Frustration shapes multi-channel Kondo physics: a star graph perspective.

We study the overscreened multi-channel Kondo (MCK) model using the recently developed unitary renormalisation group technique. Our results display the importance of ground state degeneracy in explaining various important properties like the breakdown of screening and the presence of local non-Fermi liquids (NFLs). The impurity susceptibility of the intermediate coupling fixed point Hamiltonian in the zero-bandwidth (or star graph) limit shows a power-law divergence at low temperature. Despite the absence of inter-channel coupling in the MCK fixed point Hamiltonian, the study of mutual information between any two channels shows non-zero correlation between them. A spectral flow analysis of the star graph reveals that the degenerate ground state manifold possesses topological quantum numbers. Upon disentangling the impurity spin from its partners in the star graph, we find the presence of a local Mott liquid arising from inter-channel scattering processes. The low energy effective Hamiltonian obtained upon adding a finite non-zero conduction bath dispersion to the star graph Hamiltonian for both the two and three-channel cases displays the presence of local NFLs arising from inter-channel quantum fluctuations. Specifically, we confirm the presence of a local marginal Fermi liquid in the two channel case, whose properties show logarithmic scaling at low temperature as expected. Discontinuous behaviour is observed in several measures of ground state entanglement, signalling the underlying orthogonality catastrophe associated with the degenerate ground state manifold. We extend our results to underscreened and perfectly screened MCK models through duality arguments. A study of channel anisotropy under renormalisation flow reveals a series of quantum phase transitions due to the change in ground state degeneracy. Our work thus presents a template for the study of how a degenerate ground state manifold arising from symmetry and duality properties in a multichannel quantum impurity model can lead to novel multicritical phases at intermediate coupling.

The effect of antisite disorder on magnetic and exchange bias properties of Gd-substituted Y2CoMnO6double perovskite.

Combining experimental investigations and first-principles density functional theory (DFT) calculations, we report physical and magnetic properties of Gd-substituted Y2CoMnO6double perovskite, which are strongly influenced by antisite-disorder-driven spin configurations. On Gd doping, Co and Mn ions are present in mixed-valence (Co3+, Co2+, Mn3+and Mn4+) states. Multiple magnetic transitions have been observed: (i) paramagnetic to ferromagnetic transition is found to occur atTC= 95.5 K, (ii) antiferromagnetic transition atTN= 47 K is driven by3d-4fpolarization and antisite disorder present in the sample, (iii) change in magnetization belowT⩽20 K, primarily originating from Gd ordering, as revealed from our DFT calculations. AC susceptibility measurement confirms the absence of any spin-glass or cluster-glass phases in this material. A significantly large exchange bias effect (HEB= 1.07 kOe) is found to occur below 47 K due to interfaces of FM and AFM clusters created by antisite-disorder.

Dynamic chiral magnetic effect and anisotropic natural optical activity of tilted Weyl semimetals.

We study the dynamic chiral magnetic conductivity (DCMC) and natural optical activity in an inversion-broken tilted Weyl semimetal (WSM). Starting from the Kubo formula, we derive the analytical expressions for the DCMC for two different directions of the incident electromagnetic wave. We show that the angle of rotation of the plane of polarization of the transmitted wave exhibits remarkable anisotropy and is larger along the tilt direction. This striking anisotropy of DCMC results in anisotropic optical activity and rotary power, which can be experimentally observed as a topological magneto-electric effect of inversion-broken tilted WSMs. Finally, using the low energy Hamiltonian, we show that the DCMC follows the universal [Formula: see text] decay in the high frequency regime. In the low frequency regime, however, the DCMC shows sharp peaks at the tilt dependent effective chemical potentials of the left-handed and right-handed Weyl points. This can serve as a signature to distinguish between the type-I and type-II Weyl semimetals.

Slave rotor approach to exciton condensation in a two-band system.

We have studied exciton formation and condensation in an extended Falicov-Kimball model, going beyond the weak coupling approach, employing a semi-analytical technique: the slave-rotor mean-field theory (SRMF). In this essentially strong coupling theory, charge and spin (or orbital/pseudospin) degrees are treated as independent degrees of freedom, coupled by a local constraint. Using a two-site-extension of SRMF, we capture the effective many body scale beyond conventional mean-field theory. While the formation of excitons is favoured by the interband hybridization [Formula: see text], it is strongly influenced by the on-site Coulomb interaction [Formula: see text]. Beyond a critical hybridization, there is condensation of excitons, leading to a transition from a metal to an excitonic insulator phase. Moreover, the behaviour of excitonic averages differs from the usual Hartree-Fock mean-field theory. Low-[Formula: see text] results show that excitonic order parameter (Δ) is continuous across the transition both for single as well as two-site approximation, changing to weakly first order one at intermediate [Formula: see text] for the later. The large-[Formula: see text] limit shows a continuous transition for two-site analysis but remains first order in the single-site approximation. The slave rotor theory gives a mixed state of excitons and metal in both the analyses. We have also checked the effect of intersite correlation and localized band hopping on the exciton condensation.

