1.
Chem Commun (Camb)
; 51(89): 16103-6, 2015 Nov 18.
Artigo
em Inglês
| MEDLINE
| ID: mdl-26391908
RESUMO
A Zr-based metal-organic framework with tetrakis(carboxyphenyl)porphyrin groups (Zr-MOF-TCPP: MOF-525) has been utilized as a photoredox catalyst to promote oxidative hydroxylation of arylboronic acids under green LED light irradiation. Zr-MOF-TCPP displays a superior catalytic activity for this process over the corresponding homogeneous catalyst (H4TCPP).