Saturable absorber: transparent glass-ceramics based on a mixture of Co:ß-Zn2SiO4 and Co:ZnO nanocrystals.

We report on the development of novel saturable absorbers for erbium lasers based on transparent glass-ceramics (GCs) containing a mixture of cobalt-doped ß-willemite, Co2+:ß-Zn2SiO4, and zinc oxide, Co2+:ZnO, nanosized (10-14 nm) crystals. The structure of the parent glass and GCs is studied by x-ray diffraction, differential scanning calorimetry, transmission electron microscopy, and Raman spectroscopy. Variations of absorption spectra with heat-treatment reveal that Co2+ ions from the parent glass enter the crystals of ZnO and ß-willemite. GCs are characterized by a broad absorption band due to the A24(F4)→T14(F4) transition of Co2+ ions in tetrahedral sites spanning up to ∼1.74 µm, relatively low saturation fluence, FS=0.75 J/cm2 at 1.54 µm, short recovery time, τ=830 ns, and high laser damage threshold, ∼14 J/cm2. By using the developed GCs in a diode-side-pumped Er, Yb:glass laser, 0.77 mJ/45 ns pulses are generated.