1.
IUCrdata
; 9(Pt 2): x240109, 2024 Feb.
Artigo
em Inglês
| MEDLINE
| ID: mdl-38455110
RESUMO
In the title complex salt, [Pd(C10H8N2)(C12H12N2O2)](CF3SO3)2, the palladium(II) atom is fourfold coordinated by two chelating ligands, 2,2'-bi-pyridine and 4,4'-dimeth-oxy-2,2'-bi-pyridine, in a distorted square-planar environment. In the crystal, weak π-π stacking inter-actions between the 2,2'-bi-pyridine rings [centroid-to-centroid distances = 3.8984â (19)â Å] and between the 4,4'-dimeth-oxy-2,2'-bi-pyridine rings [centroid-to-centroid distances = 3.747â (18)â Å] contribute to the alignment of the complex cations in columns parallel to the b-axis direction.