RESUMO
In safety-critical chemical reactors with potential hazards, reaction kinetics and heat transfer parameters are usually known, and a mathematical model is available. It is then meaningful to base fault detection and isolation algorithms on the first-principles model as opposed to statistics, so that physically meaningful residual signals are generated from material and/or energy balances not closing, leading to reliable fault diagnosis. Additionally, to maintain the safety of the entire system, it is necessary to take appropriate control action based on the mathematical model and the identified faults, to minimize their impact and thus ensure safe operation. In the present work, these ideas will be formulated and illustrated through a continuous stirred-tank reactor case study involving the liquid-phase oxidation of alkylpyridine with hydrogen peroxide. The proposed fault tolerant control strategy monitors the DSM (distance of the system state from the boundary of the dynamic safe set) and the estimate of the fault size, and when they cross a certain limit as a result of an abnormal event, the manipulated input is switched. Simulation results show the effectiveness of the proposed fault tolerant control strategy in dealing with cooling system failure.
