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1.
Acta Crystallogr E Crystallogr Commun ; 71(Pt 11): o889, 2015 Nov 01.
Artigo em Inglês | MEDLINE | ID: mdl-26594582

RESUMO

The title compound, C7H10O5, was synthesized by reaction of d-xylose with paraformaldehyde. In the crystal, the central part of the mol-ecule consists of a five-membered C4O ring with an envelope conformation, with the methine C atom adjacent to the O atom being the flap. The protected O atoms of both cyclic acetal groups are oriented so that the four chiral C atoms of the furan-ose part show an R configuration. C-H⋯O hydrogen bonds are present between adjacent mol-ecules, generating a three-dimensional network.

2.
Acta Crystallogr E Crystallogr Commun ; 71(Pt 12): o961-2, 2015 Dec 01.
Artigo em Inglês | MEDLINE | ID: mdl-26870551

RESUMO

The title compound, C8H12O6, was synthesized by de-acetyl-ation of 6-acetyl-1,2,3,4-di-O-methyl-ene-α-d-galactose with sodium methoxide. The central part of the mol-ecule consists of a six-membered C5O pyran-ose ring with a twist-boat conformation. Both fused dioxolane rings adopt an envelope conformation with C and O atoms as the flap. In the crystal, O-H⋯O and C-H⋯O hydrogen bonds are present between adjacent mol-ecules, generating a three-dimensional network.

3.
J Org Chem ; 79(21): 10143-52, 2014 Nov 07.
Artigo em Inglês | MEDLINE | ID: mdl-25317917

RESUMO

Sterically congested o-terphenyl crown ethers with alkoxy substituents at the 2,3,4-position or 3,4,5-position were synthesized from the corresponding tetrabromodibenzo[15]crown-5 and the corresponding boronic acids or borolanes via Suzuki cross-coupling and subsequently cyclized to the corresponding triphenylenes utilizing the Scholl reaction. Both series of compounds were investigated by differential scanning calorimetry, polarizing optical microscopy, and X-ray diffraction (SAXS, WAXS) regarding their mesomorphic properties. While all but one of the 3,4,5-substituted derivatives displayed liquid crystalline behavior (Col(h) and Col(r)), only the 2,3,4-substituted triphenylene with the shortest alkoxy chains was liquid crystalline (Col(r)).

4.
Chempluschem ; 79(2): 184, 2014 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-31986582

RESUMO

Invited for this month's cover are the three collaborating groups from the University of Stuttgart and the Fraunhofer Institute for Applied Polymer Research in Potsdam, both from Germany as well as the University of Windsor, Canada. The cover picture shows the shift of frontier orbital energies and symmetries upon excitation with light for three different chromophore lengths. Read the full text of the article at 10.1002/cplu.201300308.

5.
Chempluschem ; 79(2): 223-232, 2014 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-31986584

RESUMO

Three series of rigidified tri-, penta- and heptamethine merocyanine dyes were synthesised. A piperidyl moiety was chosen as the electron-donating substituent while the electron-accepting group was varied from ketones to malononitriles and cyanoacetates. The structures of the compounds in the solid state and in solution were elucidated by X-ray diffraction and NMR spectroscopy, respectively, while optical properties were investigated by absorption and emission spectroscopy. As a general trend, the acceptor properties decrease in the series malononitrile>cyanoacetate>ketone based on the analysis of their solvatochromic behaviour. The experimental results were further supported by calculations at the B3LYP 6-311+G(d) level of theory.

6.
Sci Rep ; 3: 2043, 2013.
Artigo em Inglês | MEDLINE | ID: mdl-23784477

RESUMO

We designed bioinspired cross-linkers based on desmosine, the cross-linker in natural elastin, to prepare hydrogels with thiolated hyaluronic acid. These short, rigid cross-linkers are based on pyridinium salts (as in desmosine) and can connect two polymer backbones. Generally, the obtained semi-synthetic hydrogels are form-stable, can withstand repeated stress, have a large linear-elastic range, and show strain stiffening behavior typical for biopolymer networks. In addition, it is possible to introduce a positive charge to the core of the cross-linker without affecting the gelation efficiency, or consequently the network connectivity. However, the mechanical properties strongly depend on the charge of the cross-linker. The properties of the presented hydrogels can thus be tuned in a range important for engineering of soft tissues by controlling the cross-linking density and the charge of the cross-linker.


