Drift-wave instability excited by field-aligned ion flow velocity shear in the absence of electron current.

The drift wave is observed to be destabilized by a magnetic-field-aligned ion flow velocity shear in the absence of field-aligned electron drift flow in laboratory experiments using a concentrically three-segmented plasma source. The fluctuation amplitude increases with increasing a shear strength, but the instability is found to be gradually stabilized when the shear strength exceeds a critical value. The destabilizing and stabilizing mechanisms are well explained by a plasma kinetic theory including the effect of radial density gradient.

Intracluster anionic oligomerization of acrylic ester molecules initiated by electron transfer from an alkali metal atom.

Stabilities and intracluster reactions have been investigated by photoionization mass spectrometry for clusters composed of an alkali metal atom (M; Na and K) and acrylic ester molecules, CH(2)=CHCO(2)R, such as methyl acrylate (MA; R = CH(3)) and ethyl acrylate (EA; R = C(2)H(5)). The following two features are commonly observed in the photoionization mass spectra of M(CH(2)=CHCO(2)R)(n): (1) The ion with n = 3 is clearly observed as a magic number. (2) Fragmented cluster ions with the loss of ROH, [M(CH(2)=CHCO(2)R)(n) - ROH] are detected only for n = 3. These features are both explained by an intracluster oligomerization reaction initiated by electron transfer from the metal atoms. The magic number trimer is concluded to have the stable structure of cyclohexane derivatives as a result of oligomerization. The fragmentation reaction is explained by Dieckmann cyclization after anionic oligomerization to produce another isomer of the trimer. The intracluster electron transfer is also supported by theoretical calculation for Na(MA) based on density functional theory.