1.
ACS Appl Mater Interfaces
; 2(1): 7-10, 2010 Jan.
Artigo
em Inglês
| MEDLINE
| ID: mdl-20356212
RESUMO
Signal amplification has been demonstrated with surface-bound electrochromic complexes that can exist in one of two oxidation states (M2+/3+). Reaction of FeCl3 with covalently immobilized Os2+ complexes on glass substrates converts the metal centers from one oxidation state to the other. The formed Fe2+ reduces a series of Ru3+-based monolayers. The absorption of light is coupled with the oxidation state of the complexes and provides the output for the monolayer-based device. The gain of the setup can be controlled by the addition of a Fe2+ chelating ligand.
Assuntos
Cloretos/química , Compostos Férricos/química , Quelantes de Ferro/química , Osmio/química , Rutênio/química , Oxirredução
2.
Angew Chem Int Ed Engl
; 49(1): 169-72, 2010.
Artigo
em Inglês
| MEDLINE
| ID: mdl-19921670