Fabrication of functional metamaterials for applications in heat-shielding windows and 6G communications.

Windows with passive multilayer coatings can allow less energy to be used when maintaining comfortable indoor temperatures. As a type of effective solar energy management, these coatings can prevent the generation of excessive heat inside buildings or vehicles by reflecting near-infrared solar radiation (750-2000 nm) while retaining visible light transmission (400-750 nm) over a large range of viewing angles. To prevent overheating, they must also reflect rather than absorb near-infrared radiation. A transparent heat-shielding window is numerically and experimentally demonstrated in this study. High visual transparency (77.2%), near-infrared reflectance (86.1%), and low infrared absorption (<20%) over a wide range of oblique incident angles were achieved using nanometer-scale cross-shaped metamaterials manufactured by electron beam lithography. Furthermore, high terahertz transmittance (up to 82%) was also achieved for 6G communication system applications.

Silver-based SERS substrates fabricated using a 3D printed microfluidic device.

The detection of harmful chemicals in the environment and for food safety is a crucial requirement. While traditional techniques such as GC-MS and HPLC provide high sensitivity, they are expensive, time-consuming, and require skilled labor. Surface-enhanced Raman spectroscopy (SERS) is a powerful analytical tool for detecting ultralow concentrations of chemical compounds and biomolecules. We present a reproducible method for producing Ag nanoparticles that can be used to create highly sensitive SERS substrates. A microfluidic device was employed to confine the precursor reagents within the droplets, resulting in Ag nanoparticles of uniform shape and size. The study investigates the effects of various synthesis conditions on the size distribution, dispersity, and localized surface plasmon resonance wavelength of the Ag nanoparticles. To create the SERS substrate, the as-synthesized Ag nanoparticles were assembled into a monolayer on a liquid/air interface and deposited onto a porous silicon array prepared through a metal-assisted chemical etching approach. By using the developed microfluidic device, enhancement factors of the Raman signal for rhodamine B (at 10-9 M) and melamine (at 10-7 M) of 8.59 × 106 and 8.21 × 103, respectively, were obtained. The detection limits for rhodamine B and melamine were estimated to be 1.94 × 10-10 M and 2.8 × 10-8 M with relative standard deviation values of 3.4% and 4.6%, respectively. The developed SERS substrate exhibits exceptional analytical performance and has the potential to be a valuable analytical tool for monitoring environmental contaminants.

Neisseria gonorrhoeae FC428 Subclone, Vietnam, 2019-2020.

Among 114 clinical Neisseria gonorrhoeae isolates collected in Vietnam during 2019-2020, we detected 15 of subclone sequence type 13871 of the FC428 clonal complex. Fourteen sequence type 13871 isolates with mosaic penA allele 60.001 were ceftriaxone or cefixime nonsusceptible, and 3/14 were azithromycin nonsusceptible. Emergence of this subclone threatens treatment effectiveness.

Biocontrol Potential of Aspergillus Species Producing Antimicrobial Metabolites.

Microbial metabolites have been recognized as an important source for the discovery of new antifungal agents because of their diverse chemical structures with novel modes of action. In the course of our screening for new antifungal agents from microbes, we found that culture filtrates of two fungal species Aspergillus candidus SFC20200425-M11 and Aspergillus montenegroi SFC20200425-M27 have the potentials to reduce the development of fungal plant diseases such as tomato late blight and wheat leaf rust. From these two Aspergillus spp., we isolated a total of seven active compounds, including two new compounds (4 and 6), and identified their chemical structures based on the NMR spectral analyses: sphaeropsidin A (1), (R)-formosusin A (2), (R)-variotin (3), candidusin (4), asperlin (5), montenegrol (6), and protulactone A (7). Based on the results of the in vitro bioassays of 11 plant pathogenic fungi and bacteria, sphaeropsidin A (1), (R)-formosusin A (2), (R)-variotin (3), and asperlin (5) exhibited a wide range of antimicrobial activity. Furthermore, when plants were treated with sphaeropsidin A (1) and (R)-formosusin A (2) at a concentration of 500 µg/ml, sphaeropsidin A (1) exhibited an efficacy disease control value of 96 and 90% compared to non-treated control against tomato late blight and wheat leaf rust, and (R)-formosusin A (2) strongly reduced the development of tomato gray mold by 82%. Asperlin (5) at a concentration of 500 µg/ml effectively controlled the development of tomato late blight and wheat leaf rust with a disease control value of 95%. Given that culture filtrates and active compounds derived from two Aspergillus spp. exhibited disease control efficacies, our results suggest that the Aspergillus-produced antifungal compounds could be useful for the development of new natural fungicides.

