Effective sequestration of Cr (VI) from wastewater using nanocomposite of ZnO with cotton stalks biochar: modeling, kinetics, and reusability.

The disposal of chromium (Cr) containing wastewater in surface water bodies without prior treatment is a serious threat to humans, animals, and plants. A novel nanocomposite (CSB/ZnO) of cotton stalks biochar (CSB) with ZnO nanoparticles was synthesized for the removal of Cr (VI) ions from contaminated water at batch scale. The impact of adsorbent dosage (1-4 g/L), initial Cr (VI) levels (25-200 mg/L), pH (2-8), and interaction time (0-180 min) was assessed for the removal of Cr (VI) from contaminated water. The Fourier-transform infrared (FTIR), scanning electron microscopy (SEM), and point of zero charge (PZC) characterization showed successful impregnation of ZnO particles on CSB with improved surface characteristics. The maximum adsorption (qmax) of CSB and CSB/ZnO was 54.95 and 107.53 mg Cr/g, respectively that is relatively higher than various previously studied adsorbents. The experimental isothermal data better fitted with the Freundlich model in comparison with other isotherm models while adsorption kinetics well corroborated with the pseudo-second-order model. The results revealed that doping of biochar with metallic nanoparticles (CSB/ZnO) proved very effective (99.6% at 50 mg/L) with high reusability (91%) after five adsorption/desorption cycles and seems a suitable strategy for the decontamination of Cr (VI) contaminated waters.

Synthesis of magnetite-based nanocomposites for effective removal of brilliant green dye from wastewater.

The present study aims at evaluating the batch scale potential of cotton shell powder (CSP), Moringa oleifera leaves (ML), and magnetite-assisted composites of Moringa oleifera leaves (MLMC) and cotton shell powder (CSPMC) for the removal of brilliant green dye (BG) from synthetic wastewater. This is the first attempt to combine biosorbents with nanoparticles (NPs) for the removal of BG. The surface properties of ML, CSP, and their composites were characterized with Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and energy-dispersive X-ray (EDX). The impact of dosage of the adsorbents (1-4 g/L), initial concentrations of BG (20-320 mg/L), pH (6-12), and contact time (15-180 min) on BG removal was evaluated. The BG removal was in order of CSPMC > MLMC > CSP > ML (98.8-86.6% > 98.2-82.0% > 92.3-70.7% > 89.0-57.4%) at optimum dosage (2 g/L) and pH (8). Moreover, maximum adsorption (252.17 mg/g) was obtained with CSPMC. The experimental results showed better fit with Freundlich adsorption isotherm model and kinetic data revealed that sorption followed pseudo-second-order kinetic model. The values of Gibbs free energy and mean free energy of sorption showed that physical adsorption was involved in the removal of BG. FTIR results confirmed that -O-H, -C-OH, =C-H, -C-H, =-CH3, HC ≡ CH, C=C, -C=O, -C-N, and -C-O-C- groups were involved in the removal of BG. The results revealed that application of low-cost biosorbents combined with NPs is very effective and promising for the removal of textile dyes from wastewater.