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1.
Materials (Basel) ; 17(3)2024 Feb 04.
Artigo em Inglês | MEDLINE | ID: mdl-38591661

RESUMO

In the present investigation, the corrosion tendency of mild steel under acidic pH was studied by employing unused expired amiodarone (EAD) drug as a potential corrosion inhibitor by adopting the weight loss measurement method. The corrosion inhibition efficiency (IE) of the formed protective film (EAD) on the steel surface was analyzed using potentiodynamic polarization and AC-impedance spectroscopy studies. The surface morphology of the mild steel before and after corrosion (in 1.0 M HCl) was analyzed via scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDAX), atomic force microscopy (AFM), and thermodynamic studies. The weight loss measurement under different concentrations of EAD indicated that an excellent inhibition was displayed at a concentration of 0.001 M, and the IE was found to depend on both the concentration and molecular structure of EAD. A potentiodynamic polarization study revealed that EAD predominantly acted as a cathode inhibitor, and electrochemical impedance spectroscopy (EIS) confirmed the adsorption of EAD on the surface of mild steel, which obeyed Temkin's adsorption isotherm model. The calculated thermodynamic parameters revealed that adsorption was spontaneous and exothermic.

2.
Polymers (Basel) ; 14(22)2022 Nov 18.
Artigo em Inglês | MEDLINE | ID: mdl-36433134

RESUMO

Recent advances in aircraft materials and their manufacturing technologies have enabled progressive growth in innovative materials such as composites. Al-based, Mg-based, Ti-based alloys, ceramic-based, and polymer-based composites have been developed for the aerospace industry with outstanding properties. However, these materials still have some limitations such as insufficient mechanical properties, stress corrosion cracking, fretting wear, and corrosion. Subsequently, extensive studies have been conducted to develop aerospace materials that possess superior mechanical performance and are corrosion-resistant. Such materials can improve the performance as well as the life cycle cost. This review introduces the recent advancements in the development of composites for aircraft applications. Then it focuses on the studies conducted on composite materials developed for aircraft structures, followed by various fabrication techniques and then their applications in the aircraft industry. Finally, it summarizes the efforts made by the researchers so far and the challenges faced by them, followed by the future trends in aircraft materials.

3.
Materials (Basel) ; 15(20)2022 Oct 13.
Artigo em Inglês | MEDLINE | ID: mdl-36295200

RESUMO

The resistance to delamination in polymer composite depends on their constituents, manufacturing process, environmental factors, specimen geometry, and loading conditions. The manufacturing of laminated composites is usually carried out at an elevated temperature, which induces thermal stresses in composites mainly due to a mismatch in the coefficient of thermal expansion (CTE) of fiber and matrix. This work aims to investigate the effect of these process-induced stresses on mode-I interlaminar fracture toughness (GI) of Glass-Carbon-Epoxy (GCE) and Glass-Epoxy (GE) composites. These composites are prepared using a manual layup technique and cured under room temperature, followed by post-curing using different curing conditions. Double cantilever beam (DCB) specimens were used to determine GI experimentally. The slitting technique was used to estimate residual stresses (longitudinal and transverse direction of crack growth) inherited in cured composites and the impact of these stresses on GI was investigated. Delaminated surfaces of composites were examined using a scanning electron microscopy (SEM) to investigate the effect of post-curing on the mode-I failure mechanism. It was found that GI of both GE and GEC composites are sensitive to the state of residual stress in the laminas. The increase in the GI of laminates can also be attributed to an increase in matrix deformation and fiber-matrix interfacial bond with the increase in post-curing temperature.

4.
Molecules ; 26(14)2021 Jul 07.
Artigo em Inglês | MEDLINE | ID: mdl-34299410

RESUMO

Epoxy resins, due to their high stiffness, ease of processing, good heat, and chemical resistance obtained from cross-linked structures, have found applications in electronics, adhesives coatings, industrial tooling, and aeronautic and automotive industries. These resins are inherently brittle, which has limited their further application. The emphasis of this study is to improve the properties of the epoxy resin with a low-concentration (up to 0.4% by weight) addition of Multi-Walled Carbon Nanotubes (MWCNTs). Mechanical characterization of the modified composites was conducted to study the effect of MWCNTs infusion in the epoxy resin. Nanocomposites samples showed significantly higher tensile strength and fracture toughness compared to pure epoxy samples. The morphological studies of the modified composites were studied using Scanning Electron Microscopy (SEM).

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