RESUMO
The mononuclear title molecule, [Sn(C(7)H(6)F)(2)(C(3)H(3)N(2)S(3))(2)], has 2 symmetry. The Sn(IV) atom, located on a twofold rotation axis, is in a skew trapezoidal-bipyramidal geometry, with the basal plane defined by two S,N-chelating 3-methyl-sulfanyl-1,2,4-thia-diazole-5-thiol-ate ligands. The apical positions are occupied by the C atoms of two 4-fluoro-benzyl groups.
RESUMO
In the title complex, [Sn(C(2)H(2)ClO(2))(2)(C(7)H(6)F)(2)], the Sn(IV) atom is located on a twofold rotation axis and forms a strongly distorted trans-octa-hedral geometry. The equatorial plane is defined by two chelating chloro-acetate ligands with asymmetrical Sn-O bond lengths, while the axial positions are occupied by the C atoms of two 2-fluoro-benzyl groups. In the crystal, infinite chains in the [010] direction are formed through inter-molecular Snâ¯O inter-actions [Snâ¯O separation = 3.682â (3)â Å].