Health risk assessment of soil trace elements using the Sequential Gaussian Simulation approach.

In this study, the performance of the Sequential Gaussian Simulation (SGS) approach was studied with the aim of accurately determining local health risk distributions associated with trace elements (V, Cr, Mn, Co, Ni, Cu, Zn, As, and Pb). This study plays a crucial role in determining the distribution of health risk levels, especially from heavy metals. In the SGS approach, health risk levels (non-carcinogenic and carcinogenic) were calculated for pixel sizes of 250 × 250 m2. Results were compared to the conventional Ordinary Kriging (OK) method. The cross-validation performances of both methods were compared. Non-carcinogenic health risks calculated according to SGS and OK for children were, respectively, ρc: 0.57 and 0.23, RMSE: 0.45 and 0.57, and MAE: 0.33 and 0.43. In the case of adults, non-carcinogenic SGS and OK results were, respectively, ρc: 0.53 and 0.24, RMSE: 0.06 and 0.07, and MAE: 0.04 and 0.05 for adults. Carcinogenic health risk estimates obtained by SGS and OK were, respectively, ρc: 0.72 and 0.31, RMSE: 4.1 × 10-5 and 5.8 × 10-5, and MAE: 3.2 × 10-5 and 4.3 × 10-5 in the case of children, and in the case of adults the results were, respectively, ρc: 0.71 and 0.30, RMSE: 5 × 10-6 and 4.3 × 10-6, and MAE: 4 × 10-6 and 5 × 10-6. These results indicated that SGS offered a more accurate approach in determining health risk distributions.

Determination of radioactivity level of water supply network in Trabzon province, Turkey.

In the present study, the radioactivity levels of water samples collected from the main water supply network in Trabzon province and districts and soil samples taken from the vicinity of the water network were measured. An Alphaguard-PQ2000 radon gas detector was used to determine the seasonal radon gas level in the water samples. An HPGe detector was used to determine the level of radioactivity in soil and water samples. The average concentration of 222Rn in drinking water ranges from 0.56 ± 0.51 to 13.3 ± 5 Bq L-1. In water samples, average gross alpha and gross beta values were measured as 8 ± 1 and 43 ± 1 mBq L-1, respectively. The average concentrations of 238U, 232Th, 137Cs, 40K radionuclides in soil were measured as 51 ± 2, 21 ± 2, 16 ± 1, 28 ± 7 Bq m-3, respectively. The average concentrations of 238U, 232Th, 137Cs, 40K radionuclides in drinking water were measured as 147 ± 5, 25 ± 2, 77 ± 2, 12 ± 2 mBq L-1, respectively. When the radon concentrations for drinking water were examined, it was found that the radon concentration of the three samples was above the limit value (11 Bq L-1) allowed by the US-EPA for drinking water. All other results are below the limit values.

Trace element-based geochemical contamination characteristics and potential risks to human health: a case study from Northeast Turkey.

Trace elements measured in Artvin province soil samples in Northeast Turkey were assessed using pollution and health indices. The study area is positioned in one of the essential metallogenic belts in Turkey. This attempt is the first endeavor toward the study area in this context. The measured trace elements are As, Co, Cr, Cu, Mn, Ni, Pb and Zn, as they were assessed using pollution indices, enrichment factor, geo-accumulation index, contamination factor, and health risk assessment methods. According to the results of enrichment factor (EF), geo-accumulation index (Igeo), and contamination factor (CF), the soils of Artvin province show a slightly severe enrichment, moderately polluted and very high contaminated with arsenic, respectively. The pollution load index score (PLI) index (1.57) indicates that Artvin province is polluted in terms of trace elements. The hazard index (HI) calculated values for children and adults were 1.55 and 0.18, respectively. This revealed that the aforementioned metals can have non-carcinogenic effects (HI > 1). Total potential carcinogenic health risk (TCR) values for children and adults were 3.22 × 10-5 and 1.40 × 10-5, respectively. The non-carcinogenic risk level indicates that there may be a risk for children rather than adults.

Comparison of active and passive radon survey in cave atmosphere, and estimation of the radon exposed dose equivalents and gamma absorbed dose rates.

