Catalytic upgrade for pyrolysis of food waste in a bubbling fluidized-bed reactor.

Biofuel production via pyrolysis has received increasing interest as a promising solution for utilization of now wasted food residue. In this study, the fast pyrolysis of mixed food waste (MFW) was performed in a bubbling fluidized-bed reactor. This was done under different operating conditions (reaction temperatures and carrier gas flow rate) that influence product distribution and bio-oil composition. The highest liquid yield (49.05 wt%) was observed at a pyrolysis temperature of 475 °C. It was also found that the quality of pyrolysis bio-oils (POs) could be improved using catalysts. The catalytic fast pyrolysis of MFW was studied to upgrade the pyrolysis vapor, using dolomite, red mud, and HZSM-5. The higher heating values (HHVs) of the catalytic pyrolysis bio-oils (CPOs) ranged between 30.47 and 35.69 MJ/kg, which are higher than the HHVs of non-catalytic pyrolysis bio-oils (27.69-31.58 MJ/kg). The major components of the bio-oils were fatty acids, N-containing compounds, and derivatives of phenol. The selectivity for bio-oil components varied depending on the catalysts. In the presence of the catalysts, the oxygen was removed from oxygenates via moisture, CO2, and CO. The CPOs contained aliphatic hydrocarbons, polycyclic aromatic compounds (such as naphthalene), pyridine derivatives, and light oxygenates (cyclic alkenes and ketones).

Optimized flash light-emitting diode spectra for mobile phone cameras.

Flash light-emitting diodes (LEDs) of modern mobile phones lack red and cyan spectral parts, however, the color gamut of their respective displays has increased in recent years. The influence of this discrepancy on the color reproduction of smart phones is investigated in this paper. Based on the CIECAM02 color appearance model, a metric is introduced to judge color reproduction of mobile phones under flash LED illumination. An evaluation method is established to compare the visual appearance of a scene under various surrounding illuminations with the reproduction of that scene. To facilitate a comparison with measurements, the evaluation method is based on the raw data of two test cameras and a Digital ColorChecker SG. To reduce the color shift between perception and reproduction, optimized flash LED spectra are presented. A single-LED and a double-LED concept with adjustable color temperature are derived from these results. Additionally, the common characteristics of flash LED spectra giving good results is investigated, identifying the spectral parts with the most influence on camera color reproduction and showing the spectral parts not contributing or even resulting in poor color reproduction. Finally the efficiency of optimized flash LED spectra is compared to standard flash LEDs.