Exploiting Joint Base Station Equipped Multiple Antenna and Full-Duplex D2D Users in Power Domain Division Based Multiple Access Networks.

In this paper, we investigate power domain division-based multiple access (PDMA) to support the base stations (BS) equipped with multiple antennas to serve mobile users. Such a system deploys multiple input single output (MISO)-based wireless transmission and a full-duplex (FD) scheme. Furthermore, such MISO PDMA system consists of BS employing transmit antenna selection to reduce complexity in signal processing at the receivers. We distinguish two kinds of mobile users, device-to-device (D2D) users and traditional users. In such MISO PDMA, there exists a trade-off between outage performance of each PDMA user and power allocation factors. Since the implementation of the FD scheme at PDMA users, bandwidth efficiency will be enhanced despite the existence of self-interference related to such FD. In particular, exact expressions of outage probability are derived to exhibit system performance with respect to D2D users. Finally, valuable results from the simulated parameters together with the analytical results show that MISO PDMA can improve its performance by increasing the number of transmit antennas at the BS.

NOMA-Assisted Multiple Access Scheme for IoT Deployment: Relay Selection Model and Secrecy Performance Improvement.

In this paper, an Internet-of-Things (IoT) system containing a relay selection is studied as employing an emerging multiple access scheme, namely non-orthogonal multiple access (NOMA). This paper proposes a new scheme to consider secure performance, to be called relay selection NOMA (RS-NOMA). In particular, we consider metrics to evaluate secure performance in such an RS-NOMA system where a base station (master node in IoT) sends confidential messages to two main sensors (so-called NOMA users) under the influence of an external eavesdropper. In the proposed IoT scheme, both two NOMA sensors and an illegal sensor are served with different levels of allocated power at the base station. It is noticed that such RS-NOMA operates in two hop transmission of the relaying system. We formulate the closed-form expressions of secure outage probability (SOP) and the strictly positive secure capacity (SPSC) to examine the secrecy performance under controlling setting parameters such as transmit signal-to-noise ratio (SNR), the number of selected relays, channel gains, and threshold rates. The different performance is illustrated as performing comparisons between NOMA and orthogonal multiple access (OMA). Finally, the advantage of NOMA in secure performance over orthogonal multiple access (OMA) is confirmed both analytically and numerically.

Stability of Golden redfish (Sebastes marinus) during frozen storage as affected by raw material freshness and season of capture.

Physicochemical changes of Icelandic golden redfish (Sebastes marinus) as affected by seasonal variation (June and November) and raw material freshness (processed 4 and 9 days postcatch) during frozen storage (at -25°C for 20 months) were studied to find optimal conditions for production of high-quality frozen products. Thawing loss, cooking yield, and color of the fillets as well as chemical composition, water holding capacity, pH, total volatile basic nitrogen, lipid oxidation, and hydrolysis of the light and dark muscle were analyzed every 4 months of frozen storage. Lipid hydrolysis was the main degradation process in the light muscle, while the dark muscle was more affected by lipid oxidation. Fish caught in November showed greater instability in the analyzed parameters during storage than fish caught in June, which could be linked to differences in individual poly unsaturated fatty acids between the two seasons. The quality attributes of fish processed on day 9 were similar to fish processed 4 days postcatch, except slightly higher thawing loss and yellowness, were observed in fish processed 9 days postcatch. Stability of golden redfish through frozen storage was higher in the fish caught in June than in November.

Influence of smoking and packaging methods on lipid stability and microbial quality of Capelin (Mallotus villosus) and Sardine (Sardinella gibossa).

Lipid and microbial quality of smoked capelin (two groups differing in lipid content) and sardine was studied, with the aim of introducing capelin in the smoked sardine markets. Lipid hydrolysis (phospholipid and free fatty acids) and oxidation index (hydroperoxides and thiobarbituric acid-reactive substances), fatty acid composition, and total viable count were measured in raw and packaged smoked fish during chilled storage (day 2, 10, 16, 22, 28). Lipid hydrolysis was more pronounced in low lipid capelin, whereas accelerated lipid oxidation occurred in high lipid capelin. Muscle lipid was less stable in sardine than capelin. Essential polyunsaturated fatty acids (eicosapentaenoic acid and docosahexaenoic acid) constituted 12% of fatty acids in capelin and 19% in sardine. Vacuum packaging as well as hot smoking retarded bacterial growth, recording counts of ≤log 5 CFU/g compared to ≥log 7CFU/g in cold smoked air packaged. Smoked low lipid capelin was considered an alternative for introduction in smoked sardine markets.