Berry phase theory of planar Hall effect in topological insulators.

The appearance of negative longitudinal magnetoresistance (LMR) in topological semimetals such as Weyl and Dirac semimetals is understood as an effect of chiral anomaly, whereas such an anomaly is not well-defined in topological insulators. Nevertheless, it has been shown recently in both theory and experiments that nontrivial Berry phase effects can give rise to negative LMR in topological insulators even in the absence of chiral anomaly. In this paper, we present a quasi-classical theory of another intriguing phenomenon in topological insulators - also ascribed to chiral anomaly in Weyl and Dirac semimetals- the so-called planar Hall effect (PHE). PHE implies the appearance of a transverse voltage in the plane of applied non-parallel electric and magnetic fields, in a configuration in which the conventional Hall effect vanishes. Starting from Boltzmann transport equations we derive the expressions for PHE and LMR in topological insulators in the bulk conduction limit, and show the important role played by orbital magnetic moment. Our theoretical results for magnetoconductance with non-parallel electric and magnetic fields predict detailed experimental signatures in topological insulators - specifically of planar Hall effect - that can be observed in experiments.

Bulk band inversion and surface Dirac cones in LaSb and LaBi: Prediction of a new topological heterostructure.

We perform ab initio investigations of the bulk and surface band structures of LaSb and LaBi and resolve the existing disagreements about the topological property of LaSb, considering LaBi as a reference. We examine the bulk band structure for band inversion, along with the stability of surface Dirac cones (if any) to time-reversal-preserving perturbations, as a strong diagnostic test for determining the topological character of LaSb, LaBi and LaSb-LaBi multilayer. A detailed ab initio investigation of a multilayer consisting of alternating unit cells of LaSb and LaBi shows the presence of band inversion in the bulk and a massless Dirac cone on the (001) surface, which remains stable under the influence of time-reversal-preserving perturbations, thus confirming the topologically non-trivial nature of the multilayer in which the electronic properties can be tailored as per requirement. A detailed [Formula: see text] invariant calculation is performed to arrive at a holistic conclusion.

Antisite-disorder engineering in La-based oxide heterostructures via oxygen vacancy control.

It has been realized lately that disorder, primarily in the form of oxygen vacancies, cation stoichiometry, atomic inter-diffusion and antisite defects, has a major effect on the electronic and transport properties of a 2D electron liquid at oxide hetero-interfaces - the first and the last being the two key players. In order to delineate the roles of these two key factors, we have investigated the effect of oxygen vacancies on the antisite disorder at a large number of interfaces separating two La-based transition metal oxides, using density functional theory. The oxygen vacancy is found to suppress antisite disorder in some heterostructures thereby stabilizing the ordered structure, while in some others, it tends to favor disorder, opening up the possibility of using it to control the order. Our calculations show that the oxygen vacancy offers an opportunity to generate new magnetic states by manipulating the inter-site coupling. Moreover, it can be used to control the electrical transport. The oxygen vacancy and antisite disorder are intrinsic to oxide heterostructures and it is therefore incumbent to engineer the latter and tune the magnetic and transport properties by controlling the oxygen partial pressure during growth.

Nature of spiral state and absence of electric polarisation in Sr-doped YBaCuFeO5 revealed by first-principle study.

Experimental results on YBaCuFeO5, in its incommensurate magnetic phase, appear to disagree on its ferroelectric response. Ambiguity exists on the nature of the spiral magnetic state too. Using first-principles density functional theory (DFT) calculations for the parent compound within LSDA + U + SO approximation, we reveal the nature of spiral state. The helical spiral is found to be more stable below the transition temperature as spins prefer to lie in ab plane. Dzyaloshinskii-Moriya (DM) interaction turns out to be negligibly small and the spin current mechanism is not valid in the helical spiral state, ruling out an electric polarisation from either. These results are in very good agreement with the recent, high quality, single-crystal data. We also investigate the magnetic transition in YBa1-xSrxCuFeO5 for the entire range (0 ≤ x ≤ 1) of doping. The exchange interactions are estimated as a function of doping and a quantum Monte Carlo (QMC) calculation on an effective spin Hamiltonian shows that the paramagnetic to commensurate phase transition temperature increases with doping till x = 0.5 and decreases beyond. These observations are consistent with experimental findings.

Chiral Anomaly as the Origin of the Planar Hall Effect in Weyl Semimetals.