Assuntos
Reagentes de Ligações Cruzadas/química , Desmosina/química , Ácido Hialurônico/química , Hidrogéis/química , Materiais Biocompatíveis/química , Teste de Materiais , Fenômenos Mecânicos , Estrutura Molecular , Engenharia Tecidual
7.
Beilstein J Org Chem ; 9: 1093-101, 2013.
Artigo em Inglês | MEDLINE | ID: mdl-23766823

RESUMO

The recently introduced concept of ionic liquid crystals (ILCs) with complementary ion pairs, consisting of both, mesogenic cation and anion, was extended from guanidinium sulfonates to guanidinium sulfonimides. In this preliminary study, the synthesis and mesomorphic properties of selected derivatives were described, which provide the first example of an ILC with the sulfonimide anion directly attached to the mesogenic unit.

8.
Beilstein J Org Chem ; 8: 371-8, 2012.
Artigo em Inglês | MEDLINE | ID: mdl-22509205

RESUMO

4-Cyano-1,1'-biphenyl derivatives bearing ω-hydroxyalkyl substituents were reacted with methyl 3-chloro-3-oxopropionate or cyanoacetic acid, giving liquid-crystalline linear malonates and cyanoacetates. These compounds formed monotropic nematic phases at 62 °C down to ambient temperature upon cooling from the isotropic liquid. The mesomorphic properties were investigated by differential scanning calorimetry, polarizing optical microscopy and X-ray diffraction (WAXS).

9.
Chemistry ; 15(37): 9530-42, 2009 Sep 21.
Artigo em Inglês | MEDLINE | ID: mdl-19658132

RESUMO

Dibenzo[18]crown-6 derivatives 1 with two lateral tetraalkyloxy o-terphenyl units were prepared and converted to the corresponding complexes KX1 (X = halide, BF(4), PF(6), SCN) and NH(4)PF(6)1. Complexation was probed by MALDI-TOF spectrometry and NMR spectroscopy. Downfield shifts of (1)H NMR signals for complexes with soft anions Br, I, SCN, and PF(6) indicated the presence of tight ion pairs, whereas complexes with hard anions F, Cl, or BF(4) showed no or little shifts. In (13)C NMR spectra, upfield shifts were detected for soft anions. The character of the anion also influenced the mesomorphic properties of complexes MX1 (M = K, NH(4)), which were investigated by differential scanning calorimetry (DSC), polarizing optical microscopy (POM), and XRD in comparison to neat 1. Hard anions slightly stabilize or even destabilize the mesophase. Soft anions, however, improve the mesomorphic properties yielding mesophases with up to 70 degrees C phase widths in the case of KI1, KPF(6)1, and NH(4)PF(6)1. For complexes KSCN1 with a soft and bridging anion, the balance between mesophase stabilization and high order is shifted in favor of the plastic crystal phase.

10.
Beilstein J Org Chem ; 5: 63, 2009 Nov 09.
Artigo em Inglês | MEDLINE | ID: mdl-20300461

RESUMO

Based on 5-(4-hydroxyphenyl)-2-octylpyrimidine 8, 5-phenylpyrimidine derivatives 3-7, 9 with different spacer chain lengths (C(2) up to C(6)) and different terminal polar groups (Br, Cl, N(3), OH, CN) were synthesized by etherification and nucleophilic substitution. The mesomorphic behaviour of these compounds was investigated by differential scanning calorimetry (DSC), polarizing optical microscopy (POM) and X-ray diffraction (WAXS and SAXS) and revealed smectic A mesophases for bromides, chlorides and azides 3, 4 and 6. For these compounds a maximum phase width was observed for the C(5) spacer regardless of the terminal group, whereas the hydroxy- and cyano-substituted derivatives 5 and 7, respectively, were non mesomorphic and showed only melting transitions.

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