1.
Chem Commun (Camb)
; 60(6): 698-701, 2024 Jan 16.
Artigo
em Inglês
| MEDLINE
| ID: mdl-38111304
RESUMO
The aluminium salt [(NHC)Al(tol)(C6F5)2][B(C6F5)4], (NHC = C3H2(N(iPr2C6H3))2) is shown to behave as a Lewis superacid as it abstracts fluoride from [SbF6]-. It also acts as a Lewis acid catalyst for hydrosilyation, hydrodefluorination and Friedel-Crafts reactions.