Effect of extrusion parameters on the interaction between rice starch and glutelin in the preparation of reconstituted rice.

Reconstituted rice produced by extrusion has been attracted attention due to nutritional fortification and convenient production. Nevertheless, how to achieve desirable qualities and physicochemical properties of reconstituted rice nearly to natural rice by regulating extrusion process parameters is difficult. Herein, rice starch/glutelin mixture as raw material of reconstituted rice was extruded at varying extrusion conditions. Specific mechanical energy (SME) and sectional expansion index (SEI) dropped with rise in density (R2 = 0.9117 and 0.8207). Solubility was enhanced with increase in product temperature (R2 = 0.9085), color darkened and shifted to reddish and yellowish as extrusion temperature increased (R2 = 0.8577). These trends were well fitted by sigmoid models. Furthermore, SME enhanced hydrophobic and electrostatic interactions between rice starch and glutelin and caused the reduction in crystallinity and thermal stability, promoting the formation of a bi-continuous matrix of protein aggregates with rice starch. The obtained results can be applied to guide the production of reconstituted rice with desirable qualities.

Insights into the interaction mechanism of glutelin and rice starch during extrusion processing: The role of specific mechanical energy.

Extruded glutelin/rice starch composites were prepared using twin-screw extrusion at various specific mechanical energies (SME), and the interaction mechanism of glutelin and rice starch was investigated at the molecular level. The results indicated that the structure of glutelin was destroyed, hydrophobic interactions and hydrogen bonds between rice starch and glutelin were formed and enhanced as the SME increased, and new hydrogen bonds were formed at the carbonyl (δ- and γ-carbons of glutelin) and C-1 of Tyr. Molecular docking studies confirmed that SME promoted the simultaneous occurrence of the Millard reaction and non-covalent reaction between glutelin and small molecular sugars produced by starch degradation, providing information on binding sites. Additionally, scanning electron microscopy (SEM) revealed dense and uniform flake-like structures induced by these binding interactions. Overall, insights into the interaction mechanism of rice starch and glutelin provide theoretical references for generating reconstituted rice products using extrusion processing.

Preparation of High-Nitrogen Ductile Iron by Injecting Nitrogen Gas in Molten Iron.

High-nitrogen ductile iron (DI) was prepared by a new method of injecting nitrogen gas into molten iron and nodularizing treatment. The microstructure and mechanical properties of the as-prepared DI for different nitrogen gas injection periods were characterized. The graphite morphology gradually deteriorated with the increase in the nitrogen gas injection time. The maximum nitrogen and pearlite contents were obtained after 20 min of nitrogen gas injection, and the corresponding tensile strength and elongation of the DI were calculated as 492 MPa and 9.5%, respectively, which were 9.3% and 22% higher than those of the DI prepared without the nitrogen gas injection treatment, respectively.

Wear Behavior of Ductile Iron Wheel Material Used for Rail-Transit Vehicles under Dry Sliding Conditions.

: A ductile iron wheel used for a rail-transit vehicle was treated with a recommended heat-treatment process. The ductile iron wheel after heat treatment was composed of graphite nodules and tempered sorbite with an area fraction of 98%. A friction test of the ductile iron and carbon steel wheel materials was systematically performed under different normal loads and sliding velocities. The results indicated that the wear mechanism of the ductile iron wheel changed from adhesion to abrasion with an increase in the normal load level. Adhesion was the main wear mechanism at different sliding velocities and normal load level. The impact of the normal load on the wear mechanism was greater than that of the sliding velocity. Since the ductile iron wheel material had excellent thermal property and higher carbon content, it exhibited a lower wear rate, a smaller difference value of the friction coefficient, and plastic deformation on the worn surface than those of the carbon steel wheel material. This indicates that ductile iron wheels may have a longer wear life, greater traction, and higher stability during operation than carbon steel wheels. The iron wheels have the potential for being applied in rail-transit vehicles.