Radon (222Rn) measurements were conducted in the Pileki Cave with Radim 3A Active Radon Monitor equipment. Measurements were also done with the passive sampling method with CR-39 nuclear track detectors by exposing them for three months in the cave. Radon concentrations obtained from the active and passive sampling methods showed that, firstly, the concentrations inside the cave measured by the latter method differed greatly due to high humidity levels up to 88%. The total inside radon exposure dose equivalent people were subjected to was estimated to be 19 µSv a-1 for visitors and 24,065 µSv a-1 for guides. The gamma absorbed dose rates were determined for inside and outside the cave. The dose rates were calculated by means of using the 226Ra, 232Th and 40K activity concentrations and by means of real-time measurements. The gamma absorbed dose rates were found to be much higher than the value of 55 nGy h-1 given by UNSCEAR. In addition, the mineralogical compositions and elemental analyses of samples taken from the cave were determined by XRD and WD-XRF methods.

Indoor and outdoor radon measurements at lung cancer patients' homes in the dwellings of Rize Province in Turkey.

In this study, indoor and outdoor radon (222Rn) surveys were carried out in the summer and winter seasons in homes of one hundred lung cancer patients in the year 2013-2014. The aim was to investigate the relationship between radon and cancer patients. Lung cancer patients completed a questionnaire concerning their living environment, various physical parameters and living habits. Pearson correlation and t tests revealed no meaningful results between radon concentrations, on one hand, and environmental and personal living habits, on the other hand. Consequently, the BEIR VI model was adapted and 222Rn exposure was estimated to be responsible for about 12% of the lung cancer incidences in the winter season and around 5% in the summer season in the Rize Province. However, due to the limited number of data and numerous parameters that could lead to lung cancer, the estimations done with the model should be taken very lightly. The annual effective doses due to inhalation of indoor and outdoor 222Rn were estimated to be, respectively, 1.43 and 0.94 mSv y-1. The indoor and outdoor annual effective doses were, respectively, close and below the world annual effective dose (1.3 mSv y-1). At the district level, the indoor annual effective dose equivalent in the Iyidere district was 4.52 mSv y-1, which was 3.5 times greater than the world average. The number of patients in the majority of the houses in this district was more than one.

Spatial interpolation and radiological mapping of ambient gamma dose rate by using artificial neural networks and fuzzy logic methods.

The aim of this study was to determine spatial risk dispersion of ambient gamma dose rate (AGDR) by using both artificial neural network (ANN) and fuzzy logic (FL) methods, compare the performances of methods, make dose estimations for intermediate stations with no previous measurements and create dose rate risk maps of the study area. In order to determine the dose distribution by using artificial neural networks, two main networks and five different network structures were used; feed forward ANN; Multi-layer perceptron (MLP), Radial basis functional neural network (RBFNN), Quantile regression neural network (QRNN) and recurrent ANN; Jordan networks (JN), Elman networks (EN). In the evaluation of estimation performance obtained for the test data, all models appear to give similar results. According to the cross-validation results obtained for explaining AGDR distribution, Pearson's r coefficients were calculated as 0.94, 0.91, 0.89, 0.91, 0.91 and 0.92 and RMSE values were calculated as 34.78, 43.28, 63.92, 44.86, 46.77 and 37.92 for MLP, RBFNN, QRNN, JN, EN and FL, respectively. In addition, spatial risk maps showing distributions of AGDR of the study area were created by all models and results were compared with geological, topological and soil structure.

Radioactivity measurements and risk assessments of spa waters in some areas in Turkey.

The current study presents the results of the activity of radionuclides in spa waters, and evaluates their radiological influences on the population consuming these waters in the Central and Eastern Black Sea regions of Turkey. Since these waters are used for therapy and consumption purposes unconsciously, their radiological impact on the people was computed by taking into consideration the annual intake through ingestion of 226Ra, 232Th, 40K, 137Cs and 222Rn. The mean activities were estimated to be 11.35 for gross alpha, 6.23 for gross beta, 2.96 for 226Ra, 0.42 for 232Th, 0.069 for 137Cs, 0.19 for 40K, and 267 Bq L-1 for 222Rn, respectively. The estimated effective doses from spa water were found to be 49.77 µSv a-1 (226Ra), 5.95 µSv a-1 (232Th), 0.07 µSv a-1 (137Cs), 0.83 µSv a-1 (40K) and 56.03 µSv a-1 (222Rn). These values were evaluated and compared with related verified values from literature. Also, physico-chemical characterizations of spa water samples considered in the current study were investigated. This study would be useful for consumers and official authorities for the assessment of radiation exposure risk due to usage of the considered spa waters.

Distribution and environmental impacts of heavy metals and radioactivity in sediment and seawater samples of the Marmara Sea.

