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1.
A Scandium Carbide Endohedral Metallofullerene: (Sc(2)C(2))@C(84) H.S. thanks the JSPS for Future Program on New Carbon Nano-Materials for financial support of the present study. The synchrotron radiation experiments were performed at SPring-8 BL02B2 with the approval of the Japan Synchrotron Radiation Research Institute (JASRI).
Wang, Chun-Ru; Kai, Tsutomu; Tomiyama, Testuo; Yoshida, Takuya; Kobayashi, Yuji; Nishibori, Eiji; Takata, Masaki; Sakata, Makoto; Shinohara, Hisanori.
Angew Chem Int Ed Engl ; 40(2): 397-399, 2001 Jan 19.
Artigo em Inglês | MEDLINE | ID: mdl-11180336
2.
A Scandium Carbide Endohedral Metallofullerene: (Sc2 C2 )@C84.
Wang, Chun-Ru; Kai, Tsutomu; Tomiyama, Testuo; Yoshida, Takuya; Kobayashi, Yuji; Nishibori, Eiji; Takata, Masaki; Sakata, Makoto; Shinohara, Hisanori.
Angew Chem Int Ed Engl ; 40(2): 397-399, 2001 Jan 19.
Artigo em Inglês | MEDLINE | ID: mdl-29712386

RESUMO

Not Sc2 @C86 but Sc2 C2 @C84 : that is the conclusion of 13 C NMR spectroscopic and synchrotron X-ray powder diffraction studies on a new metallofullerene obtained by arc discharge of Sc2 O3 /graphite rods. The picture shows a schematic representation of the deduced structure, in which the novel scandium carbide cluster Sc2 C2 is encaged in D2d -C84 .

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