1.
Org Lett
; 25(23): 4258-4263, 2023 Jun 16.
Artigo
em Inglês
| MEDLINE
| ID: mdl-37272667
RESUMO
Pd-catalyzed double Heck reaction allows regioselective 1,1-diarylation of unactivated aliphatic alkenes. When two different aryl bromides are used, the second aryl rings are added trans to aliphatic chains in the main olefinic isomers, consistent with a mechanism of two consecutive Heck arylations at the terminal carbons.