1.
Conversion of haloform to carbonate by iridium N-heterocyclic carbene complexes and silver(i) oxide.
Dalton Trans
; 48(6): 1947-1949, 2019 Feb 05.
Artigo
em Inglês
| MEDLINE
| ID: mdl-30637429
RESUMO
The reaction between haloform, the complexes [Cp*IrCl2(κC-MeNC3H2NCH2Ar)] (Ar = C6H3F2-2,6, C6H3F-2-Cl-6, C6H3Me2-2,6) and silver(i) oxide proceeded by carbon-halogen bond fission to yield the carbonate complexes [Cp*Ir(κ2O-CO3)(κC-MeNC3H2NCH2Ar)].
