Insight into the 4-nitrophenol reduction, supercapacitive behavior, and antimicrobial activity of ZnCo2O4-rGO nanocomposite fabricated by the simple reflux method.

In this article, binary oxide ZnCo2O4 nanoparticles (NPs) have been developed on reduced graphene oxide surface by simple reflux condensation method. The physicochemical characteristics of the synthesized nanocomposite were computed using X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), and UV-Visible spectroscopy. The average size of ZnCo2O4 NPs is found to be about 9 nm. The synthesized nanocomposite was found to be an extremely efficient catalyst for reduction of 4-nitrophenol (4-NP) to produce 4-aminophenol (4-AP) and it is exhibited that about 98% 4-nitrophenol can be reduced in only 20 min. The nanocomposite behaves as supercapacitor due to possessing the specific capacitance value up to 609 F/g and excellent capacitance retention over 1000 cycles. The Brunauer-Emmett-Teller (BET) surface area analysis has been conducted to evaluate surface area and pore size of the synthesized material. The antimicrobial activity of this nanocomposite was performed against bacterial strains of Escherichia coli (E. coli), Bacillus subtilis (B. subtilis), and Staphylococcus aureus (S. aureus) and it is noticed to be a good antimicrobial agent against different bacterial strains.

Hydrogen peroxide-assisted photocatalytic dye degradation over reduced graphene oxide integrated ZnCr2O4 nanoparticles.

Zinc chromite nanoparticles (NPs) and zinc chromite-reduced graphene oxide (ZnCr2O4-rGO) nanocomposite have been synthesized by the combined effects of reflux condensation and calcination processes. The structural properties were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR), UV-visible studies, etc. Structural morphology was investigated by field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM) that indicate the formation of particles in the nanometer regime. The presence of the elements Zn, Cr, O and C has been confirmed by energy-dispersive X-ray spectroscopy (EDX) images which show the purity of the synthesized products. The photocatalytic activities of both as-prepared samples under visible light irradiation were investigated in presence of hydrogen peroxide (H2O2) and the results show that ZnCr2O4-rGO nanocomposite has a quite higher photo-activity response than virgin ZnCr2O4 NPs. The enhanced photo response indicates that, in ZnCr2O4, the photo-induced electrons favor to transfer to the rGO surface and the recombination of electron-hole pairs inhibited for which it results in the significantly increased photocatalytic activity for the ZnCr2O4-rGO photocatalyst and this phenomenon is also supported by the band gap value and photoluminescence results. Our outcomes demonstrate that ZnCr2O4-rGO nanocomposite is a more promising material to build up an efficient photocatalyst for waste water treatment.

Transformation of CuS/ZnS nanomaterials to an efficient visible light photocatalyst by 'photosensitizer' graphene and the potential antimicrobial activities of the nanocomposites.

We report the growth of CuS/ZnS (CZS) nanoparticles (NPs) on the graphene sheet by a facile green synthesis process. The CuS/ZnS-graphene (CZSG) nanocomposites exhibit enhanced visible light photocatalytic activity towards organic dye (methylene blue) degradation than that of CZS nanoparticles. To find the reason for the enhanced photo-activity, we propose a new photocatalytic mechanism where graphene in the CZSG nanocomposites acts as a 'photosensitizer' for CZS nanoparticles. This distinctive photocatalytic mechanism is noticeably different from all other previous research works on semiconductor-graphene hybrid photocatalysts where graphene behaves as an electron reservoir to capture the electrons from photo-excited semiconductor. This novel idea of the photocatalytic mechanism in semiconductor-graphene photocatalysts could draw a new track in thinking for designing of graphene-based photocatalysts for solving environmental pollution problems and they also show remarkable antimicrobial activities.