Microplastics alter soil structural stability as quantified by high-energy moisture characteristics.

Microplastics (MiPs) can potentially influence soil structural stability, with impacts likely dependent on their chemistry, concentration, size, and degradation in soil. This study used high-energy moisture characteristics (HEMC; water retention at matric suctions from 0 to 50 hPa) to quantify the effects of these MiP properties on soil structure stabiltiy. The HEMCs of soil samples contaminated with polypropylene (PP) or polyethylene (PE) were measured and modelled. Greater MiP concentrations (2 % and 7 % w w-1) increased the volume of drainable pores (VDP). At smaller MiP concentrations (0.5 % and 1 % w w-1), larger MiP fibres (3 and 5 mm) exhibited higher VDP values compared to a smaller size (1.6 mm) across a range of concentrations. Both PE and PP MiPs increased the modal matric suction (hmodal). The impacts on VDP and hmodal were more pronounced for fast than slow wetting, likely due to MiPs fibres entangling around soil aggregates, and MiPs pores filling after aggregate slaking, respectively. Soil structural index (SI) and stability ratio (SR) values increased following MiP incorporation. Our findings revealed the detrimental impacts of MiPs on soil aggregates and pores, demonstrating that MiPs significantly influence HEMC parameters due to combined impacts on structure stability and pore distribution. ENVIRONMENTAL IMPLICATION: Microplastics have emerged as a major anthropogenic hazardous material in the soil environment, with secondary impacts on soil structure and aggregate stability. Our study indicates that MiPs alter water retention, pore distribution, and soil hydraulic properties, affecting soil's ability to retain and supply water. The introduction of MiPs leads to the destruction of soil aggregates and pores, compromising soil health and productivity. By characterising structural stability and pore structure dynamics using HEMC, this study highlights the sensitivity of MiP impacts, emphasizing the need for comprehensive assessment and strategies to preserve soil ecosystem functioning in the face of increasing MiP pollution.

Impact of grain roughness on residual nonwetting phase cluster size distribution in packed columns of uniform spheres.

We imaged the pore-scale distribution of air and water within packed columns of glass spheres of different textures using x-ray microcomputed tomography after primary drainage and after secondary imbibition. Postimbibition residual air saturation increases with roughness size. Clusters larger than a critical size of about 15 to 40 pores are distributed according to a power law, with exponents ranging from τ=2.29±0.04 to 3.00±0.13 and displaying a weak negative correlation with roughness size. The largest cluster constitutes 7 to 20% of the total residual gas saturation, with no clear correlation with roughness size. These results imply that activities that enhance grain roughness by, e.g., creating acidic conditions in the subsurface, will promote capillary trapping of nonwetting phases under capillary-dominated conditions. Enhanced trapping, in turn, may be desirable in some engineering applications such as geological CO_{2} storage, but detrimental to others such as groundwater remediation and hydrocarbon recovery.

Laboratory measurements of viscosity, density, and bulk contact angle on marble and soda lime glass for three naphthenic acid + n-decane solutions.

This paper presents static oil/brine contact angles measured using the sessile drop method on soda lime glass and polished marble. Pure n-decane and three 66 mM naphthenic acid solutions in n-decane were considered as model oils. Selected naphthenic acids were: cyclohexanecarboxylic acid (CHCA), cyclohexanebutyric acid (CHBA), and cyclohexanepentanoic acid (CHPA); all oils were dyed with Oil Red O (ORO) at a concentration of 0.9 mM. Also presented are complementary density and viscosity measurements by rotational viscometry at selected temperatures ranging from T = 16.00-28.00 °C. For the application of the data to interpret microfluidic experiments, see Tanino et al. [1] and Christensen et al. [2].

Recreating mineralogical petrographic heterogeneity within microfluidic chips: assembly, examples, and applications.

To date, the visualisation of flow through porous media assembled in microfluidic chips was confined to mineralogically homogenous systems. Here we present a key evolution in the method that permits the investigation of mineralogically realistic rock analogues.

Laminar-turbulent cycles in inclined lock-exchange flows.

We consider strongly confined, stably stratified shear flows generated as a lock exchange in a tube inclined at an angle of θ=45(∘). This paper focuses on a transitional regime, in which the flow alternates between two distinct states: laminar, parallel shear flow and intense transverse motion characteristic of turbulence. Laminar-turbulent cycles were captured at Atwood numbers At≡(ρ(2)-ρ(1))/(ρ(1)+ρ(2)) ranging from 2.45×10(-3) to 4.0×10(-3), where (ρ(1),ρ(2)) are the initial densities of the two fluids, with multiple cycles observed at At=2.55×10(-3). The evolution of the density and velocity fields in these flows was measured simultaneously using laser-induced fluorescence and particle image velocimetry. During each laminar-turbulent cycle, the axial velocity exhibits a distinctive ramp-cliff pattern, indicating that the flow accelerates as it relaminarizes, then decelerates rapidly as the Kelvin-Helmholtz billows break down. Within the range of experimental conditions, transverse stratification does not directly determine the onset of instability. Instead, the data suggest that a necessary criterion for the onset of instability is for the local Reynolds number to exceed 2200, with only a weak dependence on the Richardson number.