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1.
Polymers (Basel) ; 14(4)2022 Feb 12.
Artigo em Inglês | MEDLINE | ID: mdl-35215626

RESUMO

Ultrasonic welding of thermoplastics is widely applied in automobile and aerospace industries. Increasing the weld area and avoiding thermal decomposition are contradictory factors in improving strength of ultrasonically welded polymers. In this study, relations among the loss modulus of carbon-fiber-reinforced polyamide 66 composite (CF/PA 66), time for obtaining stable weld area, and time for CF/PA 66 decomposition are investigated systematically. Then, a double-pulse ultrasonic welding process (DPUW) is proposed, and the temperature evolutions, morphologies and structures of fractured surfaces, and tensile and fatigue properties of the DPUWed joints are measured and assessed. Experimental results show the optimal welding parameters for DPUW include a weld time of 2.1 s for the first pulse, a cooling time of 12 s, and a weld time of 1.5 s for the second pulse. The DPUW process enlarged the weld area while avoided decomposition of CF/PA 66 under appropriate welding parameters. Compared to the single-pulse welded joint, the peak load, weld area, and endurance limit of the DPUWed joint increased by about 15%, 23% and 59%, respectively. DPUW also decreases the variance in strengths of the joints.

2.
ACS Appl Mater Interfaces ; 13(23): 27169-27178, 2021 Jun 16.
Artigo em Inglês | MEDLINE | ID: mdl-34081434

RESUMO

Harvesting energy from ambient moisture and natural water sources is currently of great interest due to the need for standalone self-powered nano/micro-systems. In this work, we report on the development of a cost-effective nanogenerator based on a carbon paper-Al2O3 nanoparticle layer-carbon paper (CAC) sandwich structure, where the 3D Al2O3 layer is deposited via vacuum filtration. This type of device can produce an open-circuit voltage (UOC) of up to 4 V and a short-circuit current (ISC) of ∼18 µA with only an 8 µL water droplet applied. To our knowledge, this is the highest voltage yet reported from a single moisture/water-induced electricity nanogenerator using solid oxides and carbon-based materials. A remarkable output power of 14.8 µW can be reached with an optimized resistive load. An LED with a working voltage of 3-3.2 V can operate for a short time with the power from a single CAC device exposed to one 8 µL water droplet. Furthermore, a CAC generator adsorbing as little as 2 µL water droplets every 3 min can also give a UOC of 3.63 V. We show that CAC devices provide a robust electrical output over more than 200 wet-dry cycles without any deterioration in performance. These units demonstrate much promise as cost-effective electricity generators for harvesting energy from natural sources like rainwater, tap water, snow runoff, and dew. The response time of CAC devices can be as fast as 10-100 ms, making them ideal for applications as self-powered water detectors. The generation of power in this device arises from the streaming current. To assist in the optimization of these devices, we have analyzed how their response is related to such factors as layer thickness, time interval between application of water droplets, and the volume of each water droplet.

3.
Materials (Basel) ; 13(12)2020 Jun 17.
Artigo em Inglês | MEDLINE | ID: mdl-32560372

RESUMO

Laser penetration welding of magnesium alloys and pure titanium TA2 with unequal thickness was performed. Mg base metal with different Al content (AZ31B, AZ61A, AZ91D) was used to investigate the influence of Al element in microstructure and mechanical properties of Mg/Ti dissimilar joints. The results revealed that the change of Mg base metal did not influence the weld appearance of the joints. Three kinds of joint all presented the best mechanical property when the laser power was 3500 W. With the increase content of Al elements in Mg base metal, a reaction layer was observed which was identified as Ti3Al. The highest enrichment of Al element was obtained and its fraction reached 19.31 at% at the AZ91/TA2 interface. The chemical potential gradient of Al from AZ91 to Ti alloy was higher than that from the other two base metals based on thermodynamic calculation. The maximum fracture load reached 3597 N when AZ61 was employed as the base metal and the fracture position was the Ti base metal. AZ31/TA2 joints failed at the weld seam without necking due to the rapid propagation of cracks at the Mg/Ti interface. The AZ91/TA2 joint failed inside the Mg fusion zone with necking at the middle area of the weld, which resulted from the precipitation of brittle phases such as Mg-Al, Ti-Al phases in the fusion zone of Mg alloys.

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