1.
Org Lett
; 18(21): 5588-5591, 2016 11 04.
Artigo
em Inglês
| MEDLINE
| ID: mdl-27767317
RESUMO
A new strategy for the rhodium-catalyzed enantioselective hydroacylation is described. This has been achieved through the merger of iminium ion catalysis and transition-metal catalysis such that asymmetric induction derives from a readily accessible, inexpensive chiral nonracemic secondary amine catalyst rather than a chiral nonracemic phosphine as is typical of conventional asymmetric hydroacylation methods.