In this study, the natural and anthropogenic radioactivity levels in the sediment samples collected from the Marmara Sea in Turkey were determined. The average activity concentrations (range) of (226)Ra, (238)U, (232)Th, (40)K and (137)Cs were found to be 23.8 (13.8-34.2) Bq kg(-1), 18.8 (6.4-25.9) Bq kg(-1), 23.02 (6.3-31.1) Bq kg(-1), 558.6 (378.8-693.6) Bq kg(-1) and 9.14 (4.8-16.3) Bq kg(-1), respectively. Our results showed that the average activity concentrations of (226)Ra, (238)U and (232)Th in the sediment samples were within the acceptable limits; whereas the average activity concentration of (40)K in the sediment samples was higher than the worldwide average concentration. The average radium equivalent activity, the average absorbed dose rate and the average external hazard index were calculated as 100.01 Bq kg(-1), 48.32 nGy h(-1) and 0.27, respectively. The average gross alpha and beta activity in the seawater samples were found to be 0.042 Bq L(-1) and 13.402 Bq L(-1), respectively. The gross alpha and beta activity concentrations increased with water depth in the same stations. The average heavy metal concentrations (range) in the sediment samples were 114.6 (21.6-201.7) µg g(-1) for Cr, 568.2 (190.8-1625.1) µg g(-1) for Mn, 39.3 (4.9-83.4) µg g(-1) for Cu, 85.5 (11.0-171.8) µg g(-1) for Zn, 32.9 (9.1-73.1) µg g(-1) for Pb and 49.1 (6.8-103.0) µg g(-1) for Ni. S5 station was heavily polluted by Cr, Cu, Ni and Pb. The results showed that heavy metal enrichment in sediments of the Marmara Sea was widespread.

Dose rate estimates and spatial interpolation maps of outdoor gamma dose rate with geostatistical methods; A case study from Artvin, Turkey.

In this study, compliance of geostatistical estimation methods is compared to ensure investigation and imaging natural Fon radiation using the minimum number of data. Artvin province, which has a quite hilly terrain and wide variety of soil and located in the north-east of Turkey, is selected as the study area. Outdoor gamma dose rate (OGDR), which is an important determinant of environmental radioactivity level, is measured in 204 stations. Spatial structure of OGDR is determined by anisotropic, isotropic and residual variograms. Ordinary kriging (OK) and universal kriging (UK) interpolation estimations were calculated with the help of model parameters obtained from these variograms. In OK, although calculations are made based on positions of points where samples are taken, in the UK technique, general soil groups and altitude values directly affecting OGDR are included in the calculations. When two methods are evaluated based on their performances, it has been determined that UK model (r = 0.88, p < 0.001) gives quite better results than OK model (r = 0.64, p < 0.001). In addition, as a result of the maps created at the end of the study, it was illustrated that local changes are better reflected by UK method compared to OK method and its error variance is found to be lower.

Natural radioactivity in bottled mineral and thermal spring waters of Turkey.

Radiological assessment of bottled mineral waters and thermal spring waters collected from various natural sources in Turkey was carried out using gross alpha and gross beta counting techniques. For 40 samples of bottled mineral water, the mean gross alpha activity concentration was determined to be 164 mBq l(-1) (min.:7 mBq l(-1); max.: 3042 mBq l(-1)), whereas the gross beta activity concentration was found to be 555 mBq l(-1) (min.: 21 mBq l(-1); max.: 4845 mBq l(-1)). For 24 samples of thermal spring water, the mean gross alpha activity concentration was obtained to be 663 mBq l(-1) (min.: 18 mBq l(-1); max.: 3070 mBq l(-1)). The gross beta activity concentration for these samples, on the other hand, was determined to be 3314 mBq l(-1) (min.: 79 mBq l(-1); max.: 17955 mBq l(-1)). These values lead to the average annual effective doses of 313 µSv for mineral waters and 1805 µSv for thermal spa waters, which are found to be higher than those recommended for drinking waters by the World Health Organization. It should be noted, however, that one will get less dose from mineral waters since the daily consumption is much lower than 2 l that these calculations assume.

Assessment of natural radioactivity concentrations and gamma dose rate levels in Kayseri, Turkey.

