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1.
Acta Crystallogr Sect E Struct Rep Online ; 65(Pt 4): o698, 2009 Mar 06.
Artigo em Inglês | MEDLINE | ID: mdl-21582438

RESUMO

In the title compound, C(14)H(15)NO, the seven-membered ring exhibits a slightly distorted twist-boat conformation. The pyrrole ring forms a dihedral angle of 1.44 (10)° with the fused benzene ring. N-H⋯O hydrogen bonds form a centrosymmetric dimer and weak C-H⋯π inter-actions are also found in the crystal structure.

2.
Acta Crystallogr Sect E Struct Rep Online ; 65(Pt 4): o830, 2009 Mar 25.
Artigo em Inglês | MEDLINE | ID: mdl-21582550

RESUMO

The mol-ecule of the title compound, C(17)H(13)NO(2), is nearly planar, the r.m.s. deviation for all non-H atoms excluding the two methyl C atoms being 0.089 Å. Inter-molecular N-H⋯O and C-H⋯O hydrogen bonds are found in the crystal structure. C-H⋯π inter-actions are also found. The H atoms of the methyl group attached to the benzene ring are disordered equally over two positions.

3.
Acta Crystallogr Sect E Struct Rep Online ; 65(Pt 8): o1946-7, 2009 Jul 22.
Artigo em Inglês | MEDLINE | ID: mdl-21583627

RESUMO

In the title mol-ecule, C(13)H(13)NO, the dihedral angle between the benzene ring and the fused pyrrole ring is 2.03 (5)°. The methyl group at the 3-position has an equatorial orientation. The cyclo-hexene ring adopts an envelope conformation. Three C atoms of the cyclo-hexene ring, with their attached H atoms, and all atoms of the methyl group are disordered over two positions, the site-occupancy factors being 0.883 (2) and 0.117 (2). In the crystal structure, mol-ecules are stabilized by inter-molecular N-H⋯O hydrogen bonds. A C-H⋯π inter-action, involving the benzene ring, is also found.

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