RESUMO
In the mol-ecule of the title compound, C(20)H(16)N(2)O(2), two intra-molecular N-Hâ¯O inter-actions occur. The mol-ecular chains are linked by N-Hâ¯π and C-Hâ¯π inter-actions into a three-dimensional network, which seems to be very effective in the stabilization of the crystal structure.
RESUMO
In the title compound, C(10)H(8)N(6)·2H(2)O, the central aromatic ring makes dihedral angles of 23.59â (15) and 16.99â (16)° with the terminal imidazole and tetra-zole rings, respectively, which are themselves almost coplanar [dihedral angle = 6.61â (18)°]. Two H atoms of the two water mol-ecules are half occupied. In the crystal packing, weak inter-molecular O-Hâ¯N, O-Hâ¯O and N-Hâ¯N hydrogen bonds and π-π stacking inter-actions [centroid-centroid distances of 3.73â (4)â Å between benzene rings and 3.66â (3)â Å between imidazole and tetra-zole rings] are observed.
RESUMO
The title compound, [Zn(H(2)O)(6)](C(16)H(12)O(6))·H(2)O, consists of one 4,4'-(1,2-dihy-droxy-ethane-1,2-di-yl)dibenzoate anion lying on an inversion centre, one [Zn(H(2)O)(6)](2+) dication lying on a mirror plane and one solvent water mol-ecule located on a mirror plane. The octahedral [Zn(H(2)O)(6)](2+) cations, solvent water mol-ecules and anions inter-act via O-Hâ¯O hydrogen bonds, forming a three-dimensional network.
RESUMO
In the centrosymmetric dinuclear title complex, [Zn(2)(C(13)H(19)N(4)O)(2)(C(2)H(5)OH)(2)](ClO(4))(2), the Zn(II) atom is in a distorted trigonal-bipyramidal coordination geometry. The equatorial plane is constructed by one N atom and one O atom from two 1,3-bis-(3,5-dimethyl-pyrazol-1-yl)propan-2-olate (bppo) ligands and one O atom from an ethanol mol-ecule. One N atom and one O atom from the two bppo ligands occupy the axial positions. Inter-molecular O-Hâ¯O hydrogen bonds between the ethanol mol-ecules and perchlorate anions, and Oâ¯π inter-actions between the perchlorate anions and pyrazole rings [Oâ¯centroid distances = 3.494â (3) and 3.413â (3)â Å], lead to a chain structure along [010].