This study assesses the level of background radiation for Kayseri province of Turkey. Natural radionuclide activity concentrations in soil samples were determined using high-resolution gamma spectroscopy. Outdoor gamma dose measurements in air at 1 m above ground level were determined using a portable gamma scintillation detector. The obtained results of uranium and thorium series as well as potassium ((40)K) are discussed. The present data were compared with the data obtained from different areas in Turkey. From the measured gamma-ray spectra, the average activity concentrations were determined for (238)U (range from 3.91 to 794.25 Bq kg(-1)), (232)Th (range from 0.68 to 245.55 Bq kg(-1)) and (40)K (range from 23.68 to 2718.71 Bq kg(-1)). The average activity concentrations of (238)U, (232)Th and (40)K were found to be 35.51, 37.27 and 429.66 Bq kg(-1), respectively, and 11.53 Bq kg(-1) for the fission product (137)Cs. The highest values of (238)U, (232)Th and (40)K concentrations (794.25 Bq kg(-1), 245.55 Bq kg(-1), 2718.71 Bq kg(-1), respectively) were observed in abnormal samples at Hayriye village. The average outdoor gamma dose rate in air at 1 m above the ground was determined as 114.43 nGy h(-1). Using the data obtained in this study, the average annual effective dose for a person living in Kayseri was found to be about 140.34 µSv.

A study of environmental radioactivity measurements for Cankiri, Turkey.

This study is the first to assess the level of background radiation for the Cankiri province of Turkey. Indoor air radon concentrations were determined using Columbia Resin-39 nuclear track detectors and the average (222)Rn activity was found to be 44 Bq m(-3) (equivalent to an annual effective dose of 1.1 mSv). Measurements of gamma doses in outdoor air were performed using a portable plastic scintillation detector and the average gamma absorbed dose rate was found to be 8 µR h(-1) (corresponding to an annual effective dose of 87.7 µSv). Radionuclide activity concentrations in soil samples were measured through gamma-ray spectrometry and the average activities were determined as 17.7, 22.3, 357 and 4.1 Bq kg(-1) for the radionuclides (238)U, (232)Th, (40)K and (137)Cs, respectively. The average annual effective dose from the natural radioactivity sources ((238)U series, (232)Th series and (40)K) was calculated to be 44.4 µSv. Radioactivity levels of drinking water samples were carried out using a low-background proportional counter and the average gross alpha and beta activities were obtained as 0.25 and 0.26 Bq l(-1), respectively (equivalent to an annual effective dose of 184 µSv). The average radon concentrations in indoor air and the average radionuclide activities in soil were found to be lower than most Turkish cities while higher levels of outdoor gamma dose rate and water radioactivity were observed. The results of this study showed that the region's background radioactivity level differs considerably from the reported data for Turkish cities.

Determination of the health hazards due to background radiation sources in the city of Adapazari, Northwestern Turkey.

Human body is exposed to ionising radiations both internally and externally by mainly high-energy cosmic ray particles incident on the earth's atmosphere and radioactive nuclides that originated in the earth's crust. The main objective of this study is to assess the health hazards due to environmental radiation sources in the city of Adapazari, one of the most important industrial cities of the country, Northwestern Turkey. For this purpose, natural radiation sources, external terrestrial radiations, cosmic radiations, and inhalation exposures have been investigated. The annual average external terrestrial radiation doses were determined as 0.08 and 0.35 mSv at outdoor and indoor atmospheres, respectively. The annual average cosmic radiation doses were found to be 0.08 and 0.05 mSv for directly ionising photon components and neutron components, respectively. The annual average inhalation exposure doses due to radon and thoron were obtained as 1.42 and 0.19 mSv, respectively, in the region. The annual average effective dose due to natural radiation sources was determined as a total of 2.35 mSv with the predetermined ingestion radiation dose. The lifetime cancer risk due to the background ionising radiations has been determined as 0.9×10(-2) for the residents of the Adapazari city, with the average lifespan of 70 years. The results of the effective doses due to background radiation sources in the region and the worldwide averages were discussed.

Initiation of bone and amnion banking in Turkey.

There is a growing demand in Turkey for human tissue to use in surgery and wound healing. However, our country does not have facilities for local production of tissue grafts and generally depends on imported products. Under a multi-year project initiated in 1997, the International Atomic Energy Agency has provided main equipment for tissue processing and experts on Tissue Banking as well as training on tissue processing methods.In this presentation, information on various stages of the project implementation is given. Details of lay out for the process laboratories and equipment are given. Donor selection and testing criteria, processing procedures for bone and amnion, setting up product design, implementation of quality system and radiation sterilisation are described briefly. Quality procedures included preparation of quality manual, record forms, document control, non-conformance and corrective actions, training records, equipment maintenance and calibration are all in line with GMP/GLP Standards. Clinical applications of tissue grafts and medico-legal position of organ and tissue donation in Turkey are also discussed briefly.