RESUMO
High-density polyethylene (HDPE)-based hybrid nanocomposites containing graphene nanoplatelets (GnPs) and multiwall carbon nanotubes (MWCNTs) were fabricated using melt mixing followed by compression molding. The influences of size and weight ratio of both carbon-based nanofillers on the electrical, thermal, and mechanical properties of hybrid nanocomposites were evaluated. This study proves that the size and weight ratio of carbon-based nanofillers play a critical role in determining these properties. The optimum size and weight ratio of GnPs and MWCNTs are determined at the maximum achieved enhancement for each property. The HDPE-based nanocomposites containing GnPs with larger surface area and MWCNTs with higher aspect ratio display the highest electrical conductivity at GnPs/MWCNTs weight ratio of 2/3. The combination of GnPs with larger surface area and MWCNTs with lower aspect ratio provides the maximum Young's modulus enhancement of hybrid nanocomposites at 1/4 weight ratio of GnPs and MWCNTs. The nanocomposite containing GnPs with the largest lateral size and MWCNTs with a higher aspect ratio at a 3/2 weight ratio exhibits the highest thermal conductivity. Also, at around the percolation threshold of GnPs, the incorporation of MWCNTs with larger aspect ratio into the HDPE-based nanocomposites containing GnPs with the largest lateral size shows a distinct synergic effect on the thermal conductivity and Young's modulus, while an additive effect on the electrical conductivity and thermal stability.
RESUMO
High-density polyethylene (HDPE)-based nanocomposites incorporating three different types of graphene nanoplatelets (GnPs) were fabricated to investigate the size effects of GnPs in terms of both lateral size and thickness on the morphological, thermal, electrical, and mechanical properties. The results show that the inclusion of GnPs enhance the thermal, electrical, and mechanical properties of HDPE-based nanocomposites regardless of GnP size. Nevertheless, the most significant enhancement of the thermal and electrical conductivities and the lowest electrical percolation threshold were achieved with GnPs of a larger lateral size. This could have been attributed to the fact that the GnPs of larger lateral size exhibited a better dispersion in HDPE and formed conductive pathways easily observable in scanning electron microscope (SEM) images. Our results show that the lateral size of GnPs was a more regulating factor for the above-mentioned nanocomposite properties compared to their thickness. For a given lateral size, thinner GnPs showed significantly higher electrical conductivity and a lower percolation threshold than thicker ones. On the other hand, in terms of thermal conductivity, a remarkable amount of enhancement was observed only above a certain filler concentration. The results demonstrate that GnPs with smaller lateral size and larger thickness lead to lower enhancement of the samples' mechanical properties due to poorer dispersion compared to the others. In addition, the size of the GnPs had no considerable effect on the melting and crystallization properties of the HDPE/GnP nanocomposites.
