PCDD/Fs distribution characteristics and health risk assessment in fly ash discharged from MSWIs in China.

This study provided distribution and health risk information of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in fly ash from 4 municipal solid waste incinerators (MSWIs) in four seasons from four sites, including Zhengzhou City in Henan Province, Chuzhou City in Anhui Province, Jilin City in Jilin Province and Zibo City in Shandong Province. The toxic equivalent concentration (I-TEQ) values of PCDD/Fs ranged from 0.0707 to 0.7742ng I-TEQ/g, and no identical sequence occurred during four seasons in different sampling sites. The stabilization process might efficiently reduce the content and toxicology of PCDD/Fs in fly ash. The value of PCDD/PCDF in fly ash ranged from 0.145 to 0.787 after solidification. The characteristic index (DCI) of 2,3,4,7,8-P5CDF was 0.803 with 6.6% under 95% probability for fly ash samples discharged from MSWIs. The 95th percentile carcinogenic risks (CRs) for onsite workers were lower than the threshold value (10-5), suggesting that the cancer risk levels of PCDD/Fs in fly ash for onsite workers were acceptable. The 95th percentile non-carcinogenic risks (non-CRs) for onsite workers were lower than 1, suggesting no obvious non-carcinogenic effect was developed for onsite workers. This paper provide an overview information on the distribution of PCDD/Fs in fly ash during four seasons, and it could be used as an important fingerprint to distinguish the fly ash sources. Thus, the research could provide basic information for fly ash management in environment.

Composition profiles and health risk of PCDD/F in outdoor air and fly ash from municipal solid waste incineration and adjacent villages in East China.

In present study, composition profiles and health risk of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in outdoor air and fly ash from domestic waste treatment center (DWTC) were studied. In addition, the composition profiles and health risk of PCDD/F in outdoor air from adjacent villages were researched and used to quantitatively analyze the difference between onsite workers and adjacent villagers. Moreover, the difference between old intake method and new inhalation dosimetry method in the process of assessing the health risk of PCDD/Fs in outdoor air was quantitatively compared and analyzed. The results of this study were summarized as follows. (1) The 95th percentile carcinogenic risk (CR) and non-carcinogenic risk (non-CR) for onsite workers and adjacent villagers were much lower than the threshold values of 10(-6) and 1.0, respectively, suggesting no potential health risk. (2) The 95th percentile CR for onsite workers was 1.27×10(-8) and was 64.8 times higher than that of adjacent villagers (1.99×10(-10)). (3) The 95th percentile non-CR for onsite workers and adjacent villagers were 1.37×10(-4) and 1.31×10(-7), respectively. (3) Accidental ingestion of fly ash was the largest contributor to CR and non-CR for onsite workers, contributing 62.98% and 64.04% to CR and non-CR, respectively. (4) The CR and non-CR of PCDD/Fs in outdoor air for onsite workers and adjacent villagers which calculated by old intake method was much higher than the results from new inhalation dosimetry method. The results quantitatively showed the levels and potential risks of PCDD/Fs posed by a DWTC site, which can be helpful to predict the influence from DWTC sites and promote the management of DWTC in China.