RESUMO
A novel nanoplatform composed of three types of materials with different functionalities, specifically core-shell Fe3O4@Au nanoparticles encapsulated near the outer surface of mesoporous silica (mSiO2) nanoparticles, has been successfully synthesised and used to enhance the efficiency of a photosensitiser, namely Rose Bengal, in singlet oxygen generation. Fe3O4 is responsible for the unusual location of the Fe3O4@Au nanoparticle, while the plasmonic shell acts as an optical antenna. In addition, the mesoporous silica matrix firmly encapsulates Rose Bengal by chemical bonding inside the pores, thus guaranteeing its photostability, and in turn making the nanosystem biocompatible. Moreover, the silica surface of the nanoplatform ensures further functionalisation on demand.
RESUMO
Hybrid systems based on magnetite and gold nanoparticles have been extensively used as bifunctional materials for bio- and nano-technology. The properties of these composites are assumed to be closely related to the magnetite to gold mass ratio and to the geometry of the resulting hetero-structures. To illustrate this, we compare and analyze the optical and magnetic properties of core-shell, dumbbell-like dimers and chemical cross-linked pairs of magnetite and gold nanoparticles in detail. We explore how the combination of gold with magnetite can lead to an improvement of the optical properties of these systems, such as tunability, light scattering enhancement or an increase of the local electric field at the interface between magnetic and plasmonic constituents. We also show that although the presence of gold might affect the magnetic response of these hybrid systems, they still show good performance for magnetic applications; indeed the resulting magnetic properties are more dependent on the NP size dispersion. Finally, we identify technological constraints and discuss prospective routes for the development of further magnetic-plasmonic materials.