1.
Dalton Trans
; 49(45): 16077-16081, 2020 Nov 25.
Artigo
em Inglês
| MEDLINE
| ID: mdl-32677645
RESUMO
Methods to incorporate kinetically inert metal nodes and highly basic ligands into single-crystalline metal-organic frameworks (MOFs) are scarce, which prevents synthesis and systematic variation of many potential heterogeneous catalyst materials. Here we demonstrate that metallopolymerization of kinetically inert Ru2 metallomonomers via labile Ag-N bonds provides access to a family of atomically precise single-crystalline Ru2-based coordination polymers with varied network topology and primary coordination sphere.