing artificial materials. In the present study, we fabricated artificial, cell-like cutaneous receptors embedded in skin tissue mimicking human skin structure by utilizing rubber. We addressed the fabrication of five cutaneous receptors (free nerve endings, Krause and bulbs, Meissner corpuscles, Pacinian corpuscles and Ruffini endings). In addition, we investigated the effectiveness of the fabricated tissue for mechanical and thermal sensing. At first, in the production of integrated artificial skin tissue, we proposed a novel magnetic, responsive, intelligent, hybrid fluid (HF), which is suitable for developing the hybrid rubber skin. Secondly, we presented the fabrication by utilizing not only the HF rubber but our previously proposed rubber vulcanization and adhesion techniques with electrolytic polymerization. Thirdly, we conducted a mechanical and thermal sensing touch experiment with the finger. As a result, it demonstrated that intelligence as a mechanoreceptor or thermoreceptor depends on its fabric: the HF rubber sensor mimicked Krause and bulbs has the thermal and pressing sensibility, and the one mimicked Ruffini endings the shearing sensibility.

Enhancement of Diversity in Production and Applications Utilizing Electrolytically Polymerized Rubber Sensors with MCF: The Second Report on Various Engineering Applications.

We investigated the proposed hybrid skin (H-Skin) for the requirement of haptic sensibility in rubber using our proposed consummate fabrication process together with a multi-layered magnetic compound fluid (MCF) rubber and stocking-like porous rubber permeated by liquids, which was demonstrated in our previous report. The objective was to assess its applicability to sensing normal force and temperature, as well as fields dominated by shear force. For normal force, we investigated the piezo-electricity and electric current induced voltage, as well as the piezo-resistivity of the MCF rubber sensor under pressure. Additionally, we clarified the viability of measuring the softness and texture of materials using the MCF rubber sensor. For the shear motion, we clarified the characteristics of the friction coefficient using the MCF rubber sensor. The MCF rubber sensor can capture the reactions of paper, cloth, convex- and concave-shaped objects such as plant leaves and metal, and the skin of the human finger. Therefore, it is useful to investigate its texture and biological surfaces. Our obtained outstanding results indicated the feasibility of sensing the surface texture for any material in fields such as paper, fashion, apparel manufacturing, and cosmetic industries, which was impossible until now.

Enhancement of Diversity in Production and Application Utilizing Electrolytically Polymerized Rubber Sensors with MCF: 1st Report on Consummate Fabrication Combining Varied Kinds of Constituents with Porous Permeant Stocking-Like Rubber.

To satisfy the requirement of haptic sensibility in rubber such as in the proposed hybrid skin (H-Skin), the authors have demonstrated a new method for solidifying rubber using electrolytic polymerization together with configured magnetic clusters of magnetic compound fluid (MCF) incorporated into the rubber by the application of a magnetic field. However, the rubber and magnetic fluid (MF) involved in the MCF rubber were water-soluble. In addition, the authors have demonstrated the practicability of using electrolytic polymerization with an emulsifier, polyvinyl alcohol (PVA), in which natural rubber (NR) or chloroprene rubber (CR) and silicone rubber (Q) can be mixed as water-soluble and water-insoluble rubbers, respectively. In this study, to enhance production, the feasibility of solidifying rubber by electrolytic polymerization is verified using varied water-insoluble rubber, varied water-insoluble MF, and varied surfactants to aid emulsion polymerization, except in the case of other kinds of rubber and MF which have been demonstrated until recent by the authors. Based on these diverse constituents, the authors propose a consummate fabrication process for multi-layered MCF rubber, which involves porous stocking-like rubber that can be permeated by any liquid. The investigation of this application is presented in the sequential second report.

Development of a Magnetic Compound Fluid Rubber Stability Sensor and a Novel Production Technique via Combination of Natural, Chloroprene and Silicone Rubbers.

Expanding on our previous report, we investigate the stability of a magnetic compound fluid (MCF) rubber sensor that was developed for a variety of engineering applications. To stabilize this sensor, we proposed a novel combination technique that facilitates the addition of dimethylpolysiloxane (PDMS) to natural rubber (NR)-latex or chloroprene rubber (CR)-latex using polyvinyl alcohol (PVA) by experimentally and theoretically investigating issues related to instability. This technique is one of several other novel combinations of diene and non-diene rubbers. Silicone oil or rubber with PDMS can be combined with NR-latex and CR-latex because of PVA's emulsion polymerization behavior. In addition, owing to electrolytic polymerization based on the combination of PDMS and PVA, MCF rubber is highly porous and can be infiltrated in any liquid. Hence, the fabrication of novel intelligent rubbers using any intelligent fluid is feasible. By assembling infiltrated MCF rubber sheets and by conducting electrolytic polymerization of MCF rubber liquid with a hydrate using the adhesive technique as presented in a previous paper, it is possible to stabilize the MCF rubber sensor. This sensor is resistant to cold or hot water as well as γ-irradiation as shown in the previous report.

Novel Adhesion Technique Using Metallic or Non-Metallic Hydrous Oxide of Metal Complexes Involving Magnetic Compound Fluid Rubber under Electrolytic Polymerization and Magnetic Field for Producing Sensors.

As per sequential studies on new types of soft rubber for the artificial skin of robots, smart sensors, etc., we have proposed and investigated hybrid skin (H-Skin) and haptic sensors by using magnetic compound fluid (MCF), compounding natural rubber latex (NR-latex), and applying electric and magnetic fields. Through electrolytic polymerization, the MCF rubber is solidified. The MCF rubber has hybrid sensing functions and photovoltaic effects, and electric charge as battery. In case of the production of soft rubber sensors, however, the problem of adhesion between metal electrodes and rubber is very important. In the present study, we propose a novel adhesive technique for bonding the metal electrodes and MCF rubber by using metallic or non-metallic hydrous oxide, which is a metal complex, via electrolytic polymerization. The anionic radical hydrate reacts with the isoprene molecules of NR-latex or chloroprene rubber latex (CR-latex) such that they are cross-linked and the MCF rubber with the hydrate is solidified, which can be represented via a chemical reaction equation. By means of this adhesive technique, we presented five cases of sensors fabricated using metal electrodes and rubbers. This technique is applicable for novel cohesion between rubber and metal.

Effects of NH4+, K+, Mg2+, and Ca2+ on the Cesium Adsorption/Desorption in Binding Sites of Vermiculitized Biotite.

The reversibility of cesium adsorption in contaminated soil is largely dependent on its interaction with micaceous minerals, which may be greatly influenced by various cations. Herein, we systematically investigated the effects of NH4+, K+, Mg2+, and Ca2+ on the adsorption/desorption of Cs+ into different binding sites of vermiculitized biotite (VB). Original VB was initially saturated by NH4+, K+, or Mg2+; we then evaluated the adsorption of Cs+ on three treated VBs, and the desorption by extraction with NH4+, K+, Mg2+, or Ca2+ was further evaluated. Our structural analysis and Cs+ extractability determinations showed that NH4+ and K+ both collapsed the interlayers of VB, resulting in the dominant adsorption of Cs+ to external surface sites on which Cs+ was readily extracted by NH4+, K+, Mg2+, or Ca2+ irrespective of their species, whereas Mg2+ maintained the VB with expanded interlayers, leading to the overwhelming adsorption of Cs+ in collapsed interlayer sites on which the Cs+ desorption was difficult and varied significantly by the cations used in extraction. The order of Cs+ extraction ability from the collapsed interlayers was K+ ≫ Mg2+ ≈ Ca2+ ≫ NH4+. These results could provide important insights into Cs migration in soil and its decontamination for soil remediation.