RESUMO
Herein, dual-emission carbon dots (DE-CDs) were synthesized using a one-pot hydrothermal method. DE-CDs exhibited two well-separated peaks at 433 and 513 nm under ultraviolet excitation. The prepared DE-CDs offer selective detection of Fe3+ ions via inner filter effect (IFE) and Pb2+ ions via aggregation-induced enhancement (AIE). The obtained DE-CDs showed a good affinity for both Fe3+ and Pb2+ ions in the presence of various interfering ions. The limits of detection were 0.797 ppm and 4.739 ppm for Pb2+ and Fe3+, respectively. The finding reveals the huge potential of DE-CDs for the selective detection of multiple targets in one solution.
RESUMO
Herein, the effect of nanostructured silicon and gold nanoparticles (AuNPs) on the power conversion efficiency (PCE) of an n-type silicon/poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) (n-Si/PEDOT:PSS) hybrid solar cell was investigated. The Si surface modified with different nanostructures including Si nanopyramids (SiNPs), Si nanoholes (SiNHs) and Si nanowires (SiNWs) was utilized to improve light trapping and photo-carrier collection. The highest power conversion efficiency (PCE) of 8.15% was obtained with the hybrid solar cell employing SiNWs, which is about 8%, 20% and 40% higher compared to the devices using SiNHs, SiNPs and planar Si, respectively. The enhancement is attributed to the low reflectance of the SiNW structures and large PEDOT:PSS/Si interfacial area. In addition, the influence of AuNPs on the hybrid solar cell's performance was examined. The PCE of the SiNW/PEDOT:PSS hybrid solar cell with 0.5 wt% AuNP is 8.89%, which is ca. 9% higher than that of the device without AuNPs (8.15%). This is attributed to the increase in the electrical conductivity and localized surface plasmon resonance of the AuNP-incorporated PEDOT:PSS coating layer.
RESUMO
Ordered CoNiP nanowires with the same length of 4 µm and varying diameters (d = 100 nm-600 nm) were fabricated by electrodeposition of CoNiP onto polycarbonate templates. X-ray diffraction, scanning electron microscopy, and high-resolution transmission electron microscopy confirmed the quality of the fabricated nanowires. Magnetic measurements and theoretical analysis revealed that the magnetization reversal and magnetic anisotropy were significantly influenced by varying of the diameters of the nanowires. There existed a critical wire diameter (dc ≈ 276 nm), below which the magnetization reversal occurred via a coherent rotation mode, and above which the magnetization reversal occurred via a curling rotation mode. The easy axis of the magnetization tended to change in direction from parallel to perpendicular with respect to the wire axis as the wire diameter exceeded dc ≈ 276 nm. With increasing wire diameter, the coercive field (Hc) and the remanent to saturation magnetization ratio (Mr/Ms) were also found to rapidly decrease in the range d = 100-400 nm and gradually decrease for d > 400 nm.
