1.
Science
; 261(5127): 1404-11, 1993 Sep 10.
Artigo
em Inglês
| MEDLINE
| ID: mdl-8367724
RESUMO
Recent progress in regioselective and enantioselective epoxidations catalyzed by metalloporphyrins is discussed here, with an explanation of the biomimetic antecedents of this area and its relevance to synthetic applications. Classification of the catalysts that have been studied allows useful conclusions to be drawn about the development of this field. In particular, both the most promising biomimetic and practical catalysts have arisen from systems that can be systematically modified by convenient synthetic methodology.