In condensed matter physics, the term "chiral anomaly" implies the violation of the separate number conservation laws of Weyl fermions of different chiralities in the presence of parallel electric and magnetic fields. One effect of the chiral anomaly in the recently discovered Dirac and Weyl semimetals is a positive longitudinal magnetoconductance. Here we show that chiral anomaly and nontrivial Berry curvature effects engender another striking effect in Weyl semimetals, the planar Hall effect (PHE). Remarkably, the PHE manifests itself when the applied current, magnetic field, and the induced transverse "Hall" voltage all lie in the same plane, precisely in a configuration in which the conventional Hall effect vanishes. In this work we treat the PHE quasiclassically, and predict specific experimental signatures for type-I and type-II Weyl semimetals that can be directly checked in experiments.

Dramatically Enhanced Superconductivity in Elemental Bismuth from Excitonic Fluctuation Exchange.

Motivated by the remarkable discovery of superconductivity in elemental Bismuth at ambient pressure, we study its normal state in detail using a combination of tight-binding (TB) band-structure supplemented by dynamical mean-field theory (DMFT). We show that a two-fluid model composed of preformed and dynamically fluctuating excitons coupled to a tiny number of carriers provides a unified rationalization of a range of ill-understood normal state spectral and transport data. Based on these, we propose that resonant scattering involving a very low density of renormalized carriers and the excitonic liquid drives logarithmic enhancement of vertex corrections, boosting superconductivity in Bi. A confirmatory test for our proposal would be the experimental verification of an excitonic semiconductor with electronic nematicity as a 'competing order' on inducing a semi-metal-to semiconductor transition in Bi by an external perturbation like pressure.

Medication Adherence in Kidney Transplant Recipients in an Urban Indian Setting.

Medication nonadherence is a known problem after renal transplantation and can vary from one setting to another. Since it can lead to negative outcomes, it is important to develop intervention strategies to enhance adherence in a given setting using determinants identified through exploratory studies. We explored nonadherence in renal transplant recipients. A longitudinal survey was done with adult renal transplant recipients at a tertiary care public and two private hospitals of Kolkata. Subjects were followed-up for 1 year. After screening for medication adherence status by the four-item Morisky Medication Adherence Scale, those admitting to potential nonadherence were probed further. A patient was deemed to be nonadherent if failing to take medicines on appointed time (doses missed or delayed by more than 2 h) more than three times in any month during the observation period. A pretested questionnaire was used to explore potential determinants of nonadherence. Data of 153 patients recruited over a 2-year were analyzed. The extent of nonadherence with immunosuppressant regimens was about 31% overall; 44% in the public sector and 19% in the private sector (P < 0.001). Nonadherence with other medication was around 19% in both the sectors. Several potential demographic, socioeconomic and psychosocial determinants of nonadherence were identified on univariate analysis. However, logistic regression analysis singled out only the economic status. This study had updated the issue of nonadherence in renal transplant recipients in the Indian setting. Strategies to improve medication adherence can be planned by relevant stakeholders on the basis of these findings.

First-Principles Correlated Approach to the Normal State of Strontium Ruthenate.

The interplay between multiple bands, sizable multi-band electronic correlations and strong spin-orbit coupling may conspire in selecting a rather unusual unconventional pairing symmetry in layered Sr2RuO4. This mandates a detailed revisit of the normal state and, in particular, the T-dependent incoherence-coherence crossover. Using a modern first-principles correlated view, we study this issue in the actual structure of Sr2RuO4 and present a unified and quantitative description of a range of unusual physical responses in the normal state. Armed with these, we propose that a new and important element, that of dominant multi-orbital charge fluctuations in a Hund's metal, may be a primary pair glue for unconventional superconductivity. Thereby we establish a connection between the normal state responses and superconductivity in this system.

Feasibility of a metamagnetic transition in correlated systems.

The long-standing issue of the competition between the magnetic field and the Kondo effect, favoring, respectively, triplet and singlet ground states, is addressed using a cluster slave-rotor mean-field theory for the Hubbard model and its spin-correlated, spin-frustrated extensions in two dimensions. The metamagnetic jump is established and compared with earlier results of dynamical mean-field theory. This approach also reproduces the emergent super-exchange energy scale in the insulating side. A scaling is found for the critical Zeeman field in terms of the intrinsic coherence scale just below the metal-insulator transition, where the critical spin fluctuations are soft. The conditions required for metamagnetism to appear at a reasonable field are also underlined. Gutzwiller analysis on the two-dimensional Hubbard model and a quantum Monte Carlo calculation on the Heisenberg spin system are performed to check the limiting cases of the cluster slave-rotor results for the Hubbard model. Low-field scaling features for magnetization are discussed.

The unusual normal state and charge-density-wave order in 2H-NbSe2.

Competition between collective states like charge-density-wave and superconductivity, unencumbered by the spin degrees of freedom, is played out in some of the transition metal dichalcogenides. Although 2H-NbSe2 has received much less attention than some of the other members of the family (such as 1T-TiSe2 and 2H-TaSe2) of late, it shows superconductivity at 7.2 K and incommensurate charge ordering at 33 K. Recent experiments, notably angle resolved photoemission spectroscopy, have cast serious doubts on the theories based on Fermi surface nesting and electron-phonon interaction. The normal state has been found to be a poor, incoherent metal and remarkably, the coherence increases in the broken symmetry state. From a preformed excitonic liquid scenario, we show that there exists a natural understanding of the experimental data on 2H-NbSe2, based on electron-electron interaction. The collective instabilities, in this scenario, are viewed as a condensation of an incoherent excitonic liquid already present at high temperature.

Oxygen vacancy clustering and pseudogap behaviour at the LaAlO3/SrTiO3 interface.

The two-dimensional electron gas at the LaAlO3/SrTiO3 interface promises to add a new dimension to emerging electronic devices due to its high degree of tunability. Defects in the form of oxygen vacancies in titanate surfaces and interfaces, on the other hand, play a key role in the emergence of the ordered states and their tunability at the interface. On the basis of an effective model, we study the influence of oxygen vacancies on the superconductivity and ferromagnetism at the LaAlO3/SrTiO3 interface. Using the Bogoliubov-de Gennes formulation in conjunction with Monte Carlo simulation, we find a clustering of the oxygen vacancies at the interface that favours the formation of coexisting ferromagnetic puddles spatially separated from the superconductivity. We also find a carrier freeze-out at low temperatures, observed experimentally in a wide variety of samples. A sufficiently large amount of oxygen vacancies leads to pseudogap-like behaviour in the superconducting state.

Phase segregation of superconductivity and ferromagnetism at the LaAlO3/SrTiO3 interface.

The highly conductive two-dimensional electron gas formed at the interface between insulating SrTiO3 and LaAlO3 shows low-temperature superconductivity coexisting with inhomogeneous ferromagnetism. The Rashba spin-orbit interaction with the in-plane Zeeman field of the system favors p(x) ± ip(y)-wave superconductivity at finite momentum. Owing to the intrinsic disorder at the interface, the role of spatial inhomogeneity in the superconducting and ferromagnetic states becomes important. We find that, for strong disorder, the system breaks up into mutually excluded regions of superconductivity and ferromagnetism. This inhomogeneity-driven electronic phase separation accounts for the unusual coexistence of superconductivity and ferromagnetism observed at the interface.

Metallicity and ferromagnetism in nanosystem of charge ordered Nd0.5Sr0.5MnO3.

The fascinating phenomenon of destabilization of charge/orbital order in Nd0.5Sr0.5MnO3 with the reduction of grain size is critically investigated. Based on our magnetic and transport experiments followed by a theoretical analysis, we analyze various possible mechanisms and try to delineate a universal scenario behind this phenomenon. We revisit this issue carefully and discuss various evidences from experiments in nano and bulk manganites on the absence of correlation between size reduction and pressure effects on manganites. We propose a phenomenological model based on enhanced surface disorder to explain the appearance of weak ferromagnetism and metallicity in nanosize Nd0.5Sr0.5MnO3 system. All evidence seems to suggest that the transport is mediated through the surface via enhanced density of states in the nanometric grains. We provide theoretical support for this by performing an ab-initio electronic structure calculation as well as from a recent numerical simulation and argue that the mechanism is likely to be general in all nanosize charge ordered manganites.

Quantum critical phase and Lifshitz transition in an extended periodic Anderson model.

We study the quantum phase transition in f-electron systems as a quantum Lifshitz transition driven by selective-Mott localization in a realistic extended Anderson lattice model. Using dynamical mean-field theory (DMFT), we find that a quantum critical phase with anomalous ω/T scaling separates a heavy Landau-Fermi liquid from ordered phase(s). This non-Fermi liquid state arises from a lattice orthogonality catastrophe originating from orbital-selective Mott localization. Fermi surface reconstruction occurs via the interplay between and penetration of the Green function zeros to the poles, leading to violation of Luttinger's theorem in the strange metal. We show how this naturally leads to scale-invariant responses in transport. Thus, our work represents a specific DMFT realization of the hidden-FL and FL* theories, and holds promise for the study of 'strange' metal phases in quantum matter.

Preformed excitonic liquid route to a charge density wave in 2H-TaSe2.

Recent experiments on 2H-TaSe(2) contradict the long-held view of the charge density wave arising from a nested band structure. An intrinsically strong coupling view, involving a charge density wave state arising as a Bose condensation of preformed excitons emerges as an attractive, albeit scantily investigated alternative. Using the local density approximation plus multiorbital dynamic mean field theory, we show that this scenario agrees with a variety of normal state data for 2H-TaSe(2). Based thereupon, the ordered states in a subset of dichalcogenides should be viewed as instabilities of a correlated, preformed excitonic liquid.